Cr(VI) Sorption from Aqueous Solution: A Review

Hexavalent chromium (Cr(VI)) in water systems is a major hazard for living organisms, including humans. The most popular technology currently used to remove Cr(VI) from polluted water is sorption for its effectiveness, ease of use, low cost and environmental friendliness. The electrostatic interacti...

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Main Authors: Angelo Fenti, Simeone Chianese, Pasquale Iovino, Dino Musmarra, Stefano Salvestrini
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/10/18/6477
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author Angelo Fenti
Simeone Chianese
Pasquale Iovino
Dino Musmarra
Stefano Salvestrini
author_facet Angelo Fenti
Simeone Chianese
Pasquale Iovino
Dino Musmarra
Stefano Salvestrini
author_sort Angelo Fenti
collection DOAJ
description Hexavalent chromium (Cr(VI)) in water systems is a major hazard for living organisms, including humans. The most popular technology currently used to remove Cr(VI) from polluted water is sorption for its effectiveness, ease of use, low cost and environmental friendliness. The electrostatic interactions between chromium species and the sorbent matrix are the main determinants of Cr(VI) sorption. The pH plays a central role in the process by affecting chromium speciation and the net charge on sorbent surface. In most cases, Cr(VI) sorption is an endothermic process whose kinetics is satisfactorily described by the pseudo second-order model. A critical survey of the recent literature, however, reveals that the thermodynamic and kinetic parameters reported for Cr(VI) sorption are often incorrect and/or erroneously interpreted.
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spelling doaj.art-721ef1314acf4b94a8f2958eb833bed12023-11-20T14:03:13ZengMDPI AGApplied Sciences2076-34172020-09-011018647710.3390/app10186477Cr(VI) Sorption from Aqueous Solution: A ReviewAngelo Fenti0Simeone Chianese1Pasquale Iovino2Dino Musmarra3Stefano Salvestrini4Department of Engineering, University of Campania “Luigi Vanvitelli”, Via Roma 29, 81031 Aversa (CE), ItalyDepartment of Engineering, University of Campania “Luigi Vanvitelli”, Via Roma 29, 81031 Aversa (CE), ItalyEnvironmental Technologies, University Spin Off of University of Campania “Luigi Vanvitelli”, Department of Environmental, Biological and Pharmaceutical Sciences and Technologies via Vivaldi, 43, 81100 Caserta, ItalyDepartment of Engineering, University of Campania “Luigi Vanvitelli”, Via Roma 29, 81031 Aversa (CE), ItalyEnvironmental Technologies, University Spin Off of University of Campania “Luigi Vanvitelli”, Department of Environmental, Biological and Pharmaceutical Sciences and Technologies via Vivaldi, 43, 81100 Caserta, ItalyHexavalent chromium (Cr(VI)) in water systems is a major hazard for living organisms, including humans. The most popular technology currently used to remove Cr(VI) from polluted water is sorption for its effectiveness, ease of use, low cost and environmental friendliness. The electrostatic interactions between chromium species and the sorbent matrix are the main determinants of Cr(VI) sorption. The pH plays a central role in the process by affecting chromium speciation and the net charge on sorbent surface. In most cases, Cr(VI) sorption is an endothermic process whose kinetics is satisfactorily described by the pseudo second-order model. A critical survey of the recent literature, however, reveals that the thermodynamic and kinetic parameters reported for Cr(VI) sorption are often incorrect and/or erroneously interpreted.https://www.mdpi.com/2076-3417/10/18/6477hexavalent chromiumsorptionsorption isothermsorption kineticspseudo first order modelpseudo second order model
spellingShingle Angelo Fenti
Simeone Chianese
Pasquale Iovino
Dino Musmarra
Stefano Salvestrini
Cr(VI) Sorption from Aqueous Solution: A Review
Applied Sciences
hexavalent chromium
sorption
sorption isotherm
sorption kinetics
pseudo first order model
pseudo second order model
title Cr(VI) Sorption from Aqueous Solution: A Review
title_full Cr(VI) Sorption from Aqueous Solution: A Review
title_fullStr Cr(VI) Sorption from Aqueous Solution: A Review
title_full_unstemmed Cr(VI) Sorption from Aqueous Solution: A Review
title_short Cr(VI) Sorption from Aqueous Solution: A Review
title_sort cr vi sorption from aqueous solution a review
topic hexavalent chromium
sorption
sorption isotherm
sorption kinetics
pseudo first order model
pseudo second order model
url https://www.mdpi.com/2076-3417/10/18/6477
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