Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate
Synthesis biopolymer of sulfonated copolymer eugenol-diallyl phthalate (PEGDAF), its characterization, and study of proton exchange polymer membrane properties had been done. This synthesis was conducted by eugenol and diallyl phthalate reaction to form PEGDAF, which is sulfonated using sulfuric aci...
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| Format: | Article |
| Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2020-11-01
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| Series: | Indonesian Journal of Chemistry |
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| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/55353 |
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| author | Ngadiwiyana Ngadiwiyana Nor Basid Adiwibawa Prasetya Gunawan Gunawan Tutuk Djoko Kusworo Heru Susanto |
| author_facet | Ngadiwiyana Ngadiwiyana Nor Basid Adiwibawa Prasetya Gunawan Gunawan Tutuk Djoko Kusworo Heru Susanto |
| author_sort | Ngadiwiyana Ngadiwiyana |
| collection | DOAJ |
| description | Synthesis biopolymer of sulfonated copolymer eugenol-diallyl phthalate (PEGDAF), its characterization, and study of proton exchange polymer membrane properties had been done. This synthesis was conducted by eugenol and diallyl phthalate reaction to form PEGDAF, which is sulfonated using sulfuric acid. In addition, the functional groups of the PEGDAF and its sulfonated form were analyzed using FT-IR. Furthermore, the polymer properties were determined by measuring values of sulfonation degree, cation exchange capacity, proton conductivity, and water uptake. FT-IR spectra showed that the vinyl group had been added to the process of PEGDAF formation, while spectra deconvolution was used to confirm the occurrence of sulfonation reaction. The sulfonation of PEGDAF in 2 h optimum reaction time produces a black solid with a melting point of 133 °C in 16.55% yield. The highest proton conductivity, cation exchange capacity (CEC), and water uptake were 8.334 × 10–6 S cm–1, 0.44 meq/g, and 73.0%, respectively. |
| first_indexed | 2024-12-20T21:12:08Z |
| format | Article |
| id | doaj.art-729c7b47a7f047e683c8bd70cec9409d |
| institution | Directory Open Access Journal |
| issn | 1411-9420 2460-1578 |
| language | English |
| last_indexed | 2024-12-20T21:12:08Z |
| publishDate | 2020-11-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj.art-729c7b47a7f047e683c8bd70cec9409d2022-12-21T19:26:30ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782020-11-0121116817810.22146/ijc.5535328613Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl PhthalateNgadiwiyana Ngadiwiyana0Nor Basid Adiwibawa Prasetya1Gunawan Gunawan2Tutuk Djoko Kusworo3Heru Susanto4Department of Chemistry, Faculty of Science and Mathematics, Universitas Diponegoro, Jl. Prof. Soedharto SH, Tembalang, Semarang 50275, IndonesiaDepartment of Chemistry, Faculty of Science and Mathematics, Universitas Diponegoro, Jl. Prof. Soedharto SH, Tembalang, Semarang 50275, IndonesiaDepartment of Chemistry, Faculty of Science and Mathematics, Universitas Diponegoro, Jl. Prof. Soedharto SH, Tembalang, Semarang 50275, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro, Jl. Prof. Soedharto SH, Tembalang, Semarang 50275, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro, Jl. Prof. Soedharto SH, Tembalang, Semarang 50275, IndonesiaSynthesis biopolymer of sulfonated copolymer eugenol-diallyl phthalate (PEGDAF), its characterization, and study of proton exchange polymer membrane properties had been done. This synthesis was conducted by eugenol and diallyl phthalate reaction to form PEGDAF, which is sulfonated using sulfuric acid. In addition, the functional groups of the PEGDAF and its sulfonated form were analyzed using FT-IR. Furthermore, the polymer properties were determined by measuring values of sulfonation degree, cation exchange capacity, proton conductivity, and water uptake. FT-IR spectra showed that the vinyl group had been added to the process of PEGDAF formation, while spectra deconvolution was used to confirm the occurrence of sulfonation reaction. The sulfonation of PEGDAF in 2 h optimum reaction time produces a black solid with a melting point of 133 °C in 16.55% yield. The highest proton conductivity, cation exchange capacity (CEC), and water uptake were 8.334 × 10–6 S cm–1, 0.44 meq/g, and 73.0%, respectively.https://jurnal.ugm.ac.id/ijc/article/view/55353eugenoldiallyl phthalatemembraneproton exchangepolymer |
| spellingShingle | Ngadiwiyana Ngadiwiyana Nor Basid Adiwibawa Prasetya Gunawan Gunawan Tutuk Djoko Kusworo Heru Susanto Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate Indonesian Journal of Chemistry eugenol diallyl phthalate membrane proton exchange polymer |
| title | Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate |
| title_full | Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate |
| title_fullStr | Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate |
| title_full_unstemmed | Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate |
| title_short | Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate |
| title_sort | synthesis characterization and study of proton exchange polymer membrane properties of sulfonated copolymer eugenol diallyl phthalate |
| topic | eugenol diallyl phthalate membrane proton exchange polymer |
| url | https://jurnal.ugm.ac.id/ijc/article/view/55353 |
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