Di-μ-dimethylformamide-κ4O:O-μ-tetrahydrofuran-κ2O:O-bis[(tetrahydrofuran-κO)sodium(I)] bis(μ-3,6-dichlorobenzene-1,2-dithiolato-κ3S,S′:S)bis[(3,6-dichlorobenzene-1,2-dithiolato-κ2S,S′)iron(III)]
The title compound, [Na2(C3H7NO)2(C4H8O)5][Fe2(C6H2Cl2S2)4], was synthesized and its crystal structure was solved. The ionic crystal contains a [Fe2(S2C6H2Cl2)4]2− dimeric anion and a [Na2(THF)4(μ-THF)(μ-DMF)2]2+ cation, where THF is tetrahydrofuran and DMF is dimethylformamide, comprising two sodiu...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-04-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431461600643X |
| _version_ | 1818966412597657600 |
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| author | Jesús Barrio Esther Delgado Diego Hernández Elisa Hernández Josefina Perles Félix Zamora |
| author_facet | Jesús Barrio Esther Delgado Diego Hernández Elisa Hernández Josefina Perles Félix Zamora |
| author_sort | Jesús Barrio |
| collection | DOAJ |
| description | The title compound, [Na2(C3H7NO)2(C4H8O)5][Fe2(C6H2Cl2S2)4], was synthesized and its crystal structure was solved. The ionic crystal contains a [Fe2(S2C6H2Cl2)4]2− dimeric anion and a [Na2(THF)4(μ-THF)(μ-DMF)2]2+ cation, where THF is tetrahydrofuran and DMF is dimethylformamide, comprising two sodium atoms joined by one THF and two DMF molecules bridging through their O atoms. The five-coordinate environment of each Na site is completed by two terminal THF molecules. The asymmetric unit contains half a cationic unit (as the cation is placed on a twofold axis) and half an anion, as there is an inversion centre at the midpoint of the Fe—Fe vectors. The cationic and anionic moieties are linked by C—H...Cl and C—H...S interactions. |
| first_indexed | 2024-12-20T13:32:30Z |
| format | Article |
| id | doaj.art-7318927ee6144835a2cd8984a2bba49b |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-20T13:32:30Z |
| publishDate | 2016-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-7318927ee6144835a2cd8984a2bba49b2022-12-21T19:39:03ZengInternational Union of CrystallographyIUCrData2414-31462016-04-0114x16064310.1107/S241431461600643Xbh4005Di-μ-dimethylformamide-κ4O:O-μ-tetrahydrofuran-κ2O:O-bis[(tetrahydrofuran-κO)sodium(I)] bis(μ-3,6-dichlorobenzene-1,2-dithiolato-κ3S,S′:S)bis[(3,6-dichlorobenzene-1,2-dithiolato-κ2S,S′)iron(III)]Jesús Barrio0Esther Delgado1Diego Hernández2Elisa Hernández3Josefina Perles4Félix Zamora5Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, SpainDepartamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, SpainDepartamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, SpainDepartamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, SpainLaboratorio de Difracción de Rayos X de Monocristal, Servicio Interdepartamental de Investigación, Universidad Autónoma de Madrid, 28049 Madrid, SpainDepartamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, SpainThe title compound, [Na2(C3H7NO)2(C4H8O)5][Fe2(C6H2Cl2S2)4], was synthesized and its crystal structure was solved. The ionic crystal contains a [Fe2(S2C6H2Cl2)4]2− dimeric anion and a [Na2(THF)4(μ-THF)(μ-DMF)2]2+ cation, where THF is tetrahydrofuran and DMF is dimethylformamide, comprising two sodium atoms joined by one THF and two DMF molecules bridging through their O atoms. The five-coordinate environment of each Na site is completed by two terminal THF molecules. The asymmetric unit contains half a cationic unit (as the cation is placed on a twofold axis) and half an anion, as there is an inversion centre at the midpoint of the Fe—Fe vectors. The cationic and anionic moieties are linked by C—H...Cl and C—H...S interactions.http://scripts.iucr.org/cgi-bin/paper?S241431461600643Xcrystal structureiron dithiolatecoordination compoundsodium compound |
| spellingShingle | Jesús Barrio Esther Delgado Diego Hernández Elisa Hernández Josefina Perles Félix Zamora Di-μ-dimethylformamide-κ4O:O-μ-tetrahydrofuran-κ2O:O-bis[(tetrahydrofuran-κO)sodium(I)] bis(μ-3,6-dichlorobenzene-1,2-dithiolato-κ3S,S′:S)bis[(3,6-dichlorobenzene-1,2-dithiolato-κ2S,S′)iron(III)] IUCrData crystal structure iron dithiolate coordination compound sodium compound |
| title | Di-μ-dimethylformamide-κ4O:O-μ-tetrahydrofuran-κ2O:O-bis[(tetrahydrofuran-κO)sodium(I)] bis(μ-3,6-dichlorobenzene-1,2-dithiolato-κ3S,S′:S)bis[(3,6-dichlorobenzene-1,2-dithiolato-κ2S,S′)iron(III)] |
| title_full | Di-μ-dimethylformamide-κ4O:O-μ-tetrahydrofuran-κ2O:O-bis[(tetrahydrofuran-κO)sodium(I)] bis(μ-3,6-dichlorobenzene-1,2-dithiolato-κ3S,S′:S)bis[(3,6-dichlorobenzene-1,2-dithiolato-κ2S,S′)iron(III)] |
| title_fullStr | Di-μ-dimethylformamide-κ4O:O-μ-tetrahydrofuran-κ2O:O-bis[(tetrahydrofuran-κO)sodium(I)] bis(μ-3,6-dichlorobenzene-1,2-dithiolato-κ3S,S′:S)bis[(3,6-dichlorobenzene-1,2-dithiolato-κ2S,S′)iron(III)] |
| title_full_unstemmed | Di-μ-dimethylformamide-κ4O:O-μ-tetrahydrofuran-κ2O:O-bis[(tetrahydrofuran-κO)sodium(I)] bis(μ-3,6-dichlorobenzene-1,2-dithiolato-κ3S,S′:S)bis[(3,6-dichlorobenzene-1,2-dithiolato-κ2S,S′)iron(III)] |
| title_short | Di-μ-dimethylformamide-κ4O:O-μ-tetrahydrofuran-κ2O:O-bis[(tetrahydrofuran-κO)sodium(I)] bis(μ-3,6-dichlorobenzene-1,2-dithiolato-κ3S,S′:S)bis[(3,6-dichlorobenzene-1,2-dithiolato-κ2S,S′)iron(III)] |
| title_sort | di μ dimethylformamide κ4o o μ tetrahydrofuran κ2o o bis tetrahydrofuran κo sodium i bis μ 3 6 dichlorobenzene 1 2 dithiolato κ3s s s bis 3 6 dichlorobenzene 1 2 dithiolato κ2s s iron iii |
| topic | crystal structure iron dithiolate coordination compound sodium compound |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431461600643X |
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