Kinetic Study of the Ultrasound Effect on Acid Brown 83 Dye Degradation by Hydrogen Peroxide Oxidation Processes
The effect of ultrasound on the degradation of the dye Acid Brown 83 by seven different degradation methods (blank test using only ultrasound, hydrogen peroxide in a neutral medium, hydrogen peroxide in a sulfuric acid medium and hydrogen peroxide in a sulfuric acid medium in the presence of Fe(II),...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2021-08-01
|
| Series: | ChemEngineering |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2305-7084/5/3/52 |
| _version_ | 1797519833783336960 |
|---|---|
| author | Gerardo León Beatriz Miguel Laura Manzanares María Isabel Saavedra María Amelia Guzmán |
| author_facet | Gerardo León Beatriz Miguel Laura Manzanares María Isabel Saavedra María Amelia Guzmán |
| author_sort | Gerardo León |
| collection | DOAJ |
| description | The effect of ultrasound on the degradation of the dye Acid Brown 83 by seven different degradation methods (blank test using only ultrasound, hydrogen peroxide in a neutral medium, hydrogen peroxide in a sulfuric acid medium and hydrogen peroxide in a sulfuric acid medium in the presence of Fe(II), both without and with ultrasonic irradiation) is studied in this paper. The effectiveness of these methods is compared by analyzing the degradation percentages of the dye and its initial degradation rate. The application of ultrasound leads to a significant increase in the efficiency of any of the degradation method studied. Kinetic study of Acid Brown 83 degradation by the above-mentioned methods is carried out by using four kinetic models (first order, second order, Behnajady and pseudo-first order). The pseudo-first order model is the one that best fits the experimental data in all the used degradation methods. Although when the degradation is performed in the presence of Fe(II), the Behnajady model presents correlation coefficients slightly higher than those of the pseudo-first order, the maximum experimental conversions obtained fit much better in all cases to the pseudo first order model. |
| first_indexed | 2024-03-10T07:48:24Z |
| format | Article |
| id | doaj.art-7225ffc7b6124ad9b4f793d4a15236fa |
| institution | Directory Open Access Journal |
| issn | 2305-7084 |
| language | English |
| last_indexed | 2024-03-10T07:48:24Z |
| publishDate | 2021-08-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | ChemEngineering |
| spelling | doaj.art-7225ffc7b6124ad9b4f793d4a15236fa2023-11-22T12:27:44ZengMDPI AGChemEngineering2305-70842021-08-01535210.3390/chemengineering5030052Kinetic Study of the Ultrasound Effect on Acid Brown 83 Dye Degradation by Hydrogen Peroxide Oxidation ProcessesGerardo León0Beatriz Miguel1Laura Manzanares2María Isabel Saavedra3María Amelia Guzmán4Departamento de Ingeniería Química y Ambiental, Universidad Politécnica de Cartagena, Paseo Alfonso XIII 52, 30206 Cartagena, SpainDepartamento de Ingeniería Química y Ambiental, Universidad Politécnica de Cartagena, Paseo Alfonso XIII 52, 30206 Cartagena, SpainDepartamento de Ingeniería Química y Ambiental, Universidad Politécnica de Cartagena, Paseo Alfonso XIII 52, 30206 Cartagena, SpainDepartamento de Ingeniería Química y Ambiental, Universidad Politécnica de Cartagena, Paseo Alfonso XIII 52, 30206 Cartagena, SpainDepartamento de Ingeniería Química y Ambiental, Universidad Politécnica de Cartagena, Paseo Alfonso XIII 52, 30206 Cartagena, SpainThe effect of ultrasound on the degradation of the dye Acid Brown 83 by seven different degradation methods (blank test using only ultrasound, hydrogen peroxide in a neutral medium, hydrogen peroxide in a sulfuric acid medium and hydrogen peroxide in a sulfuric acid medium in the presence of Fe(II), both without and with ultrasonic irradiation) is studied in this paper. The effectiveness of these methods is compared by analyzing the degradation percentages of the dye and its initial degradation rate. The application of ultrasound leads to a significant increase in the efficiency of any of the degradation method studied. Kinetic study of Acid Brown 83 degradation by the above-mentioned methods is carried out by using four kinetic models (first order, second order, Behnajady and pseudo-first order). The pseudo-first order model is the one that best fits the experimental data in all the used degradation methods. Although when the degradation is performed in the presence of Fe(II), the Behnajady model presents correlation coefficients slightly higher than those of the pseudo-first order, the maximum experimental conversions obtained fit much better in all cases to the pseudo first order model.https://www.mdpi.com/2305-7084/5/3/52dye degradationultrasound effecthydrogen peroxideFe(II)kinetics |
| spellingShingle | Gerardo León Beatriz Miguel Laura Manzanares María Isabel Saavedra María Amelia Guzmán Kinetic Study of the Ultrasound Effect on Acid Brown 83 Dye Degradation by Hydrogen Peroxide Oxidation Processes ChemEngineering dye degradation ultrasound effect hydrogen peroxide Fe(II) kinetics |
| title | Kinetic Study of the Ultrasound Effect on Acid Brown 83 Dye Degradation by Hydrogen Peroxide Oxidation Processes |
| title_full | Kinetic Study of the Ultrasound Effect on Acid Brown 83 Dye Degradation by Hydrogen Peroxide Oxidation Processes |
| title_fullStr | Kinetic Study of the Ultrasound Effect on Acid Brown 83 Dye Degradation by Hydrogen Peroxide Oxidation Processes |
| title_full_unstemmed | Kinetic Study of the Ultrasound Effect on Acid Brown 83 Dye Degradation by Hydrogen Peroxide Oxidation Processes |
| title_short | Kinetic Study of the Ultrasound Effect on Acid Brown 83 Dye Degradation by Hydrogen Peroxide Oxidation Processes |
| title_sort | kinetic study of the ultrasound effect on acid brown 83 dye degradation by hydrogen peroxide oxidation processes |
| topic | dye degradation ultrasound effect hydrogen peroxide Fe(II) kinetics |
| url | https://www.mdpi.com/2305-7084/5/3/52 |
| work_keys_str_mv | AT gerardoleon kineticstudyoftheultrasoundeffectonacidbrown83dyedegradationbyhydrogenperoxideoxidationprocesses AT beatrizmiguel kineticstudyoftheultrasoundeffectonacidbrown83dyedegradationbyhydrogenperoxideoxidationprocesses AT lauramanzanares kineticstudyoftheultrasoundeffectonacidbrown83dyedegradationbyhydrogenperoxideoxidationprocesses AT mariaisabelsaavedra kineticstudyoftheultrasoundeffectonacidbrown83dyedegradationbyhydrogenperoxideoxidationprocesses AT mariaameliaguzman kineticstudyoftheultrasoundeffectonacidbrown83dyedegradationbyhydrogenperoxideoxidationprocesses |