Synthesis of modified graphene/ZnO nanocomposite and its application for removal of the heavy metal ions from aqueous solutions

The existence of heavy metals in nature is one of the pressing concerns because of their toxicity and threat to human life. The aim of this study is the preparation of suitable adsorbent for heavy metal adsorption from the waste water using nanotechnology. In this work, modified graphene/ZnO (MG/ZnO...

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Main Author: S.S Sajadi
Format: Article
Language:fas
Published: Nuclear Science and Technology Research Institute 2019-08-01
Series:مجله علوم و فنون هسته‌ای
Subjects:
Online Access:https://jonsat.nstri.ir/article_1001_f446e43b4b069b9f65dd32e6ca5413bd.pdf
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author S.S Sajadi
author_facet S.S Sajadi
author_sort S.S Sajadi
collection DOAJ
description The existence of heavy metals in nature is one of the pressing concerns because of their toxicity and threat to human life. The aim of this study is the preparation of suitable adsorbent for heavy metal adsorption from the waste water using nanotechnology. In this work, modified graphene/ZnO (MG/ZnO) nanocomposite was first synthesized. The as-prepared composite was then used as an adsorbent for heavy metal removal, and its adsorption efficiency was compared with the modified graphene and ZnO nanoparticles. Adsorption efficiency of the modified graphene/ZnO was found higher than modified graphene and ZnO nanoparticles. The influence of the effective parameters on the adsorption process was studied and optimized. The obtained optimum conditions were: time = 30 min, an adsorbent dosage of 0.03 g/L, pH of 6, and T = 25˚C. The experimental data were best described by the pseudo-second-order kinetic and Langmuir isotherm models. The obtained thermodynamic parameters indicate that the adsorption process was exothermic and spontaneous.
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spelling doaj.art-73120300c34f4f7b86f8e2c76f370c872023-05-02T10:16:15ZfasNuclear Science and Technology Research Instituteمجله علوم و فنون هسته‌ای1735-18712676-58612019-08-01402849110.24200/nst.2019.10011001Synthesis of modified graphene/ZnO nanocomposite and its application for removal of the heavy metal ions from aqueous solutionsS.S Sajadi0پژوهشکده‌ی مواد و سوخت هسته‌ای، پژوهشگاه علوم و فنون هسته‌ای، سازمان انرژی اتمی ایران، صندوق پستی: 8486-11365، تهران ـ ایرانThe existence of heavy metals in nature is one of the pressing concerns because of their toxicity and threat to human life. The aim of this study is the preparation of suitable adsorbent for heavy metal adsorption from the waste water using nanotechnology. In this work, modified graphene/ZnO (MG/ZnO) nanocomposite was first synthesized. The as-prepared composite was then used as an adsorbent for heavy metal removal, and its adsorption efficiency was compared with the modified graphene and ZnO nanoparticles. Adsorption efficiency of the modified graphene/ZnO was found higher than modified graphene and ZnO nanoparticles. The influence of the effective parameters on the adsorption process was studied and optimized. The obtained optimum conditions were: time = 30 min, an adsorbent dosage of 0.03 g/L, pH of 6, and T = 25˚C. The experimental data were best described by the pseudo-second-order kinetic and Langmuir isotherm models. The obtained thermodynamic parameters indicate that the adsorption process was exothermic and spontaneous.https://jonsat.nstri.ir/article_1001_f446e43b4b069b9f65dd32e6ca5413bd.pdfnanocompositemodified grapheneznoheavy metals
spellingShingle S.S Sajadi
Synthesis of modified graphene/ZnO nanocomposite and its application for removal of the heavy metal ions from aqueous solutions
مجله علوم و فنون هسته‌ای
nanocomposite
modified graphene
zno
heavy metals
title Synthesis of modified graphene/ZnO nanocomposite and its application for removal of the heavy metal ions from aqueous solutions
title_full Synthesis of modified graphene/ZnO nanocomposite and its application for removal of the heavy metal ions from aqueous solutions
title_fullStr Synthesis of modified graphene/ZnO nanocomposite and its application for removal of the heavy metal ions from aqueous solutions
title_full_unstemmed Synthesis of modified graphene/ZnO nanocomposite and its application for removal of the heavy metal ions from aqueous solutions
title_short Synthesis of modified graphene/ZnO nanocomposite and its application for removal of the heavy metal ions from aqueous solutions
title_sort synthesis of modified graphene zno nanocomposite and its application for removal of the heavy metal ions from aqueous solutions
topic nanocomposite
modified graphene
zno
heavy metals
url https://jonsat.nstri.ir/article_1001_f446e43b4b069b9f65dd32e6ca5413bd.pdf
work_keys_str_mv AT sssajadi synthesisofmodifiedgrapheneznonanocompositeanditsapplicationforremovaloftheheavymetalionsfromaqueoussolutions