Preparation of a new weakly acidic cation exchanger and the evaluation of cations by non-suppressed ion chromatography(新型弱酸性阳离子色谱柱的制备及非抑制型离子色谱法电导检测)
制备出一种新型弱酸性非抑制电导检测阳离子色谱固定相,并通过对色谱条件的摸索选择,成功实现了常见一价、二价阳离子的分离检测,以及过渡金属离子Ni2+,Mn2+的分离检测.选用甲基磺酸溶液(2 mmol • L-1)和草酸(0.5 mmol• L-1)的混合液作为流动相,一步分离并测得了Li+、Na+、NH4+、K+、Mg2+、Ca2+ 6种阳离子的检测限和线性范围.选用酒石酸(2 mmol• L-1)和草酸(1 mmol • L-1)的混合溶液为流动相,成功分离并测得了过渡金属离子Ni2+,Mn2+的检测限和线性范围.用于雨水分析,实验结果良好,应用效果令人满意....
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Format: | Article |
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Zhejiang University Press
2007-03-01
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Series: | Zhejiang Daxue xuebao. Lixue ban |
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Online Access: | https://doi.org/zjup/1008-9497.2007.34.2.210-213 |
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author | GUOYan-ru(郭龑茹) ZHUYan(朱岩) YEMing-li(叶明立) |
author_facet | GUOYan-ru(郭龑茹) ZHUYan(朱岩) YEMing-li(叶明立) |
author_sort | GUOYan-ru(郭龑茹) |
collection | DOAJ |
description | 制备出一种新型弱酸性非抑制电导检测阳离子色谱固定相,并通过对色谱条件的摸索选择,成功实现了常见一价、二价阳离子的分离检测,以及过渡金属离子Ni2+,Mn2+的分离检测.选用甲基磺酸溶液(2 mmol • L-1)和草酸(0.5 mmol• L-1)的混合液作为流动相,一步分离并测得了Li+、Na+、NH4+、K+、Mg2+、Ca2+ 6种阳离子的检测限和线性范围.选用酒石酸(2 mmol• L-1)和草酸(1 mmol • L-1)的混合溶液为流动相,成功分离并测得了过渡金属离子Ni2+,Mn2+的检测限和线性范围.用于雨水分析,实验结果良好,应用效果令人满意. |
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language | zho |
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spelling | doaj.art-7255b3bb3fb84899b6204ab997cfe81e2024-03-29T01:58:24ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972007-03-01342210213zjup/1008-9497.2007.34.2.210-213Preparation of a new weakly acidic cation exchanger and the evaluation of cations by non-suppressed ion chromatography(新型弱酸性阳离子色谱柱的制备及非抑制型离子色谱法电导检测)GUOYan-ru(郭龑茹)0ZHUYan(朱岩)1YEMing-li(叶明立)2Department of Chemistry, Zhejiang University, Hangzhou 310028, China(浙江大学化学系,浙江 杭州 310028)Department of Chemistry, Zhejiang University, Hangzhou 310028, China(浙江大学化学系,浙江 杭州 310028)Department of Chemistry, Zhejiang University, Hangzhou 310028, China(浙江大学化学系,浙江 杭州 310028)制备出一种新型弱酸性非抑制电导检测阳离子色谱固定相,并通过对色谱条件的摸索选择,成功实现了常见一价、二价阳离子的分离检测,以及过渡金属离子Ni2+,Mn2+的分离检测.选用甲基磺酸溶液(2 mmol • L-1)和草酸(0.5 mmol• L-1)的混合液作为流动相,一步分离并测得了Li+、Na+、NH4+、K+、Mg2+、Ca2+ 6种阳离子的检测限和线性范围.选用酒石酸(2 mmol• L-1)和草酸(1 mmol • L-1)的混合溶液为流动相,成功分离并测得了过渡金属离子Ni2+,Mn2+的检测限和线性范围.用于雨水分析,实验结果良好,应用效果令人满意.https://doi.org/zjup/1008-9497.2007.34.2.210-213非抑制电导检测离子色谱固定相 |
spellingShingle | GUOYan-ru(郭龑茹) ZHUYan(朱岩) YEMing-li(叶明立) Preparation of a new weakly acidic cation exchanger and the evaluation of cations by non-suppressed ion chromatography(新型弱酸性阳离子色谱柱的制备及非抑制型离子色谱法电导检测) Zhejiang Daxue xuebao. Lixue ban 非抑制 电导检测 离子色谱 固定相 |
title | Preparation of a new weakly acidic cation exchanger and the evaluation of cations by non-suppressed ion chromatography(新型弱酸性阳离子色谱柱的制备及非抑制型离子色谱法电导检测) |
title_full | Preparation of a new weakly acidic cation exchanger and the evaluation of cations by non-suppressed ion chromatography(新型弱酸性阳离子色谱柱的制备及非抑制型离子色谱法电导检测) |
title_fullStr | Preparation of a new weakly acidic cation exchanger and the evaluation of cations by non-suppressed ion chromatography(新型弱酸性阳离子色谱柱的制备及非抑制型离子色谱法电导检测) |
title_full_unstemmed | Preparation of a new weakly acidic cation exchanger and the evaluation of cations by non-suppressed ion chromatography(新型弱酸性阳离子色谱柱的制备及非抑制型离子色谱法电导检测) |
title_short | Preparation of a new weakly acidic cation exchanger and the evaluation of cations by non-suppressed ion chromatography(新型弱酸性阳离子色谱柱的制备及非抑制型离子色谱法电导检测) |
title_sort | preparation of a new weakly acidic cation exchanger and the evaluation of cations by non suppressed ion chromatography 新型弱酸性阳离子色谱柱的制备及非抑制型离子色谱法电导检测 |
topic | 非抑制 电导检测 离子色谱 固定相 |
url | https://doi.org/zjup/1008-9497.2007.34.2.210-213 |
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