Method for introducing heteroatoms into the framework of FER-type zeolite by intercalation of sub-zeolite of Lamellar precusor PLS-3
A method for introducing heteroatoms Al, Ti, and Sn into the framework of FER-type zeolite was provided. The incorporation of heteroatoms was achieved by intercalation of sub-zeolite of lamellar precursor PLS-3 that possessed disordered structure along layered direction using 4-amion-2,2,6,6-tetrame...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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IOP Publishing
2022-01-01
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| Series: | Materials Research Express |
| Subjects: | |
| Online Access: | https://doi.org/10.1088/2053-1591/ac6a4b |
| _version_ | 1827868788020740096 |
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| author | Boting Yang Tianxiao Cui |
| author_facet | Boting Yang Tianxiao Cui |
| author_sort | Boting Yang |
| collection | DOAJ |
| description | A method for introducing heteroatoms Al, Ti, and Sn into the framework of FER-type zeolite was provided. The incorporation of heteroatoms was achieved by intercalation of sub-zeolite of lamellar precursor PLS-3 that possessed disordered structure along layered direction using 4-amion-2,2,6,6-tetramentylniperidine together with salts containing a heteroatom. During intercalation, the molar ratio of Si and heteroatoms can be adjusted between 30 to ∞. Heteroatoms entered the material with the help of hydrothermal synthesis conditions used in the intercalation process, resulting in reordered layered metalosilicate structure. After mild acid treatment of these metalosilicates to remove extra-framework heteroatoms and further calcination, we obtained a three-dimensional zeolite of FER topology with framework Al, Ti, and Sn. |
| first_indexed | 2024-03-12T15:36:22Z |
| format | Article |
| id | doaj.art-73627ac8922443079cbed46d75ebf04d |
| institution | Directory Open Access Journal |
| issn | 2053-1591 |
| language | English |
| last_indexed | 2024-03-12T15:36:22Z |
| publishDate | 2022-01-01 |
| publisher | IOP Publishing |
| record_format | Article |
| series | Materials Research Express |
| spelling | doaj.art-73627ac8922443079cbed46d75ebf04d2023-08-09T16:12:31ZengIOP PublishingMaterials Research Express2053-15912022-01-019505500110.1088/2053-1591/ac6a4bMethod for introducing heteroatoms into the framework of FER-type zeolite by intercalation of sub-zeolite of Lamellar precusor PLS-3Boting Yang0https://orcid.org/0000-0002-4286-2595Tianxiao Cui1College of Science, Beihua University , Jilin 132013, People’s Republic of ChinaSchool of Engineering Training Center, Northeast Electric Power University , Jilin, 132012, People’s Republic of ChinaA method for introducing heteroatoms Al, Ti, and Sn into the framework of FER-type zeolite was provided. The incorporation of heteroatoms was achieved by intercalation of sub-zeolite of lamellar precursor PLS-3 that possessed disordered structure along layered direction using 4-amion-2,2,6,6-tetramentylniperidine together with salts containing a heteroatom. During intercalation, the molar ratio of Si and heteroatoms can be adjusted between 30 to ∞. Heteroatoms entered the material with the help of hydrothermal synthesis conditions used in the intercalation process, resulting in reordered layered metalosilicate structure. After mild acid treatment of these metalosilicates to remove extra-framework heteroatoms and further calcination, we obtained a three-dimensional zeolite of FER topology with framework Al, Ti, and Sn.https://doi.org/10.1088/2053-1591/ac6a4bheteroatomsub-zeoliteintercalation |
| spellingShingle | Boting Yang Tianxiao Cui Method for introducing heteroatoms into the framework of FER-type zeolite by intercalation of sub-zeolite of Lamellar precusor PLS-3 Materials Research Express heteroatom sub-zeolite intercalation |
| title | Method for introducing heteroatoms into the framework of FER-type zeolite by intercalation of sub-zeolite of Lamellar precusor PLS-3 |
| title_full | Method for introducing heteroatoms into the framework of FER-type zeolite by intercalation of sub-zeolite of Lamellar precusor PLS-3 |
| title_fullStr | Method for introducing heteroatoms into the framework of FER-type zeolite by intercalation of sub-zeolite of Lamellar precusor PLS-3 |
| title_full_unstemmed | Method for introducing heteroatoms into the framework of FER-type zeolite by intercalation of sub-zeolite of Lamellar precusor PLS-3 |
| title_short | Method for introducing heteroatoms into the framework of FER-type zeolite by intercalation of sub-zeolite of Lamellar precusor PLS-3 |
| title_sort | method for introducing heteroatoms into the framework of fer type zeolite by intercalation of sub zeolite of lamellar precusor pls 3 |
| topic | heteroatom sub-zeolite intercalation |
| url | https://doi.org/10.1088/2053-1591/ac6a4b |
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