Water sorption behaviour of commercial furcellaran

Water sorption isotherms are important tool for designing the technological processes and predicting stability and shelf life of food. The aim of the work was to determine the water sorption isotherms of commercial furcellaran at different temperatures (20, 35 and 50 °C) using a gravimetric method u...

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Main Authors: Kairit Eha, Aleksei Kaleda, Anne Menert, Katrin Laos
Format: Article
Language:English
Published: Elsevier 2022-10-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844022023441
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author Kairit Eha
Aleksei Kaleda
Anne Menert
Katrin Laos
author_facet Kairit Eha
Aleksei Kaleda
Anne Menert
Katrin Laos
author_sort Kairit Eha
collection DOAJ
description Water sorption isotherms are important tool for designing the technological processes and predicting stability and shelf life of food. The aim of the work was to determine the water sorption isotherms of commercial furcellaran at different temperatures (20, 35 and 50 °C) using a gravimetric method under different levels of relative humidity (19–95%). The experimental data obtained have been interpreted in the terms of various isotherm models and it was found that the best results were obtained with the Peleg model (P < 2.1%; RSME <0.01; R2 = 1.00). The obtained isotherms followed the type II pattern and, in all cases, the sorption capacity increased with increasing water activity and decreased with increasing temperature. The maximum net isosteric heat for adsorption and desorption was 938.9 and 988.6 J g −1, respectively, at an equilibrium moisture content of 0.05 gw gdb−1. The net isosteric heat of sorption decreased exponentially with increasing moisture content and approached zero at 0.26 gw gdb−1 for adsorption and 0.32 gw gdb−1 for desorption. The developed mathematical relationships can be used to optimize the drying processes and storage conditions of furcellaran.
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spelling doaj.art-723ef14549ad41189a185d08938d64862022-12-22T03:27:36ZengElsevierHeliyon2405-84402022-10-01810e11056Water sorption behaviour of commercial furcellaranKairit Eha0Aleksei Kaleda1Anne Menert2Katrin Laos3Department of Chemistry and Biotechnology, Tallinn University of Technology, Akadeemia tee 15, 12618 Tallinn, EstoniaCenter of Food and Fermentation Technologies, Akadeemia tee 15A, 12618 Tallinn, EstoniaInstitute of Molecular and Cell Biology, University of Tartu, Ülikooli 18, 50090 Tartu, EstoniaDepartment of Chemistry and Biotechnology, Tallinn University of Technology, Akadeemia tee 15, 12618 Tallinn, EstoniaWater sorption isotherms are important tool for designing the technological processes and predicting stability and shelf life of food. The aim of the work was to determine the water sorption isotherms of commercial furcellaran at different temperatures (20, 35 and 50 °C) using a gravimetric method under different levels of relative humidity (19–95%). The experimental data obtained have been interpreted in the terms of various isotherm models and it was found that the best results were obtained with the Peleg model (P < 2.1%; RSME <0.01; R2 = 1.00). The obtained isotherms followed the type II pattern and, in all cases, the sorption capacity increased with increasing water activity and decreased with increasing temperature. The maximum net isosteric heat for adsorption and desorption was 938.9 and 988.6 J g −1, respectively, at an equilibrium moisture content of 0.05 gw gdb−1. The net isosteric heat of sorption decreased exponentially with increasing moisture content and approached zero at 0.26 gw gdb−1 for adsorption and 0.32 gw gdb−1 for desorption. The developed mathematical relationships can be used to optimize the drying processes and storage conditions of furcellaran.http://www.sciencedirect.com/science/article/pii/S2405844022023441FurcellaranSorption isothermModellingNet isosteric heat of sorption
spellingShingle Kairit Eha
Aleksei Kaleda
Anne Menert
Katrin Laos
Water sorption behaviour of commercial furcellaran
Heliyon
Furcellaran
Sorption isotherm
Modelling
Net isosteric heat of sorption
title Water sorption behaviour of commercial furcellaran
title_full Water sorption behaviour of commercial furcellaran
title_fullStr Water sorption behaviour of commercial furcellaran
title_full_unstemmed Water sorption behaviour of commercial furcellaran
title_short Water sorption behaviour of commercial furcellaran
title_sort water sorption behaviour of commercial furcellaran
topic Furcellaran
Sorption isotherm
Modelling
Net isosteric heat of sorption
url http://www.sciencedirect.com/science/article/pii/S2405844022023441
work_keys_str_mv AT kairiteha watersorptionbehaviourofcommercialfurcellaran
AT alekseikaleda watersorptionbehaviourofcommercialfurcellaran
AT annemenert watersorptionbehaviourofcommercialfurcellaran
AT katrinlaos watersorptionbehaviourofcommercialfurcellaran