Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils

The production of biodiesel using vegetable oil is an effective way to meet growing energy demands, which could potentially reduce the dependency on fossil fuels. The aim of this study was to evaluate grape seed (<i>Vitis vinifera</i>), Philippine tung (<i>Reutealis trisperma</i...

Full description

Bibliographic Details
Main Authors: Hwai Chyuan Ong, M. Mofijur, A.S. Silitonga, D. Gumilang, Fitranto Kusumo, T.M.I. Mahlia
Format: Article
Language:English
Published: MDPI AG 2020-03-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/13/6/1319
_version_ 1811263819376230400
author Hwai Chyuan Ong
M. Mofijur
A.S. Silitonga
D. Gumilang
Fitranto Kusumo
T.M.I. Mahlia
author_facet Hwai Chyuan Ong
M. Mofijur
A.S. Silitonga
D. Gumilang
Fitranto Kusumo
T.M.I. Mahlia
author_sort Hwai Chyuan Ong
collection DOAJ
description The production of biodiesel using vegetable oil is an effective way to meet growing energy demands, which could potentially reduce the dependency on fossil fuels. The aim of this study was to evaluate grape seed (<i>Vitis vinifera</i>), Philippine tung (<i>Reutealis trisperma</i>), and kesambi (<i>Schleichera oleosa</i>) oils as potential feedstocks for biodiesel production to meet this demand. Firstly, biodiesels from these oils were produced and then their fatty acid methyl ester profiles and physicochemical properties were evaluated and compared with palm biodiesel. The results showed that the biodiesel produced from grape seed oil possessed the highest oxidation stability of 4.62 h. On the other hand, poor oxidation stability was observed for Philippine tung biodiesel at 2.47 h. The poor properties of Philippine tung biodiesel can be attributed to the presence of &#945;-elaeostearic fatty acid. Furthermore, synthetic antioxidants (pyrogallol) and diesel were used to improve the oxidation stability. The 0.2 wt.% concentration of pyrogallol antioxidant could increase the oxidation stability of grape seed biodiesel to 6.24 h, while for kesambi and Philippine tung, biodiesels at higher concentrations of 0.3% and 0.4 wt.%, respectively, were needed to meet the minimum limit of 8 h. The blending of biodiesel with fossil diesel at different ratios can also increase the oxidation stability.
first_indexed 2024-04-12T19:51:58Z
format Article
id doaj.art-7338890d529242268338fd223586230f
institution Directory Open Access Journal
issn 1996-1073
language English
last_indexed 2024-04-12T19:51:58Z
publishDate 2020-03-01
publisher MDPI AG
record_format Article
series Energies
spelling doaj.art-7338890d529242268338fd223586230f2022-12-22T03:18:48ZengMDPI AGEnergies1996-10732020-03-01136131910.3390/en13061319en13061319Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm OilsHwai Chyuan Ong0M. Mofijur1A.S. Silitonga2D. Gumilang3Fitranto Kusumo4T.M.I. Mahlia5School of Information, Systems and Modelling, Faculty of Engineering and Information Technology, University of Technology Sydney, 15 Broadway, Ultimo 2007, AustraliaSchool of Information, Systems and Modelling, Faculty of Engineering and Information Technology, University of Technology Sydney, 15 Broadway, Ultimo 2007, AustraliaDepartment of Mechanical Engineering, Politeknik Negeri Medan, Medan 20155, IndonesiaDepartment of Mechanical Engineering, Politeknik Negeri Medan, Medan 20155, IndonesiaSchool of Information, Systems and Modelling, Faculty of Engineering and Information Technology, University of Technology Sydney, 15 Broadway, Ultimo 2007, AustraliaSchool of Information, Systems and Modelling, Faculty of Engineering and Information Technology, University of Technology Sydney, 15 Broadway, Ultimo 2007, AustraliaThe production of biodiesel using vegetable oil is an effective way to meet growing energy demands, which could potentially reduce the dependency on fossil fuels. The aim of this study was to evaluate grape seed (<i>Vitis vinifera</i>), Philippine tung (<i>Reutealis trisperma</i>), and kesambi (<i>Schleichera oleosa</i>) oils as potential feedstocks for biodiesel production to meet this demand. Firstly, biodiesels from these oils were produced and then their fatty acid methyl ester profiles and physicochemical properties were evaluated and compared with palm biodiesel. The results showed that the biodiesel produced from grape seed oil possessed the highest oxidation stability of 4.62 h. On the other hand, poor oxidation stability was observed for Philippine tung biodiesel at 2.47 h. The poor properties of Philippine tung biodiesel can be attributed to the presence of &#945;-elaeostearic fatty acid. Furthermore, synthetic antioxidants (pyrogallol) and diesel were used to improve the oxidation stability. The 0.2 wt.% concentration of pyrogallol antioxidant could increase the oxidation stability of grape seed biodiesel to 6.24 h, while for kesambi and Philippine tung, biodiesels at higher concentrations of 0.3% and 0.4 wt.%, respectively, were needed to meet the minimum limit of 8 h. The blending of biodiesel with fossil diesel at different ratios can also increase the oxidation stability.https://www.mdpi.com/1996-1073/13/6/1319biodieselalternative energyantioxidantblending ratiobiofuelviscosity
spellingShingle Hwai Chyuan Ong
M. Mofijur
A.S. Silitonga
D. Gumilang
Fitranto Kusumo
T.M.I. Mahlia
Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils
Energies
biodiesel
alternative energy
antioxidant
blending ratio
biofuel
viscosity
title Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils
title_full Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils
title_fullStr Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils
title_full_unstemmed Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils
title_short Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils
title_sort physicochemical properties of biodiesel synthesised from grape seed philippine tung kesambi and palm oils
topic biodiesel
alternative energy
antioxidant
blending ratio
biofuel
viscosity
url https://www.mdpi.com/1996-1073/13/6/1319
work_keys_str_mv AT hwaichyuanong physicochemicalpropertiesofbiodieselsynthesisedfromgrapeseedphilippinetungkesambiandpalmoils
AT mmofijur physicochemicalpropertiesofbiodieselsynthesisedfromgrapeseedphilippinetungkesambiandpalmoils
AT assilitonga physicochemicalpropertiesofbiodieselsynthesisedfromgrapeseedphilippinetungkesambiandpalmoils
AT dgumilang physicochemicalpropertiesofbiodieselsynthesisedfromgrapeseedphilippinetungkesambiandpalmoils
AT fitrantokusumo physicochemicalpropertiesofbiodieselsynthesisedfromgrapeseedphilippinetungkesambiandpalmoils
AT tmimahlia physicochemicalpropertiesofbiodieselsynthesisedfromgrapeseedphilippinetungkesambiandpalmoils