Studying the effect of modifying additives on the hydration and hardening of cement composites for 3D printing

The development and application of multicomponent multifunctional additives for cement composites is an important research area since the use of such additives allows controlling both the rheological properties of fresh mixtures and the physical and mechanical properties of the hardened composite....

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Main Authors: Galina S. Slavcheva, Olga V. Artamonova, Dmitry S. Babenko, Maria A. Shvedova
Format: Article
Language:English
Published: Voronezh State University 2023-03-01
Series:Конденсированные среды и межфазные границы
Subjects:
Online Access:https://journals.vsu.ru/kcmf/article/view/10979
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author Galina S. Slavcheva
Olga V. Artamonova
Dmitry S. Babenko
Maria A. Shvedova
author_facet Galina S. Slavcheva
Olga V. Artamonova
Dmitry S. Babenko
Maria A. Shvedova
author_sort Galina S. Slavcheva
collection DOAJ
description The development and application of multicomponent multifunctional additives for cement composites is an important research area since the use of such additives allows controlling both the rheological properties of fresh mixtures and the physical and mechanical properties of the hardened composite. In our study, we used several additives, including metakaolin and xanthan gum together with tetrapotassium pyrophosphate and a SiO2 based complex additive, to modify cementitious sand-based materials. We studied the peculiarities of the influence of these additives on the technological characteristics of mixtures (plasticity and shape retention) and the processes of setting, hydration, and hardening of the composite materials. The optimal values of plasticity, for stability, acceleration of hardening were demonstrated by sand-based systems modified with a complex nanosized additive and metakaolin. The hydration products in the such systems are mainly formed from low basic hydroxides. Metakaolin also results in the formation of ettringite. These systems demonstrate the optimal time of the beginning of setting and the maximum strength gain of the modified cementitious sand-based materials at 28 days. The optimal ratio of indicators of plasticity and shape retention of cement mixtures and the strength of composites based on them obtained by using the studied additives allows us to recommend using these additives in the innovative technologies for 3D-build printing.
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spelling doaj.art-717c36dfe4c2471b98237b6ada21e7af2023-04-20T07:33:04ZengVoronezh State UniversityКонденсированные среды и межфазные границы1606-867X2023-03-0125110.17308/kcmf.2023.25/10979Studying the effect of modifying additives on the hydration and hardening of cement composites for 3D printingGalina S. Slavcheva0https://orcid.org/0000-0001-8800-2657Olga V. Artamonova1https://orcid.org/0000-0001-9157-527XDmitry S. Babenko2Maria A. Shvedova3https://orcid.org/0000-0002-6484-8719Voronezh State Technical University, 84 20-Letiya Oktyabrya ul., Voronezh 394006, Russian FederationVoronezh State Technical University, 84 20-Letiya Oktyabrya ul., Voronezh 394006, Russian FederationVoronezh State Technical University, 84 20-Letiya Oktyabrya ul., Voronezh 394006, Russian FederationVoronezh State Technical University, 84 20-Letiya Oktyabrya ul., Voronezh 394006, Russian FederationThe development and application of multicomponent multifunctional additives for cement composites is an important research area since the use of such additives allows controlling both the rheological properties of fresh mixtures and the physical and mechanical properties of the hardened composite. In our study, we used several additives, including metakaolin and xanthan gum together with tetrapotassium pyrophosphate and a SiO2 based complex additive, to modify cementitious sand-based materials. We studied the peculiarities of the influence of these additives on the technological characteristics of mixtures (plasticity and shape retention) and the processes of setting, hydration, and hardening of the composite materials. The optimal values of plasticity, for stability, acceleration of hardening were demonstrated by sand-based systems modified with a complex nanosized additive and metakaolin. The hydration products in the such systems are mainly formed from low basic hydroxides. Metakaolin also results in the formation of ettringite. These systems demonstrate the optimal time of the beginning of setting and the maximum strength gain of the modified cementitious sand-based materials at 28 days. The optimal ratio of indicators of plasticity and shape retention of cement mixtures and the strength of composites based on them obtained by using the studied additives allows us to recommend using these additives in the innovative technologies for 3D-build printing.https://journals.vsu.ru/kcmf/article/view/10979cement hardening systemsmodificationmodifying additiveshydration processrheological propertiescompressive strength
spellingShingle Galina S. Slavcheva
Olga V. Artamonova
Dmitry S. Babenko
Maria A. Shvedova
Studying the effect of modifying additives on the hydration and hardening of cement composites for 3D printing
Конденсированные среды и межфазные границы
cement hardening systems
modification
modifying additives
hydration process
rheological properties
compressive strength
title Studying the effect of modifying additives on the hydration and hardening of cement composites for 3D printing
title_full Studying the effect of modifying additives on the hydration and hardening of cement composites for 3D printing
title_fullStr Studying the effect of modifying additives on the hydration and hardening of cement composites for 3D printing
title_full_unstemmed Studying the effect of modifying additives on the hydration and hardening of cement composites for 3D printing
title_short Studying the effect of modifying additives on the hydration and hardening of cement composites for 3D printing
title_sort studying the effect of modifying additives on the hydration and hardening of cement composites for 3d printing
topic cement hardening systems
modification
modifying additives
hydration process
rheological properties
compressive strength
url https://journals.vsu.ru/kcmf/article/view/10979
work_keys_str_mv AT galinasslavcheva studyingtheeffectofmodifyingadditivesonthehydrationandhardeningofcementcompositesfor3dprinting
AT olgavartamonova studyingtheeffectofmodifyingadditivesonthehydrationandhardeningofcementcompositesfor3dprinting
AT dmitrysbabenko studyingtheeffectofmodifyingadditivesonthehydrationandhardeningofcementcompositesfor3dprinting
AT mariaashvedova studyingtheeffectofmodifyingadditivesonthehydrationandhardeningofcementcompositesfor3dprinting