Cobalt Oxide Synthesis via Flame Spray Pyrolysis as Anode Electrocatalyst for Alkaline Membrane Water Electrolyzer

Nanostructured cobalt oxide powders as electro catalysts for the oxygen evolution reaction (OER) in an alkaline membrane electrolysis cell (AME) were prepared by flame spray synthesis (FS); an AME’s anode was then produced by depositing the FS prepared cobalt oxide powders on an AISI-316 sintered me...

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Main Authors: Alfonso Pozio, Francesco Bozza, Nicola Lisi, Rosa Chierchia, Francesca Migliorini, Roberto Dondè, Silvana De Iuliis
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/13/4626
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author Alfonso Pozio
Francesco Bozza
Nicola Lisi
Rosa Chierchia
Francesca Migliorini
Roberto Dondè
Silvana De Iuliis
author_facet Alfonso Pozio
Francesco Bozza
Nicola Lisi
Rosa Chierchia
Francesca Migliorini
Roberto Dondè
Silvana De Iuliis
author_sort Alfonso Pozio
collection DOAJ
description Nanostructured cobalt oxide powders as electro catalysts for the oxygen evolution reaction (OER) in an alkaline membrane electrolysis cell (AME) were prepared by flame spray synthesis (FS); an AME’s anode was then produced by depositing the FS prepared cobalt oxide powders on an AISI-316 sintered metal fiber by the electrophoretic deposition (EPD) method. FS powders and the composite electrode were characterized by SEM, XRD, and XPS analysis. The electrode showed an increase in the OER catalytic activity in a KOH 0.5 M solution with respect to commercial materials commonly applied in alkaline electrolysis, demonstrating that the flame spray synthesis of nanoparticles combined with the electrophoretic deposition technique represent an effective methodology for producing an anodic catalyst for alkaline membrane electrolyzers.
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spelling doaj.art-72fcb853dccf436180caaa35e734d53d2023-12-01T21:34:31ZengMDPI AGMaterials1996-19442022-07-011513462610.3390/ma15134626Cobalt Oxide Synthesis via Flame Spray Pyrolysis as Anode Electrocatalyst for Alkaline Membrane Water ElectrolyzerAlfonso Pozio0Francesco Bozza1Nicola Lisi2Rosa Chierchia3Francesca Migliorini4Roberto Dondè5Silvana De Iuliis6ENEA, C.R. Casaccia, Via Anguillarese 301, 00123 Rome, ItalyENEA, C.R. Casaccia, Via Anguillarese 301, 00123 Rome, ItalyENEA, C.R. Casaccia, Via Anguillarese 301, 00123 Rome, ItalyENEA, C.R. Casaccia, Via Anguillarese 301, 00123 Rome, ItalyCNR-ICMATE, Institute of Condensed Matter Chemistry and Technology for Energy, Via Cozzi 53, 20125 Milano, ItalyCNR-ICMATE, Institute of Condensed Matter Chemistry and Technology for Energy, Via Cozzi 53, 20125 Milano, ItalyCNR-ICMATE, Institute of Condensed Matter Chemistry and Technology for Energy, Via Cozzi 53, 20125 Milano, ItalyNanostructured cobalt oxide powders as electro catalysts for the oxygen evolution reaction (OER) in an alkaline membrane electrolysis cell (AME) were prepared by flame spray synthesis (FS); an AME’s anode was then produced by depositing the FS prepared cobalt oxide powders on an AISI-316 sintered metal fiber by the electrophoretic deposition (EPD) method. FS powders and the composite electrode were characterized by SEM, XRD, and XPS analysis. The electrode showed an increase in the OER catalytic activity in a KOH 0.5 M solution with respect to commercial materials commonly applied in alkaline electrolysis, demonstrating that the flame spray synthesis of nanoparticles combined with the electrophoretic deposition technique represent an effective methodology for producing an anodic catalyst for alkaline membrane electrolyzers.https://www.mdpi.com/1996-1944/15/13/4626flame spray pyrolysiselectrolysisAMEcobalt oxideOER
spellingShingle Alfonso Pozio
Francesco Bozza
Nicola Lisi
Rosa Chierchia
Francesca Migliorini
Roberto Dondè
Silvana De Iuliis
Cobalt Oxide Synthesis via Flame Spray Pyrolysis as Anode Electrocatalyst for Alkaline Membrane Water Electrolyzer
Materials
flame spray pyrolysis
electrolysis
AME
cobalt oxide
OER
title Cobalt Oxide Synthesis via Flame Spray Pyrolysis as Anode Electrocatalyst for Alkaline Membrane Water Electrolyzer
title_full Cobalt Oxide Synthesis via Flame Spray Pyrolysis as Anode Electrocatalyst for Alkaline Membrane Water Electrolyzer
title_fullStr Cobalt Oxide Synthesis via Flame Spray Pyrolysis as Anode Electrocatalyst for Alkaline Membrane Water Electrolyzer
title_full_unstemmed Cobalt Oxide Synthesis via Flame Spray Pyrolysis as Anode Electrocatalyst for Alkaline Membrane Water Electrolyzer
title_short Cobalt Oxide Synthesis via Flame Spray Pyrolysis as Anode Electrocatalyst for Alkaline Membrane Water Electrolyzer
title_sort cobalt oxide synthesis via flame spray pyrolysis as anode electrocatalyst for alkaline membrane water electrolyzer
topic flame spray pyrolysis
electrolysis
AME
cobalt oxide
OER
url https://www.mdpi.com/1996-1944/15/13/4626
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