Applicability of Nickel-Based Catalytic Systems for Hydrodehalogenation of Recalcitrant Halogenated Aromatic Compounds
This review summarizes recent applications of nickel as a nonprecious metal catalyst in hydrodehalogenation (HDH) reactions of halogenated aromatic compounds (Ar–Xs). Nickel-based HDH catalysts were developed for reductive treatment of both waste containing concentrated Ar–Xs (mainly polychlorinated...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-11-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/11/12/1465 |
| _version_ | 1797506314151133184 |
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| author | Tomáš Weidlich |
| author_facet | Tomáš Weidlich |
| author_sort | Tomáš Weidlich |
| collection | DOAJ |
| description | This review summarizes recent applications of nickel as a nonprecious metal catalyst in hydrodehalogenation (HDH) reactions of halogenated aromatic compounds (Ar–Xs). Nickel-based HDH catalysts were developed for reductive treatment of both waste containing concentrated Ar–Xs (mainly polychlorinated benzenes) and for wastewater contaminated with Ar–Xs. Ni-catalyzed HDH enables the production of corresponding nonhalogenated aromatic products (Ar–Hs), which are principally further applicable/recyclable and/or Ar–Hs, which are much more biodegradable and can be mineralized during aerobic wastewater treatment. Developed HDH methods enable the utilization of both gaseous hydrogen via the direct HDH process or other chemical reductants as a source of hydrogen utilized in the transfer of the hydrodehalogenation process. This review highlights recent and major developments in Ni-catalyzed hydrodehalogenation topic since 1990. |
| first_indexed | 2024-03-10T04:30:51Z |
| format | Article |
| id | doaj.art-7342298f0f694daf91a4e9a22b3c93c9 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T04:30:51Z |
| publishDate | 2021-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-7342298f0f694daf91a4e9a22b3c93c92023-11-23T04:09:24ZengMDPI AGCatalysts2073-43442021-11-011112146510.3390/catal11121465Applicability of Nickel-Based Catalytic Systems for Hydrodehalogenation of Recalcitrant Halogenated Aromatic CompoundsTomáš Weidlich0Chemical Technology Group, Institute of Environmental and Chemical Engineering, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech RepublicThis review summarizes recent applications of nickel as a nonprecious metal catalyst in hydrodehalogenation (HDH) reactions of halogenated aromatic compounds (Ar–Xs). Nickel-based HDH catalysts were developed for reductive treatment of both waste containing concentrated Ar–Xs (mainly polychlorinated benzenes) and for wastewater contaminated with Ar–Xs. Ni-catalyzed HDH enables the production of corresponding nonhalogenated aromatic products (Ar–Hs), which are principally further applicable/recyclable and/or Ar–Hs, which are much more biodegradable and can be mineralized during aerobic wastewater treatment. Developed HDH methods enable the utilization of both gaseous hydrogen via the direct HDH process or other chemical reductants as a source of hydrogen utilized in the transfer of the hydrodehalogenation process. This review highlights recent and major developments in Ni-catalyzed hydrodehalogenation topic since 1990.https://www.mdpi.com/2073-4344/11/12/1465hydrodehalogenationhydrodechlorinationnickelbimetallic systemsnanocatalystsAl–Ni |
| spellingShingle | Tomáš Weidlich Applicability of Nickel-Based Catalytic Systems for Hydrodehalogenation of Recalcitrant Halogenated Aromatic Compounds Catalysts hydrodehalogenation hydrodechlorination nickel bimetallic systems nanocatalysts Al–Ni |
| title | Applicability of Nickel-Based Catalytic Systems for Hydrodehalogenation of Recalcitrant Halogenated Aromatic Compounds |
| title_full | Applicability of Nickel-Based Catalytic Systems for Hydrodehalogenation of Recalcitrant Halogenated Aromatic Compounds |
| title_fullStr | Applicability of Nickel-Based Catalytic Systems for Hydrodehalogenation of Recalcitrant Halogenated Aromatic Compounds |
| title_full_unstemmed | Applicability of Nickel-Based Catalytic Systems for Hydrodehalogenation of Recalcitrant Halogenated Aromatic Compounds |
| title_short | Applicability of Nickel-Based Catalytic Systems for Hydrodehalogenation of Recalcitrant Halogenated Aromatic Compounds |
| title_sort | applicability of nickel based catalytic systems for hydrodehalogenation of recalcitrant halogenated aromatic compounds |
| topic | hydrodehalogenation hydrodechlorination nickel bimetallic systems nanocatalysts Al–Ni |
| url | https://www.mdpi.com/2073-4344/11/12/1465 |
| work_keys_str_mv | AT tomasweidlich applicabilityofnickelbasedcatalyticsystemsforhydrodehalogenationofrecalcitranthalogenatedaromaticcompounds |