The Kinetic Parameters of Carbonaceous Materials Activated with Potassium Hydroxide

On the basis of micropore formation in carbonaceous materials, the activation energy for the potassium hydroxide activation of Chinese petroleum coke and coal has been deduced theoretically as dB 0 /dt = A exp(–E a ∈/RT), where ∈ is the formation energy for the metastable solid formed at the activat...

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Main Authors: Zou Yong, Han Bu-Xing
Format: Article
Language:English
Published: SAGE Publications 2000-07-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263617001493639
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author Zou Yong
Han Bu-Xing
author_facet Zou Yong
Han Bu-Xing
author_sort Zou Yong
collection DOAJ
description On the basis of micropore formation in carbonaceous materials, the activation energy for the potassium hydroxide activation of Chinese petroleum coke and coal has been deduced theoretically as dB 0 /dt = A exp(–E a ∈/RT), where ∈ is the formation energy for the metastable solid formed at the activation temperature. The kinetic parameters (frequency factor, A, and apparent activation energy, E a ) were calculated from this equation as being 5.319 mg/(g min), 36.51 kJ/mol and 6.64 mg/(g min), 49.46 kJ/mol, respectively, for the two carbonaceous materials studied.
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spelling doaj.art-72586329e7654a728fc1ef222c67337e2024-03-02T00:30:35ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382000-07-011810.1260/0263617001493639The Kinetic Parameters of Carbonaceous Materials Activated with Potassium HydroxideZou YongHan Bu-XingOn the basis of micropore formation in carbonaceous materials, the activation energy for the potassium hydroxide activation of Chinese petroleum coke and coal has been deduced theoretically as dB 0 /dt = A exp(–E a ∈/RT), where ∈ is the formation energy for the metastable solid formed at the activation temperature. The kinetic parameters (frequency factor, A, and apparent activation energy, E a ) were calculated from this equation as being 5.319 mg/(g min), 36.51 kJ/mol and 6.64 mg/(g min), 49.46 kJ/mol, respectively, for the two carbonaceous materials studied.https://doi.org/10.1260/0263617001493639
spellingShingle Zou Yong
Han Bu-Xing
The Kinetic Parameters of Carbonaceous Materials Activated with Potassium Hydroxide
Adsorption Science & Technology
title The Kinetic Parameters of Carbonaceous Materials Activated with Potassium Hydroxide
title_full The Kinetic Parameters of Carbonaceous Materials Activated with Potassium Hydroxide
title_fullStr The Kinetic Parameters of Carbonaceous Materials Activated with Potassium Hydroxide
title_full_unstemmed The Kinetic Parameters of Carbonaceous Materials Activated with Potassium Hydroxide
title_short The Kinetic Parameters of Carbonaceous Materials Activated with Potassium Hydroxide
title_sort kinetic parameters of carbonaceous materials activated with potassium hydroxide
url https://doi.org/10.1260/0263617001493639
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