Bis(μ2-2-amino-5-nitrobenzoato)bis(2-amino-5-nitrobenzoato)octabutyldi-μ3-oxido-tetratin(IV)
In the title complex, [Sn4(C4H9)8(C7H5N2O4)4O2], all four SnIV atoms are five-coordinated with distorted trigonal–bipyramidal SnC2O3 geometries. Two SnIV atoms are coordinated by two butyl groups, one benzoate O atom and two bridging O atoms, whereas the other two SnIV atoms are coordi...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811028212 |
| _version_ | 1819294651294679040 |
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| author | Yip-Foo Win Chen-Shang Choong Siang-Guan Teoh Chin Sing Yeap Hoong-Kun Fun |
| author_facet | Yip-Foo Win Chen-Shang Choong Siang-Guan Teoh Chin Sing Yeap Hoong-Kun Fun |
| author_sort | Yip-Foo Win |
| collection | DOAJ |
| description | In the title complex, [Sn4(C4H9)8(C7H5N2O4)4O2], all four SnIV atoms are five-coordinated with distorted trigonal–bipyramidal SnC2O3 geometries. Two SnIV atoms are coordinated by two butyl groups, one benzoate O atom and two bridging O atoms, whereas the other two SnIV atoms are coordinated by two butyl groups, two benzoate O atoms and a bridging O atom. All the butyl groups are equatorial with respect to the SnO3 trigonal plane. In the crystal, molecules are linked into a two-dimensional layer parallel to the ab plane by intermolecular N—H...O and C—H...O hydrogen bonds and further stabilized by a π–π interaction [centroid–centroid distance = 3.6489 (11) Å]. Intramolecular N—H...O and C—H...O hydrogen bonds stabilize the molecular structure. Two of the butyl groups are each disordered over two sets of sites with site-occupancy ratios of 0.510 (4):0.490 (4) and 0.860 (5):0.140 (5). |
| first_indexed | 2024-12-24T04:29:42Z |
| format | Article |
| id | doaj.art-72f90461af104032bec0e69cf4df65cd |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T04:29:42Z |
| publishDate | 2011-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-72f90461af104032bec0e69cf4df65cd2022-12-21T17:15:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1114m111510.1107/S1600536811028212Bis(μ2-2-amino-5-nitrobenzoato)bis(2-amino-5-nitrobenzoato)octabutyldi-μ3-oxido-tetratin(IV)Yip-Foo WinChen-Shang ChoongSiang-Guan TeohChin Sing YeapHoong-Kun FunIn the title complex, [Sn4(C4H9)8(C7H5N2O4)4O2], all four SnIV atoms are five-coordinated with distorted trigonal–bipyramidal SnC2O3 geometries. Two SnIV atoms are coordinated by two butyl groups, one benzoate O atom and two bridging O atoms, whereas the other two SnIV atoms are coordinated by two butyl groups, two benzoate O atoms and a bridging O atom. All the butyl groups are equatorial with respect to the SnO3 trigonal plane. In the crystal, molecules are linked into a two-dimensional layer parallel to the ab plane by intermolecular N—H...O and C—H...O hydrogen bonds and further stabilized by a π–π interaction [centroid–centroid distance = 3.6489 (11) Å]. Intramolecular N—H...O and C—H...O hydrogen bonds stabilize the molecular structure. Two of the butyl groups are each disordered over two sets of sites with site-occupancy ratios of 0.510 (4):0.490 (4) and 0.860 (5):0.140 (5).http://scripts.iucr.org/cgi-bin/paper?S1600536811028212 |
| spellingShingle | Yip-Foo Win Chen-Shang Choong Siang-Guan Teoh Chin Sing Yeap Hoong-Kun Fun Bis(μ2-2-amino-5-nitrobenzoato)bis(2-amino-5-nitrobenzoato)octabutyldi-μ3-oxido-tetratin(IV) Acta Crystallographica Section E |
| title | Bis(μ2-2-amino-5-nitrobenzoato)bis(2-amino-5-nitrobenzoato)octabutyldi-μ3-oxido-tetratin(IV) |
| title_full | Bis(μ2-2-amino-5-nitrobenzoato)bis(2-amino-5-nitrobenzoato)octabutyldi-μ3-oxido-tetratin(IV) |
| title_fullStr | Bis(μ2-2-amino-5-nitrobenzoato)bis(2-amino-5-nitrobenzoato)octabutyldi-μ3-oxido-tetratin(IV) |
| title_full_unstemmed | Bis(μ2-2-amino-5-nitrobenzoato)bis(2-amino-5-nitrobenzoato)octabutyldi-μ3-oxido-tetratin(IV) |
| title_short | Bis(μ2-2-amino-5-nitrobenzoato)bis(2-amino-5-nitrobenzoato)octabutyldi-μ3-oxido-tetratin(IV) |
| title_sort | bis amp 956 2 2 amino 5 nitrobenzoato bis 2 amino 5 nitrobenzoato octabutyldi amp 956 3 oxido tetratin iv |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811028212 |
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