[6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate
A new heteroleptic Cu(I) complex, [Cu(L)(PPh<sub>3</sub>)<sub>2</sub>][BF<sub>4</sub>] (L = 6-(furan-2-yl)-2,2′-bipyridine; PPh<sub>3</sub> = triphenylphosphine), was successfully synthesized and characterized. Its molecular structure was determined us...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-09-01
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| Series: | Molbank |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1422-8599/2023/3/M1724 |
| Summary: | A new heteroleptic Cu(I) complex, [Cu(L)(PPh<sub>3</sub>)<sub>2</sub>][BF<sub>4</sub>] (L = 6-(furan-2-yl)-2,2′-bipyridine; PPh<sub>3</sub> = triphenylphosphine), was successfully synthesized and characterized. Its molecular structure was determined using X-ray crystallography, and NMR as well as HR-ESI-MS data confirm the compound’s integrity in solution. The complex exhibits emission solely in the solid state (λ<sub>em</sub> = 576 nm) and demonstrates a photoluminescence quantum yield of 2.5%. |
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| ISSN: | 1422-8599 |