Electrochemical Detection of p-Aminophenol by Flexible Devices Based on Multi-Wall Carbon Nanotubes Dispersed in Electrochemically Modified Nafion
A conducting composite prepared by dispersing multi-walled carbon nanotubes (MWCNTs) into a host matrix consisting of Nafion, electrochemically doped with copper, has been prepared, characterized and used to modify one of the gold electrodes of simply designed electrochemical cells having copier g...
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MDPI AG
2014-05-01
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Series: | Sensors |
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Online Access: | http://www.mdpi.com/1424-8220/14/5/8926 |
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author | Graziella Scandurra Arena Antonella Carmine Ciofi Gaetano Saitta Maurizio Lanza |
author_facet | Graziella Scandurra Arena Antonella Carmine Ciofi Gaetano Saitta Maurizio Lanza |
author_sort | Graziella Scandurra |
collection | DOAJ |
description | A conducting composite prepared by dispersing multi-walled carbon nanotubes (MWCNTs) into a host matrix consisting of Nafion, electrochemically doped with copper, has been prepared, characterized and used to modify one of the gold electrodes of simply designed electrochemical cells having copier grade transparency sheets as substrates. Electrical measurements performed in deionized water show that the Au/Nafion/Au-MWCNTs–Nafion:Cu cells can be successfully used in order to detect the presence of p-aminophenol (PAP) in water, without the need for any supporting electrolyte. The intensity of the redox peaks arising when PAP is added to deionized water is found to be linearly related to the analyte in the range from 0.2 to 1.6 µM, with a detection limit of 90 nM and a sensitivity of 7 µA·(µM−1)·cm−2. |
first_indexed | 2024-04-11T13:05:05Z |
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id | doaj.art-731eb541a68545dcade70c6846f2b587 |
institution | Directory Open Access Journal |
issn | 1424-8220 |
language | English |
last_indexed | 2024-04-11T13:05:05Z |
publishDate | 2014-05-01 |
publisher | MDPI AG |
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series | Sensors |
spelling | doaj.art-731eb541a68545dcade70c6846f2b5872022-12-22T04:22:49ZengMDPI AGSensors1424-82202014-05-011458926893910.3390/s140508926s140508926Electrochemical Detection of p-Aminophenol by Flexible Devices Based on Multi-Wall Carbon Nanotubes Dispersed in Electrochemically Modified NafionGraziella Scandurra0Arena Antonella1Carmine Ciofi2Gaetano Saitta3Maurizio Lanza4Department of Electronic Engineering, Chemistry and Industrial Engineering, Messina University, Messina 98166, ItalyDepartment of Electronic Engineering, Chemistry and Industrial Engineering, Messina University, Messina 98166, ItalyDepartment of Electronic Engineering, Chemistry and Industrial Engineering, Messina University, Messina 98166, ItalyDepartment of Electronic Engineering, Chemistry and Industrial Engineering, Messina University, Messina 98166, ItalyCNR, Institute for Chemical-Physics Processes, Messina Section, Messina 98166, ItalyA conducting composite prepared by dispersing multi-walled carbon nanotubes (MWCNTs) into a host matrix consisting of Nafion, electrochemically doped with copper, has been prepared, characterized and used to modify one of the gold electrodes of simply designed electrochemical cells having copier grade transparency sheets as substrates. Electrical measurements performed in deionized water show that the Au/Nafion/Au-MWCNTs–Nafion:Cu cells can be successfully used in order to detect the presence of p-aminophenol (PAP) in water, without the need for any supporting electrolyte. The intensity of the redox peaks arising when PAP is added to deionized water is found to be linearly related to the analyte in the range from 0.2 to 1.6 µM, with a detection limit of 90 nM and a sensitivity of 7 µA·(µM−1)·cm−2.http://www.mdpi.com/1424-8220/14/5/8926p-aminophenolelectrochemical sensorNafion/MWCNTs-modified electrodes |
spellingShingle | Graziella Scandurra Arena Antonella Carmine Ciofi Gaetano Saitta Maurizio Lanza Electrochemical Detection of p-Aminophenol by Flexible Devices Based on Multi-Wall Carbon Nanotubes Dispersed in Electrochemically Modified Nafion Sensors p-aminophenol electrochemical sensor Nafion/MWCNTs-modified electrodes |
title | Electrochemical Detection of p-Aminophenol by Flexible Devices Based on Multi-Wall Carbon Nanotubes Dispersed in Electrochemically Modified Nafion |
title_full | Electrochemical Detection of p-Aminophenol by Flexible Devices Based on Multi-Wall Carbon Nanotubes Dispersed in Electrochemically Modified Nafion |
title_fullStr | Electrochemical Detection of p-Aminophenol by Flexible Devices Based on Multi-Wall Carbon Nanotubes Dispersed in Electrochemically Modified Nafion |
title_full_unstemmed | Electrochemical Detection of p-Aminophenol by Flexible Devices Based on Multi-Wall Carbon Nanotubes Dispersed in Electrochemically Modified Nafion |
title_short | Electrochemical Detection of p-Aminophenol by Flexible Devices Based on Multi-Wall Carbon Nanotubes Dispersed in Electrochemically Modified Nafion |
title_sort | electrochemical detection of p aminophenol by flexible devices based on multi wall carbon nanotubes dispersed in electrochemically modified nafion |
topic | p-aminophenol electrochemical sensor Nafion/MWCNTs-modified electrodes |
url | http://www.mdpi.com/1424-8220/14/5/8926 |
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