A high spatial resolution retrieval of NO<sub> 2</sub> column densities from OMI: method and evaluation
We present a new retrieval of tropospheric NO<sub>2</sub> vertical column density from the Ozone Monitoring Instrument (OMI) based on high spatial and temporal resolution terrain and profile inputs. We compare our NO<sub>2</sub> product, the Berkeley High-Resolution (BEHR) pr...
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| Format: | Article |
| Language: | English |
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Copernicus Publications
2011-08-01
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| Series: | Atmospheric Chemistry and Physics |
| Online Access: | http://www.atmos-chem-phys.net/11/8543/2011/acp-11-8543-2011.pdf |
| _version_ | 1831839002936737792 |
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| author | R. C. Cohen E. J. Bucsela E. C. Browne P. J. Wooldridge L. C. Valin A. R. Russell A. E. Perring |
| author_facet | R. C. Cohen E. J. Bucsela E. C. Browne P. J. Wooldridge L. C. Valin A. R. Russell A. E. Perring |
| author_sort | R. C. Cohen |
| collection | DOAJ |
| description | We present a new retrieval of tropospheric NO<sub>2</sub> vertical column density from the Ozone Monitoring Instrument (OMI) based on high spatial and temporal resolution terrain and profile inputs. We compare our NO<sub>2</sub> product, the Berkeley High-Resolution (BEHR) product, with operational retrievals and find that the operational retrievals are biased high (30 %) over remote areas and biased low (8 %) over urban regions. Additionally, we find non-negligible impacts on the retrieved NO<sub>2</sub> column for terrain pressure (±20 %), albedo (±40 %), and NO<sub>2</sub> vertical profile (−75 %–+10 %). We validate the operational and BEHR products using boundary layer aircraft observations from the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS-CA) field campaign which occurred in June 2008 in California. Results indicate that columns derived using our boundary layer extrapolation method show good agreement with satellite observations (<i>R</i><sup>2</sup> = 0.65–0.83; <i>N</i> = 68) and provide a more robust validation of satellite-observed NO<sub>2</sub> column than those determined using full vertical spirals (<i>R</i><sup>2</sup> = 0.26; <i>N</i> = 5) as in previous work. Agreement between aircraft observations and the BEHR product (<i>R</i><sup>2</sup> = 0.83) is better than agreement with the operational products (<i>R</i><sup>2</sup> = 0.65–0.72). We also show that agreement between satellite and aircraft observations can be further improved (e.g. BEHR: <i>R</i><sup>2</sup> = 0.91) using cloud information from the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument instead of the OMI cloud product. These results indicate that much of the variance in the operational products can be attributed to coarse resolution terrain pressure, albedo, and profile parameters implemented in the retrievals. |
| first_indexed | 2024-12-23T05:43:25Z |
| format | Article |
| id | doaj.art-716878caf59c443c8f57e8d75a300be0 |
| institution | Directory Open Access Journal |
| issn | 1680-7316 1680-7324 |
| language | English |
| last_indexed | 2024-12-23T05:43:25Z |
| publishDate | 2011-08-01 |
| publisher | Copernicus Publications |
| record_format | Article |
| series | Atmospheric Chemistry and Physics |
| spelling | doaj.art-716878caf59c443c8f57e8d75a300be02022-12-21T17:58:07ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242011-08-0111168543855410.5194/acp-11-8543-2011A high spatial resolution retrieval of NO<sub> 2</sub> column densities from OMI: method and evaluationR. C. CohenE. J. BucselaE. C. BrowneP. J. WooldridgeL. C. ValinA. R. RussellA. E. PerringWe present a new retrieval of tropospheric NO<sub>2</sub> vertical column density from the Ozone Monitoring Instrument (OMI) based on high spatial and temporal resolution terrain and profile inputs. We compare our NO<sub>2</sub> product, the Berkeley High-Resolution (BEHR) product, with operational retrievals and find that the operational retrievals are biased high (30 %) over remote areas and biased low (8 %) over urban regions. Additionally, we find non-negligible impacts on the retrieved NO<sub>2</sub> column for terrain pressure (±20 %), albedo (±40 %), and NO<sub>2</sub> vertical profile (−75 %–+10 %). We validate the operational and BEHR products using boundary layer aircraft observations from the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS-CA) field campaign which occurred in June 2008 in California. Results indicate that columns derived using our boundary layer extrapolation method show good agreement with satellite observations (<i>R</i><sup>2</sup> = 0.65–0.83; <i>N</i> = 68) and provide a more robust validation of satellite-observed NO<sub>2</sub> column than those determined using full vertical spirals (<i>R</i><sup>2</sup> = 0.26; <i>N</i> = 5) as in previous work. Agreement between aircraft observations and the BEHR product (<i>R</i><sup>2</sup> = 0.83) is better than agreement with the operational products (<i>R</i><sup>2</sup> = 0.65–0.72). We also show that agreement between satellite and aircraft observations can be further improved (e.g. BEHR: <i>R</i><sup>2</sup> = 0.91) using cloud information from the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument instead of the OMI cloud product. These results indicate that much of the variance in the operational products can be attributed to coarse resolution terrain pressure, albedo, and profile parameters implemented in the retrievals.http://www.atmos-chem-phys.net/11/8543/2011/acp-11-8543-2011.pdf |
| spellingShingle | R. C. Cohen E. J. Bucsela E. C. Browne P. J. Wooldridge L. C. Valin A. R. Russell A. E. Perring A high spatial resolution retrieval of NO<sub> 2</sub> column densities from OMI: method and evaluation Atmospheric Chemistry and Physics |
| title | A high spatial resolution retrieval of NO<sub> 2</sub> column densities from OMI: method and evaluation |
| title_full | A high spatial resolution retrieval of NO<sub> 2</sub> column densities from OMI: method and evaluation |
| title_fullStr | A high spatial resolution retrieval of NO<sub> 2</sub> column densities from OMI: method and evaluation |
| title_full_unstemmed | A high spatial resolution retrieval of NO<sub> 2</sub> column densities from OMI: method and evaluation |
| title_short | A high spatial resolution retrieval of NO<sub> 2</sub> column densities from OMI: method and evaluation |
| title_sort | high spatial resolution retrieval of no sub 2 sub column densities from omi method and evaluation |
| url | http://www.atmos-chem-phys.net/11/8543/2011/acp-11-8543-2011.pdf |
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