Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN2)ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate
In the title salt, [Ni(C12H14N6O)2](CF3SO3)2·2H2O, the NiII cation is located on an inversion centre and is coordinated by six N atoms from two tridentate 1-methoxy-2,2,2-tris(pyrazol-1-yl)ethane ligands in a distorted octahedral geometry. The Ni—N distances range from 2.0594&...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813024252 |
| _version_ | 1818322405737627648 |
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| author | Ganna Lyubartseva Sean Parkin Uma Prasad Mallik |
| author_facet | Ganna Lyubartseva Sean Parkin Uma Prasad Mallik |
| author_sort | Ganna Lyubartseva |
| collection | DOAJ |
| description | In the title salt, [Ni(C12H14N6O)2](CF3SO3)2·2H2O, the NiII cation is located on an inversion centre and is coordinated by six N atoms from two tridentate 1-methoxy-2,2,2-tris(pyrazol-1-yl)ethane ligands in a distorted octahedral geometry. The Ni—N distances range from 2.0594 (12) to 2.0664 (12) Å, intra-ligand N—Ni—N angles range from 84.59 (5) to 86.06 (5)°, and adjacent inter-ligand N—Ni—N angles range between 93.94 (5) and 95.41 (5)°. In the crystal, inversion-related pyrazole rings are π–π stacked, with an interplanar spacing of 3.4494 (18) Å, forming chains that propagate parallel to the a-axis direction. Intermolecular O—H...O hydrogen bonds are present between water molecules and trifluoromethanesulfonate anions. |
| first_indexed | 2024-12-13T10:56:17Z |
| format | Article |
| id | doaj.art-72aeac19dfff4b0db4ce594de30a5448 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:56:17Z |
| publishDate | 2013-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-72aeac19dfff4b0db4ce594de30a54482022-12-21T23:49:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-10-016910m532m53310.1107/S1600536813024252Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN2)ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrateGanna LyubartsevaSean ParkinUma Prasad MallikIn the title salt, [Ni(C12H14N6O)2](CF3SO3)2·2H2O, the NiII cation is located on an inversion centre and is coordinated by six N atoms from two tridentate 1-methoxy-2,2,2-tris(pyrazol-1-yl)ethane ligands in a distorted octahedral geometry. The Ni—N distances range from 2.0594 (12) to 2.0664 (12) Å, intra-ligand N—Ni—N angles range from 84.59 (5) to 86.06 (5)°, and adjacent inter-ligand N—Ni—N angles range between 93.94 (5) and 95.41 (5)°. In the crystal, inversion-related pyrazole rings are π–π stacked, with an interplanar spacing of 3.4494 (18) Å, forming chains that propagate parallel to the a-axis direction. Intermolecular O—H...O hydrogen bonds are present between water molecules and trifluoromethanesulfonate anions.http://scripts.iucr.org/cgi-bin/paper?S1600536813024252 |
| spellingShingle | Ganna Lyubartseva Sean Parkin Uma Prasad Mallik Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN2)ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate Acta Crystallographica Section E |
| title | Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN2)ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate |
| title_full | Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN2)ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate |
| title_fullStr | Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN2)ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate |
| title_full_unstemmed | Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN2)ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate |
| title_short | Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN2)ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate |
| title_sort | bis 1 methoxy 2 2 2 tris pyrazol 1 yl 954 n2 ethane nickel ii bis trifluoromethanesulfonate dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813024252 |
| work_keys_str_mv | AT gannalyubartseva bis1methoxy222trispyrazol1yl954n2ethanenickeliibistrifluoromethanesulfonatedihydrate AT seanparkin bis1methoxy222trispyrazol1yl954n2ethanenickeliibistrifluoromethanesulfonatedihydrate AT umaprasadmallik bis1methoxy222trispyrazol1yl954n2ethanenickeliibistrifluoromethanesulfonatedihydrate |