COMPUŞI COORDINATIVI AI CUPRULUI(II) CU 1,5-BIS-TIOCARBOHIDRAZONE ALE ALDEHIDEI SALICILICE SUBSTITUITE
There is described the synthesis, structure and magneto-chemical investigation of a new series of copper(II) complexes with substituted salicylaldehyde thiocarbohydrazone. The ligands were obtained by condensation of thiocarbohydrazide with the respective salicylaldehyde (its 3-methoxy-, 3-ethoxy-...
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| Format: | Article |
| Language: | English |
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Moldova State University
2007-12-01
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| Series: | Studia Universitatis Moldaviae: Stiinte reale si ale naturii |
| Online Access: | https://ojs.studiamsu.md/index.php/stiinte_reale_naturii/article/view/185 |
| _version_ | 1828168000191070208 |
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| author | USM ADMIN |
| author_facet | USM ADMIN |
| author_sort | USM ADMIN |
| collection | DOAJ |
| description |
There is described the synthesis, structure and magneto-chemical investigation of a new series of copper(II) complexes with substituted salicylaldehyde thiocarbohydrazone. The ligands were obtained by condensation of thiocarbohydrazide with the respective salicylaldehyde (its 3-methoxy-, 3-ethoxy- and 3,5-di-Br derivatives). The formation of binuclear copper(II) complexes containing as ligand its three- deprotonated form was observed. The donor atom sites used by the ligand for the coordination to the copper(II) are nonequivalent: ONN and SNO. Magnetic measurements of the complexes in the temperature range 2-290K indicated the antiferromagnetic interactions between the paramagnetic copper(II) ions.
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| first_indexed | 2024-04-12T02:26:34Z |
| format | Article |
| id | doaj.art-733fd234020a4c3b862a91101c673bd1 |
| institution | Directory Open Access Journal |
| issn | 1814-3237 1857-498X |
| language | English |
| last_indexed | 2024-04-12T02:26:34Z |
| publishDate | 2007-12-01 |
| publisher | Moldova State University |
| record_format | Article |
| series | Studia Universitatis Moldaviae: Stiinte reale si ale naturii |
| spelling | doaj.art-733fd234020a4c3b862a91101c673bd12022-12-22T03:51:58ZengMoldova State UniversityStudia Universitatis Moldaviae: Stiinte reale si ale naturii1814-32371857-498X2007-12-017COMPUŞI COORDINATIVI AI CUPRULUI(II) CU 1,5-BIS-TIOCARBOHIDRAZONE ALE ALDEHIDEI SALICILICE SUBSTITUITEUSM ADMIN0Studia Universitas Moldaviae There is described the synthesis, structure and magneto-chemical investigation of a new series of copper(II) complexes with substituted salicylaldehyde thiocarbohydrazone. The ligands were obtained by condensation of thiocarbohydrazide with the respective salicylaldehyde (its 3-methoxy-, 3-ethoxy- and 3,5-di-Br derivatives). The formation of binuclear copper(II) complexes containing as ligand its three- deprotonated form was observed. The donor atom sites used by the ligand for the coordination to the copper(II) are nonequivalent: ONN and SNO. Magnetic measurements of the complexes in the temperature range 2-290K indicated the antiferromagnetic interactions between the paramagnetic copper(II) ions. https://ojs.studiamsu.md/index.php/stiinte_reale_naturii/article/view/185 |
| spellingShingle | USM ADMIN COMPUŞI COORDINATIVI AI CUPRULUI(II) CU 1,5-BIS-TIOCARBOHIDRAZONE ALE ALDEHIDEI SALICILICE SUBSTITUITE Studia Universitatis Moldaviae: Stiinte reale si ale naturii |
| title | COMPUŞI COORDINATIVI AI CUPRULUI(II) CU 1,5-BIS-TIOCARBOHIDRAZONE ALE ALDEHIDEI SALICILICE SUBSTITUITE |
| title_full | COMPUŞI COORDINATIVI AI CUPRULUI(II) CU 1,5-BIS-TIOCARBOHIDRAZONE ALE ALDEHIDEI SALICILICE SUBSTITUITE |
| title_fullStr | COMPUŞI COORDINATIVI AI CUPRULUI(II) CU 1,5-BIS-TIOCARBOHIDRAZONE ALE ALDEHIDEI SALICILICE SUBSTITUITE |
| title_full_unstemmed | COMPUŞI COORDINATIVI AI CUPRULUI(II) CU 1,5-BIS-TIOCARBOHIDRAZONE ALE ALDEHIDEI SALICILICE SUBSTITUITE |
| title_short | COMPUŞI COORDINATIVI AI CUPRULUI(II) CU 1,5-BIS-TIOCARBOHIDRAZONE ALE ALDEHIDEI SALICILICE SUBSTITUITE |
| title_sort | compusi coordinativi ai cuprului ii cu 1 5 bis tiocarbohidrazone ale aldehidei salicilice substituite |
| url | https://ojs.studiamsu.md/index.php/stiinte_reale_naturii/article/view/185 |
| work_keys_str_mv | AT usmadmin compusicoordinativiaicupruluiiicu15bistiocarbohidrazonealealdehideisalicilicesubstituite |