An Innovative and Easy Method for Iron-Doped Titania Synthesis

In this work, photocatalytically active titanium oxide nanoparticles were synthesized for the treatment of contaminated water under visible light. Various Ag, Sr and Fe-based synthesis and doping techniques (mainly hydrothermal and sol-gel methods) were performed. Adsorptive and photocatalytic prope...

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Main Authors: Domenico Rosa, Francesca D'Agostino, Irene Bavasso, Luca Di Palma
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2023-07-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/13450
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author Domenico Rosa
Francesca D'Agostino
Irene Bavasso
Luca Di Palma
author_facet Domenico Rosa
Francesca D'Agostino
Irene Bavasso
Luca Di Palma
author_sort Domenico Rosa
collection DOAJ
description In this work, photocatalytically active titanium oxide nanoparticles were synthesized for the treatment of contaminated water under visible light. Various Ag, Sr and Fe-based synthesis and doping techniques (mainly hydrothermal and sol-gel methods) were performed. Adsorptive and photocatalytic properties were studied by testing in batch mode for the decontaminating a synthetic methylene blue solution (used as a model contaminant) using a simple 13 W LED bulb as the light source. The best material in terms of both activity (high removal kinetics) and simplicity of synthesis was found to be titanium oxide doped with Fe via "solid-state" method. This method enabled the synthesis of titania nanoparticles about 70 nanometers in size with Fe3+ effectively substituting titanium atoms (Ti4+) in the crystalline bulk of titania. The pseudo-first-order kinetic model was found to represent the behavior of the experimental data.
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spelling doaj.art-735d0f88dc4440908a0b8cfa573b76222023-07-29T22:35:52ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162023-07-01101An Innovative and Easy Method for Iron-Doped Titania SynthesisDomenico RosaFrancesca D'AgostinoIrene BavassoLuca Di PalmaIn this work, photocatalytically active titanium oxide nanoparticles were synthesized for the treatment of contaminated water under visible light. Various Ag, Sr and Fe-based synthesis and doping techniques (mainly hydrothermal and sol-gel methods) were performed. Adsorptive and photocatalytic properties were studied by testing in batch mode for the decontaminating a synthetic methylene blue solution (used as a model contaminant) using a simple 13 W LED bulb as the light source. The best material in terms of both activity (high removal kinetics) and simplicity of synthesis was found to be titanium oxide doped with Fe via "solid-state" method. This method enabled the synthesis of titania nanoparticles about 70 nanometers in size with Fe3+ effectively substituting titanium atoms (Ti4+) in the crystalline bulk of titania. The pseudo-first-order kinetic model was found to represent the behavior of the experimental data.https://www.cetjournal.it/index.php/cet/article/view/13450
spellingShingle Domenico Rosa
Francesca D'Agostino
Irene Bavasso
Luca Di Palma
An Innovative and Easy Method for Iron-Doped Titania Synthesis
Chemical Engineering Transactions
title An Innovative and Easy Method for Iron-Doped Titania Synthesis
title_full An Innovative and Easy Method for Iron-Doped Titania Synthesis
title_fullStr An Innovative and Easy Method for Iron-Doped Titania Synthesis
title_full_unstemmed An Innovative and Easy Method for Iron-Doped Titania Synthesis
title_short An Innovative and Easy Method for Iron-Doped Titania Synthesis
title_sort innovative and easy method for iron doped titania synthesis
url https://www.cetjournal.it/index.php/cet/article/view/13450
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