1-Dichloroacetyl-3,3-dimethyl-2,6-diphenylpiperidin-4-one
In the title compound, C21H21Cl2NO2, the piperidine ring adopts a distorted boat conformation. The two phenyl rings are approximately perpendicular to each other, with a dihedral angle of 86.12 (7)°. Molecules are linked into centrosymmetric dimers by pairs of bifurcated CR...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808040051 |
| _version_ | 1798017858855239680 |
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| author | S. Ponnuswamy M. Jamesh J. Umamaheshwari M. N. Ponnuswamy T. Kavitha |
| author_facet | S. Ponnuswamy M. Jamesh J. Umamaheshwari M. N. Ponnuswamy T. Kavitha |
| author_sort | S. Ponnuswamy |
| collection | DOAJ |
| description | In the title compound, C21H21Cl2NO2, the piperidine ring adopts a distorted boat conformation. The two phenyl rings are approximately perpendicular to each other, with a dihedral angle of 86.12 (7)°. Molecules are linked into centrosymmetric dimers by pairs of bifurcated C—H...O hydrogen bonds, forming R22(10) and R22(14) ring motifs, and an intramolecular C—H...O link also occurs. |
| first_indexed | 2024-04-11T16:14:17Z |
| format | Article |
| id | doaj.art-7155ab6627cf447b9465f04cd2055799 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:14:17Z |
| publishDate | 2009-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7155ab6627cf447b9465f04cd20557992022-12-22T04:14:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651o10o1010.1107/S16005368080400511-Dichloroacetyl-3,3-dimethyl-2,6-diphenylpiperidin-4-oneS. PonnuswamyM. JameshJ. UmamaheshwariM. N. PonnuswamyT. KavithaIn the title compound, C21H21Cl2NO2, the piperidine ring adopts a distorted boat conformation. The two phenyl rings are approximately perpendicular to each other, with a dihedral angle of 86.12 (7)°. Molecules are linked into centrosymmetric dimers by pairs of bifurcated C—H...O hydrogen bonds, forming R22(10) and R22(14) ring motifs, and an intramolecular C—H...O link also occurs.http://scripts.iucr.org/cgi-bin/paper?S1600536808040051 |
| spellingShingle | S. Ponnuswamy M. Jamesh J. Umamaheshwari M. N. Ponnuswamy T. Kavitha 1-Dichloroacetyl-3,3-dimethyl-2,6-diphenylpiperidin-4-one Acta Crystallographica Section E |
| title | 1-Dichloroacetyl-3,3-dimethyl-2,6-diphenylpiperidin-4-one |
| title_full | 1-Dichloroacetyl-3,3-dimethyl-2,6-diphenylpiperidin-4-one |
| title_fullStr | 1-Dichloroacetyl-3,3-dimethyl-2,6-diphenylpiperidin-4-one |
| title_full_unstemmed | 1-Dichloroacetyl-3,3-dimethyl-2,6-diphenylpiperidin-4-one |
| title_short | 1-Dichloroacetyl-3,3-dimethyl-2,6-diphenylpiperidin-4-one |
| title_sort | 1 dichloroacetyl 3 3 dimethyl 2 6 diphenylpiperidin 4 one |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808040051 |
| work_keys_str_mv | AT sponnuswamy 1dichloroacetyl33dimethyl26diphenylpiperidin4one AT mjamesh 1dichloroacetyl33dimethyl26diphenylpiperidin4one AT jumamaheshwari 1dichloroacetyl33dimethyl26diphenylpiperidin4one AT mnponnuswamy 1dichloroacetyl33dimethyl26diphenylpiperidin4one AT tkavitha 1dichloroacetyl33dimethyl26diphenylpiperidin4one |