Tris{N-[(anthracen-9-yl)methyleneamino]thioureato}cobalt(III) tetrahydrate
In the title complex, [Co(C16H12N3S)3]·4H2O, the central CoIII atom is in a distorted octahedral coordination environment. There are three N-[(anthracen-9-yl)methyleneamino]thioureate ligands coordinated to the CoIII atom via three imine N and three thioamide S atoms. The Co—S and...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808031425 |
| _version_ | 1823962029312966656 |
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| author | Jianying Zhao Yu Zhang |
| author_facet | Jianying Zhao Yu Zhang |
| author_sort | Jianying Zhao |
| collection | DOAJ |
| description | In the title complex, [Co(C16H12N3S)3]·4H2O, the central CoIII atom is in a distorted octahedral coordination environment. There are three N-[(anthracen-9-yl)methyleneamino]thioureate ligands coordinated to the CoIII atom via three imine N and three thioamide S atoms. The Co—S and Co—N bond distances are in expected ranges [2.2194 (8)—2.2545 (8) and 1.926 (2)—1.985 (2)Å, respectively]. The endocyclic S—Co—N bond angles in the five-membered chelate rings range from 82.91 (7) to 85.33 (7)°. The structure contains four water molecules which are disordered over 12 sites and link the complex molecules into a three-dimensional network through N—H...O, O—H...O, O—H...N, and O—H...S hydrogen bonds. |
| first_indexed | 2024-12-17T17:12:48Z |
| format | Article |
| id | doaj.art-725c38dbebf34d35b037f0e1f2171e3b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-17T17:12:48Z |
| publishDate | 2008-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-725c38dbebf34d35b037f0e1f2171e3b2022-12-21T21:40:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1355m135610.1107/S1600536808031425Tris{N-[(anthracen-9-yl)methyleneamino]thioureato}cobalt(III) tetrahydrateJianying ZhaoYu ZhangIn the title complex, [Co(C16H12N3S)3]·4H2O, the central CoIII atom is in a distorted octahedral coordination environment. There are three N-[(anthracen-9-yl)methyleneamino]thioureate ligands coordinated to the CoIII atom via three imine N and three thioamide S atoms. The Co—S and Co—N bond distances are in expected ranges [2.2194 (8)—2.2545 (8) and 1.926 (2)—1.985 (2)Å, respectively]. The endocyclic S—Co—N bond angles in the five-membered chelate rings range from 82.91 (7) to 85.33 (7)°. The structure contains four water molecules which are disordered over 12 sites and link the complex molecules into a three-dimensional network through N—H...O, O—H...O, O—H...N, and O—H...S hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536808031425 |
| spellingShingle | Jianying Zhao Yu Zhang Tris{N-[(anthracen-9-yl)methyleneamino]thioureato}cobalt(III) tetrahydrate Acta Crystallographica Section E |
| title | Tris{N-[(anthracen-9-yl)methyleneamino]thioureato}cobalt(III) tetrahydrate |
| title_full | Tris{N-[(anthracen-9-yl)methyleneamino]thioureato}cobalt(III) tetrahydrate |
| title_fullStr | Tris{N-[(anthracen-9-yl)methyleneamino]thioureato}cobalt(III) tetrahydrate |
| title_full_unstemmed | Tris{N-[(anthracen-9-yl)methyleneamino]thioureato}cobalt(III) tetrahydrate |
| title_short | Tris{N-[(anthracen-9-yl)methyleneamino]thioureato}cobalt(III) tetrahydrate |
| title_sort | tris n anthracen 9 yl methyleneamino thioureato cobalt iii tetrahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808031425 |
| work_keys_str_mv | AT jianyingzhao trisnanthracen9ylmethyleneaminothioureatocobaltiiitetrahydrate AT yuzhang trisnanthracen9ylmethyleneaminothioureatocobaltiiitetrahydrate |