[6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate
A new heteroleptic Cu(I) complex, [Cu(L)(PPh<sub>3</sub>)<sub>2</sub>][BF<sub>4</sub>] (L = 6-(furan-2-yl)-2,2′-bipyridine; PPh<sub>3</sub> = triphenylphosphine), was successfully synthesized and characterized. Its molecular structure was determined us...
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-09-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2023/3/M1724 |
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| author | Panagiotis Kouvatsis Dimitrios Glykos John C. Plakatouras Gerasimos Malandrinos |
| author_facet | Panagiotis Kouvatsis Dimitrios Glykos John C. Plakatouras Gerasimos Malandrinos |
| author_sort | Panagiotis Kouvatsis |
| collection | DOAJ |
| description | A new heteroleptic Cu(I) complex, [Cu(L)(PPh<sub>3</sub>)<sub>2</sub>][BF<sub>4</sub>] (L = 6-(furan-2-yl)-2,2′-bipyridine; PPh<sub>3</sub> = triphenylphosphine), was successfully synthesized and characterized. Its molecular structure was determined using X-ray crystallography, and NMR as well as HR-ESI-MS data confirm the compound’s integrity in solution. The complex exhibits emission solely in the solid state (λ<sub>em</sub> = 576 nm) and demonstrates a photoluminescence quantum yield of 2.5%. |
| first_indexed | 2024-03-10T22:26:09Z |
| format | Article |
| id | doaj.art-71a202d84b614b17852a978d36956f88 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-03-10T22:26:09Z |
| publishDate | 2023-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-71a202d84b614b17852a978d36956f882023-11-19T12:07:12ZengMDPI AGMolbank1422-85992023-09-0120233M172410.3390/M1724[6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) TetrafluoroboratePanagiotis Kouvatsis0Dimitrios Glykos1John C. Plakatouras2Gerasimos Malandrinos3Laboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, GreeceLaboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, GreeceLaboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, GreeceLaboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, GreeceA new heteroleptic Cu(I) complex, [Cu(L)(PPh<sub>3</sub>)<sub>2</sub>][BF<sub>4</sub>] (L = 6-(furan-2-yl)-2,2′-bipyridine; PPh<sub>3</sub> = triphenylphosphine), was successfully synthesized and characterized. Its molecular structure was determined using X-ray crystallography, and NMR as well as HR-ESI-MS data confirm the compound’s integrity in solution. The complex exhibits emission solely in the solid state (λ<sub>em</sub> = 576 nm) and demonstrates a photoluminescence quantum yield of 2.5%.https://www.mdpi.com/1422-8599/2023/3/M1724copper(I) complexphotoluminesceneX-ray diffraction |
| spellingShingle | Panagiotis Kouvatsis Dimitrios Glykos John C. Plakatouras Gerasimos Malandrinos [6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate Molbank copper(I) complex photoluminescene X-ray diffraction |
| title | [6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate |
| title_full | [6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate |
| title_fullStr | [6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate |
| title_full_unstemmed | [6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate |
| title_short | [6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate |
| title_sort | 6 furan 2 yl 2 2 bipyridine bis triphenylphosphine copper i tetrafluoroborate |
| topic | copper(I) complex photoluminescene X-ray diffraction |
| url | https://www.mdpi.com/1422-8599/2023/3/M1724 |
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