Trimethylcyanosilane as a Convenient Reagent for the Preparation of Trimethylsilyl Enol Ethers of 1,3-Diketones

Trimethylsilyl enol ethers of 1,3-diketones are generated “in situ†or obtained in high isolated yield by the reaction of 1,3-diketones with trimethylcyanosilane in various solvents such as cyclohexane, hexane, benzene, methylene chloride, chloroform, carbon tetrachloride, and acetonitrile....

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Main Author: Jin-Cong Zhuo
Format: Article
Language:English
Published: MDPI AG 1999-10-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/4/10/310/
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author Jin-Cong Zhuo
author_facet Jin-Cong Zhuo
author_sort Jin-Cong Zhuo
collection DOAJ
description Trimethylsilyl enol ethers of 1,3-diketones are generated “in situ†or obtained in high isolated yield by the reaction of 1,3-diketones with trimethylcyanosilane in various solvents such as cyclohexane, hexane, benzene, methylene chloride, chloroform, carbon tetrachloride, and acetonitrile.
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spelling doaj.art-7323795d63e2464886084f020fc113a92022-12-22T03:53:44ZengMDPI AGMolecules1420-30491999-10-0141031031510.3390/41000310Trimethylcyanosilane as a Convenient Reagent for the Preparation of Trimethylsilyl Enol Ethers of 1,3-DiketonesJin-Cong ZhuoTrimethylsilyl enol ethers of 1,3-diketones are generated “in situ†or obtained in high isolated yield by the reaction of 1,3-diketones with trimethylcyanosilane in various solvents such as cyclohexane, hexane, benzene, methylene chloride, chloroform, carbon tetrachloride, and acetonitrile.http://www.mdpi.com/1420-3049/4/10/310/TrimethylcyanosilaneSilylation13-DiketonesTrimethylsilyl enol ethers
spellingShingle Jin-Cong Zhuo
Trimethylcyanosilane as a Convenient Reagent for the Preparation of Trimethylsilyl Enol Ethers of 1,3-Diketones
Molecules
Trimethylcyanosilane
Silylation
1
3-Diketones
Trimethylsilyl enol ethers
title Trimethylcyanosilane as a Convenient Reagent for the Preparation of Trimethylsilyl Enol Ethers of 1,3-Diketones
title_full Trimethylcyanosilane as a Convenient Reagent for the Preparation of Trimethylsilyl Enol Ethers of 1,3-Diketones
title_fullStr Trimethylcyanosilane as a Convenient Reagent for the Preparation of Trimethylsilyl Enol Ethers of 1,3-Diketones
title_full_unstemmed Trimethylcyanosilane as a Convenient Reagent for the Preparation of Trimethylsilyl Enol Ethers of 1,3-Diketones
title_short Trimethylcyanosilane as a Convenient Reagent for the Preparation of Trimethylsilyl Enol Ethers of 1,3-Diketones
title_sort trimethylcyanosilane as a convenient reagent for the preparation of trimethylsilyl enol ethers of 1 3 diketones
topic Trimethylcyanosilane
Silylation
1
3-Diketones
Trimethylsilyl enol ethers
url http://www.mdpi.com/1420-3049/4/10/310/
work_keys_str_mv AT jincongzhuo trimethylcyanosilaneasaconvenientreagentforthepreparationoftrimethylsilylenolethersof13diketones