Experimental Conditions for the Stabilization of the Lyotropic Biaxial Nematic Mesophase

Nematic phases are some of the most common phases among the lyotropic liquid crystalline structures. They have been widely investigated during last decades. In early studies, two uniaxial nematic phases (discotic, ND, and calamitic, NC) were identified. After the discovery of the third one, named bi...

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Main Authors: Erol Akpinar, Antônio Martins Figueiredo Neto
Format: Article
Language:English
Published: MDPI AG 2019-03-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/9/3/158
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author Erol Akpinar
Antônio Martins Figueiredo Neto
author_facet Erol Akpinar
Antônio Martins Figueiredo Neto
author_sort Erol Akpinar
collection DOAJ
description Nematic phases are some of the most common phases among the lyotropic liquid crystalline structures. They have been widely investigated during last decades. In early studies, two uniaxial nematic phases (discotic, ND, and calamitic, NC) were identified. After the discovery of the third one, named biaxial nematic phase (NB) in 1980, however, some controversies in the stability of biaxial nematic phases began and still continue in the literature. From the theoretical point of view, the existence of a biaxial nematic phase is well established. This review aims to bring information about the historical development of those phases considering the early studies and then summarize the recent studies on how to stabilize different nematic phases from the experimental conditions, especially, choosing the suitable constituents of lyotropic mixtures.
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spelling doaj.art-716b0fd6fc684a619f3f57d167e20a672022-12-22T02:57:53ZengMDPI AGCrystals2073-43522019-03-019315810.3390/cryst9030158cryst9030158Experimental Conditions for the Stabilization of the Lyotropic Biaxial Nematic MesophaseErol Akpinar0Antônio Martins Figueiredo Neto1Bolu Abant Izzet Baysal University, Faculty of Arts and Sciences, Department of Chemistry, 14030, Golkoy, Bolu 14030, TurkeyInstituto de Física, Universidade de São Paulo, Rua do Matão, 1371, São Paulo-SP 05508-090, BrazilNematic phases are some of the most common phases among the lyotropic liquid crystalline structures. They have been widely investigated during last decades. In early studies, two uniaxial nematic phases (discotic, ND, and calamitic, NC) were identified. After the discovery of the third one, named biaxial nematic phase (NB) in 1980, however, some controversies in the stability of biaxial nematic phases began and still continue in the literature. From the theoretical point of view, the existence of a biaxial nematic phase is well established. This review aims to bring information about the historical development of those phases considering the early studies and then summarize the recent studies on how to stabilize different nematic phases from the experimental conditions, especially, choosing the suitable constituents of lyotropic mixtures.http://www.mdpi.com/2073-4352/9/3/158Lyotropic liquid crystalsuniaxial nematic phasebiaxial nematic phasestabilization of nematic phasesmicellesurfactants
spellingShingle Erol Akpinar
Antônio Martins Figueiredo Neto
Experimental Conditions for the Stabilization of the Lyotropic Biaxial Nematic Mesophase
Crystals
Lyotropic liquid crystals
uniaxial nematic phase
biaxial nematic phase
stabilization of nematic phases
micelle
surfactants
title Experimental Conditions for the Stabilization of the Lyotropic Biaxial Nematic Mesophase
title_full Experimental Conditions for the Stabilization of the Lyotropic Biaxial Nematic Mesophase
title_fullStr Experimental Conditions for the Stabilization of the Lyotropic Biaxial Nematic Mesophase
title_full_unstemmed Experimental Conditions for the Stabilization of the Lyotropic Biaxial Nematic Mesophase
title_short Experimental Conditions for the Stabilization of the Lyotropic Biaxial Nematic Mesophase
title_sort experimental conditions for the stabilization of the lyotropic biaxial nematic mesophase
topic Lyotropic liquid crystals
uniaxial nematic phase
biaxial nematic phase
stabilization of nematic phases
micelle
surfactants
url http://www.mdpi.com/2073-4352/9/3/158
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