Development of SOFC Interconnects Based on Industrial Steels with Oxide Coating

This work suggests a method for obtaining heat-resistant protective coatings for 08Kh17T stainless steel that can be used as interconnect material for solid oxide fuel cells. The suggested approach is based on the layer-by-layer precipitation of nickel, cobalt, and manganese, followed by heat treatm...

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Main Authors: Andrey Bushuev, Oleg El’kin, Ivan Tolstobrov, Yulia Chetvertnykh, Mark Bobro, Nailya Saetova, Anton Kuzmin
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/16/3/1237
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author Andrey Bushuev
Oleg El’kin
Ivan Tolstobrov
Yulia Chetvertnykh
Mark Bobro
Nailya Saetova
Anton Kuzmin
author_facet Andrey Bushuev
Oleg El’kin
Ivan Tolstobrov
Yulia Chetvertnykh
Mark Bobro
Nailya Saetova
Anton Kuzmin
author_sort Andrey Bushuev
collection DOAJ
description This work suggests a method for obtaining heat-resistant protective coatings for 08Kh17T stainless steel that can be used as interconnect material for solid oxide fuel cells. The suggested approach is based on the layer-by-layer precipitation of nickel, cobalt, and manganese, followed by heat treatment in a vacuum and oxidizing atmosphere. XRD results show that the coatings consist of a mixture of metal oxides and compounds with a spinel structure. The obtained coatings demonstrate high resistance to high-temperature oxidation for 100 h. The coating with the ratio of the thicknesses of the cobalt and manganese layers of 1.5/0.5 μm obtained by electrodeposition is the most stable. The specific electrical resistance of this coating is 3.50·10<sup>−3</sup> Ω·cm<sup>2</sup> after 100 h of exposure at 850 °C, which meets the requirements for SOFC interconnect materials.
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spelling doaj.art-725c9001e24245eabcaaa628f0ad40ce2023-11-16T16:34:38ZengMDPI AGEnergies1996-10732023-01-01163123710.3390/en16031237Development of SOFC Interconnects Based on Industrial Steels with Oxide CoatingAndrey Bushuev0Oleg El’kin1Ivan Tolstobrov2Yulia Chetvertnykh3Mark Bobro4Nailya Saetova5Anton Kuzmin6Institute of Chemistry and Ecology, Vyatka State University, 36 Moskovskaya St., 610000 Kirov, RussiaInstitute of Chemistry and Ecology, Vyatka State University, 36 Moskovskaya St., 610000 Kirov, RussiaInstitute of Chemistry and Ecology, Vyatka State University, 36 Moskovskaya St., 610000 Kirov, RussiaInstitute of Chemistry and Ecology, Vyatka State University, 36 Moskovskaya St., 610000 Kirov, RussiaInstitute of Chemistry and Ecology, Vyatka State University, 36 Moskovskaya St., 610000 Kirov, RussiaInstitute of Chemistry and Ecology, Vyatka State University, 36 Moskovskaya St., 610000 Kirov, RussiaInstitute of Chemistry and Ecology, Vyatka State University, 36 Moskovskaya St., 610000 Kirov, RussiaThis work suggests a method for obtaining heat-resistant protective coatings for 08Kh17T stainless steel that can be used as interconnect material for solid oxide fuel cells. The suggested approach is based on the layer-by-layer precipitation of nickel, cobalt, and manganese, followed by heat treatment in a vacuum and oxidizing atmosphere. XRD results show that the coatings consist of a mixture of metal oxides and compounds with a spinel structure. The obtained coatings demonstrate high resistance to high-temperature oxidation for 100 h. The coating with the ratio of the thicknesses of the cobalt and manganese layers of 1.5/0.5 μm obtained by electrodeposition is the most stable. The specific electrical resistance of this coating is 3.50·10<sup>−3</sup> Ω·cm<sup>2</sup> after 100 h of exposure at 850 °C, which meets the requirements for SOFC interconnect materials.https://www.mdpi.com/1996-1073/16/3/1237solid oxide fuel cellinterconnectprotective coatingelectrodepositionoxide
spellingShingle Andrey Bushuev
Oleg El’kin
Ivan Tolstobrov
Yulia Chetvertnykh
Mark Bobro
Nailya Saetova
Anton Kuzmin
Development of SOFC Interconnects Based on Industrial Steels with Oxide Coating
Energies
solid oxide fuel cell
interconnect
protective coating
electrodeposition
oxide
title Development of SOFC Interconnects Based on Industrial Steels with Oxide Coating
title_full Development of SOFC Interconnects Based on Industrial Steels with Oxide Coating
title_fullStr Development of SOFC Interconnects Based on Industrial Steels with Oxide Coating
title_full_unstemmed Development of SOFC Interconnects Based on Industrial Steels with Oxide Coating
title_short Development of SOFC Interconnects Based on Industrial Steels with Oxide Coating
title_sort development of sofc interconnects based on industrial steels with oxide coating
topic solid oxide fuel cell
interconnect
protective coating
electrodeposition
oxide
url https://www.mdpi.com/1996-1073/16/3/1237
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AT yuliachetvertnykh developmentofsofcinterconnectsbasedonindustrialsteelswithoxidecoating
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AT nailyasaetova developmentofsofcinterconnectsbasedonindustrialsteelswithoxidecoating
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