On the structure and ultraviolet emission of terbium doped zinc oxide thin films on silicon after high temperature treatment

Terbium (Tb) doped zinc oxide (ZnO) thin films were deposited on Si substrates by magnetron sputtering in an oxygen containing plasma. The Tb doping concentration was varied from 0 to 0.38 at.%. The effect of heat treatment at high temperature on the ultraviolet (UV) emission was studied along with...

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Main Authors: L. Zhang, C.L. Heng, C.N. Zhao, W.Y. Su, Y.K. Gao, P.G. Yin, T.G. Finstad
Format: Article
Language:English
Published: Elsevier 2022-01-01
Series:Results in Physics
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2211379721010913
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author L. Zhang
C.L. Heng
C.N. Zhao
W.Y. Su
Y.K. Gao
P.G. Yin
T.G. Finstad
author_facet L. Zhang
C.L. Heng
C.N. Zhao
W.Y. Su
Y.K. Gao
P.G. Yin
T.G. Finstad
author_sort L. Zhang
collection DOAJ
description Terbium (Tb) doped zinc oxide (ZnO) thin films were deposited on Si substrates by magnetron sputtering in an oxygen containing plasma. The Tb doping concentration was varied from 0 to 0.38 at.%. The effect of heat treatment at high temperature on the ultraviolet (UV) emission was studied along with the structure of the films. Photoluminescence (PL) spectra show that the UV intensity increases much by heat treatment and after 1000 °C annealing the doped films have stronger UV emission than that of an un-doped film. The enhanced UV emission is related to crystallinity improvements of the films. After heat treatment at 1000 °C Zn (Tb) silicates had formed. The film prepared with a Tb concentration of 0.029 at.% showed the best crystallinity and highest UV intensity. Finally, it was shown that the UV PL intensity can be increased further with TiN nanoparticle capping on the surface of the films.
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spelling doaj.art-721d4e385e74414ca622c5db7a5645102022-12-21T18:45:03ZengElsevierResults in Physics2211-37972022-01-0132105121On the structure and ultraviolet emission of terbium doped zinc oxide thin films on silicon after high temperature treatmentL. Zhang0C.L. Heng1C.N. Zhao2W.Y. Su3Y.K. Gao4P.G. Yin5T.G. Finstad6School of Physics, Beijing Institute of Technology, Beijing 100081, PR ChinaSchool of Physics, Beijing Institute of Technology, Beijing 100081, PR China; Corresponding authors.School of Physics, Beijing Institute of Technology, Beijing 100081, PR ChinaSchool of Physics, Beijing Institute of Technology, Beijing 100081, PR ChinaKey Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191, PR ChinaKey Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191, PR ChinaPhysics Department, University of Oslo, PO Box 1048, Blindern, N-0316 Oslo, Norway; Corresponding authors.Terbium (Tb) doped zinc oxide (ZnO) thin films were deposited on Si substrates by magnetron sputtering in an oxygen containing plasma. The Tb doping concentration was varied from 0 to 0.38 at.%. The effect of heat treatment at high temperature on the ultraviolet (UV) emission was studied along with the structure of the films. Photoluminescence (PL) spectra show that the UV intensity increases much by heat treatment and after 1000 °C annealing the doped films have stronger UV emission than that of an un-doped film. The enhanced UV emission is related to crystallinity improvements of the films. After heat treatment at 1000 °C Zn (Tb) silicates had formed. The film prepared with a Tb concentration of 0.029 at.% showed the best crystallinity and highest UV intensity. Finally, it was shown that the UV PL intensity can be increased further with TiN nanoparticle capping on the surface of the films.http://www.sciencedirect.com/science/article/pii/S2211379721010913ZnOThin filmsUV emissionTb dopingTiN nanoparticles
spellingShingle L. Zhang
C.L. Heng
C.N. Zhao
W.Y. Su
Y.K. Gao
P.G. Yin
T.G. Finstad
On the structure and ultraviolet emission of terbium doped zinc oxide thin films on silicon after high temperature treatment
Results in Physics
ZnO
Thin films
UV emission
Tb doping
TiN nanoparticles
title On the structure and ultraviolet emission of terbium doped zinc oxide thin films on silicon after high temperature treatment
title_full On the structure and ultraviolet emission of terbium doped zinc oxide thin films on silicon after high temperature treatment
title_fullStr On the structure and ultraviolet emission of terbium doped zinc oxide thin films on silicon after high temperature treatment
title_full_unstemmed On the structure and ultraviolet emission of terbium doped zinc oxide thin films on silicon after high temperature treatment
title_short On the structure and ultraviolet emission of terbium doped zinc oxide thin films on silicon after high temperature treatment
title_sort on the structure and ultraviolet emission of terbium doped zinc oxide thin films on silicon after high temperature treatment
topic ZnO
Thin films
UV emission
Tb doping
TiN nanoparticles
url http://www.sciencedirect.com/science/article/pii/S2211379721010913
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