catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N]
The molecular structure of the title compound, [FePt(CN)4(C14H8N2)2(H2O)2]n, consists of one-dimensional polymeric [–Fe–NC–Pt(CN)2–CN–]∞ chains. Two water molecules and two monodentate 1,4-bis(pyridin-4-yl)buta-1,3-diyne (bpb) ligand molecules complete the octahedral coordination sphere of the FeII...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-10-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314617014134 |
| _version_ | 1828328174581186560 |
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| author | Lucia Piñeiro-López Francisco Javier Valverde-Muñoz Maksym Seredyuk Kateryna Znovjyak |
| author_facet | Lucia Piñeiro-López Francisco Javier Valverde-Muñoz Maksym Seredyuk Kateryna Znovjyak |
| author_sort | Lucia Piñeiro-López |
| collection | DOAJ |
| description | The molecular structure of the title compound, [FePt(CN)4(C14H8N2)2(H2O)2]n, consists of one-dimensional polymeric [–Fe–NC–Pt(CN)2–CN–]∞ chains. Two water molecules and two monodentate 1,4-bis(pyridin-4-yl)buta-1,3-diyne (bpb) ligand molecules complete the octahedral coordination sphere of the FeII atoms. The Fe—N(py) bond length (py is pyridine) is 2.2700 (15) Å, Fe—N(cyanide) is 2.1185 (16) Å and the Fe—O distance is 2.1275 (14) Å. The water molecules are hydrogen bonded to either bpb ligands or cyanide groups of the planar [Pt(CN)4]2− anion of adjacent polymeric chains. These O—H...N hydrogen bonds, in conjunction with offset and tilted π–π stacking interactions between bpb ligands and cyanide groups, extend the one-dimensional chains into a three-dimensional assembly. |
| first_indexed | 2024-04-13T20:05:56Z |
| format | Article |
| id | doaj.art-7186ebcdb35147bbb2635527feceb95b |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-04-13T20:05:56Z |
| publishDate | 2017-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-7186ebcdb35147bbb2635527feceb95b2022-12-22T02:32:00ZengInternational Union of CrystallographyIUCrData2414-31462017-10-01210x17141310.1107/S2414314617014134zl4019catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N]Lucia Piñeiro-López0Francisco Javier Valverde-Muñoz1Maksym Seredyuk2Kateryna Znovjyak3Institut de Ciencia Molecular (ICMol), Departament de Quimica Inorganica, Universitat de Valencia, Catedratico José Beltran Martinez, 2, 46980, Paterna, Valencia, SpainInstitut de Ciencia Molecular (ICMol), Departament de Quimica Inorganica, Universitat de Valencia, Catedratico José Beltran Martinez, 2, 46980, Paterna, Valencia, SpainInstitut de Ciencia Molecular (ICMol), Departament de Quimica Inorganica, Universitat de Valencia, Catedratico José Beltran Martinez, 2, 46980, Paterna, Valencia, SpainNational Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv, UkraineThe molecular structure of the title compound, [FePt(CN)4(C14H8N2)2(H2O)2]n, consists of one-dimensional polymeric [–Fe–NC–Pt(CN)2–CN–]∞ chains. Two water molecules and two monodentate 1,4-bis(pyridin-4-yl)buta-1,3-diyne (bpb) ligand molecules complete the octahedral coordination sphere of the FeII atoms. The Fe—N(py) bond length (py is pyridine) is 2.2700 (15) Å, Fe—N(cyanide) is 2.1185 (16) Å and the Fe—O distance is 2.1275 (14) Å. The water molecules are hydrogen bonded to either bpb ligands or cyanide groups of the planar [Pt(CN)4]2− anion of adjacent polymeric chains. These O—H...N hydrogen bonds, in conjunction with offset and tilted π–π stacking interactions between bpb ligands and cyanide groups, extend the one-dimensional chains into a three-dimensional assembly.http://scripts.iucr.org/cgi-bin/paper?S2414314617014134crystal structurebitopic bpb ligandhydrogen bondingπ–π stacking interactions |
| spellingShingle | Lucia Piñeiro-López Francisco Javier Valverde-Muñoz Maksym Seredyuk Kateryna Znovjyak catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N] IUCrData crystal structure bitopic bpb ligand hydrogen bonding π–π stacking interactions |
| title | catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N] |
| title_full | catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N] |
| title_fullStr | catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N] |
| title_full_unstemmed | catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N] |
| title_short | catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N] |
| title_sort | catena poly diaquabis 1 4 bis pyridin 4 yl buta 1 3 diyne κn iron ii μ cyanido κ2n c dicyanido κ2c platinum ii μ cyanido κ2c n |
| topic | crystal structure bitopic bpb ligand hydrogen bonding π–π stacking interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314617014134 |
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