Assessing tolerances in direct write laser grayscale lithography and reactive ion etching pattern transfer for fabrication of 2.5D Si master molds

Direct Write Laser (DWL) Grayscale (GS) lithography has gathered attention as a versatile technological solution to fabricate arbitrary and complex 2.5D structures in photoresist (PR). In combination with Reactive Ion Etching (RIE), DWL GS can enable the fabrication of 2.5D micro-structured silicon...

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Main Authors: Joao Cunha, Inês S. Garcia, Joana D. Santos, José Fernandes, Pedro González-Losada, Carlos Silva, João Gaspar, Ana Cortez, Marcos Sampaio, Diogo E. Aguiam
Format: Article
Language:English
Published: Elsevier 2023-06-01
Series:Micro and Nano Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590007223000126
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author Joao Cunha
Inês S. Garcia
Joana D. Santos
José Fernandes
Pedro González-Losada
Carlos Silva
João Gaspar
Ana Cortez
Marcos Sampaio
Diogo E. Aguiam
author_facet Joao Cunha
Inês S. Garcia
Joana D. Santos
José Fernandes
Pedro González-Losada
Carlos Silva
João Gaspar
Ana Cortez
Marcos Sampaio
Diogo E. Aguiam
author_sort Joao Cunha
collection DOAJ
description Direct Write Laser (DWL) Grayscale (GS) lithography has gathered attention as a versatile technological solution to fabricate arbitrary and complex 2.5D structures in photoresist (PR). In combination with Reactive Ion Etching (RIE), DWL GS can enable the fabrication of 2.5D micro-structured silicon substrates to be used as molds in high-precision replication processes. To this end, typically, a multilevel pattern is first defined in a low contrast PR and then transferred to the Si substrate via anisotropic RIE. The uniformity and selectivity of the etching process to the PR and substrate materials will define the dimensions of the 2.5D structures in the substrate. However, while there have been numerous examples of etched shapes in Si using this strategy, the wafer scale dimensional variations for etched Si molds fabricated via DWL GS and RIE have not been reported so far. In this work, we present a wafer-scale and wafer-to-wafer analysis of the dimensional variations in the fabrication process of Si molds with 2.5D 100-μm deep cavities using DWL GS lithography and RIE. The dimensional variations and deviations were characterized along each process step over several wafers. The final Si etched shapes consisting of microlens array cavities showed a maximum relative deviation of 10.35% with respect to the intended shape design with a curvature radius variation up to ∼5%, demonstrating this process potential for arbitrary 2.5D Si mold fabrication.
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spelling doaj.art-7372a300dc254bf681b3c115a7db2de72023-06-21T06:58:52ZengElsevierMicro and Nano Engineering2590-00722023-06-0119100182Assessing tolerances in direct write laser grayscale lithography and reactive ion etching pattern transfer for fabrication of 2.5D Si master moldsJoao Cunha0Inês S. Garcia1Joana D. Santos2José Fernandes3Pedro González-Losada4Carlos Silva5João Gaspar6Ana Cortez7Marcos Sampaio8Diogo E. Aguiam9International Iberian Nanotechnology Laboratory (INL), 4715-330 Braga, Portugal; Corresponding author.International Iberian Nanotechnology Laboratory (INL), 4715-330 Braga, PortugalInternational Iberian Nanotechnology Laboratory (INL), 4715-330 Braga, PortugalInternational Iberian Nanotechnology Laboratory (INL), 4715-330 Braga, PortugalInternational Iberian Nanotechnology Laboratory (INL), 4715-330 Braga, PortugalInternational Iberian Nanotechnology Laboratory (INL), 4715-330 Braga, Portugal; ALGORITMI Center, University of Minho, 4800-058 Guimarães, PortugalInternational Iberian Nanotechnology Laboratory (INL), 4715-330 Braga, PortugalCELOPLÁS, Plásticos para a Indústria S.A., Rua de S. Mateus, 4775-127 Grimancelos, PortugalCELOPLÁS, Plásticos para a Indústria S.A., Rua de S. Mateus, 4775-127 Grimancelos, PortugalInternational Iberian Nanotechnology Laboratory (INL), 4715-330 Braga, Portugal; ALGORITMI Center, University of Minho, 4800-058 Guimarães, PortugalDirect Write Laser (DWL) Grayscale (GS) lithography has gathered attention as a versatile technological solution to fabricate arbitrary and complex 2.5D structures in photoresist (PR). In combination with Reactive Ion Etching (RIE), DWL GS can enable the fabrication of 2.5D micro-structured silicon substrates to be used as molds in high-precision replication processes. To this end, typically, a multilevel pattern is first defined in a low contrast PR and then transferred to the Si substrate via anisotropic RIE. The uniformity and selectivity of the etching process to the PR and substrate materials will define the dimensions of the 2.5D structures in the substrate. However, while there have been numerous examples of etched shapes in Si using this strategy, the wafer scale dimensional variations for etched Si molds fabricated via DWL GS and RIE have not been reported so far. In this work, we present a wafer-scale and wafer-to-wafer analysis of the dimensional variations in the fabrication process of Si molds with 2.5D 100-μm deep cavities using DWL GS lithography and RIE. The dimensional variations and deviations were characterized along each process step over several wafers. The final Si etched shapes consisting of microlens array cavities showed a maximum relative deviation of 10.35% with respect to the intended shape design with a curvature radius variation up to ∼5%, demonstrating this process potential for arbitrary 2.5D Si mold fabrication.http://www.sciencedirect.com/science/article/pii/S2590007223000126Grayscale lithographyDirect write laserPattern transferReactive ion etchingMicrolens arrays
spellingShingle Joao Cunha
Inês S. Garcia
Joana D. Santos
José Fernandes
Pedro González-Losada
Carlos Silva
João Gaspar
Ana Cortez
Marcos Sampaio
Diogo E. Aguiam
Assessing tolerances in direct write laser grayscale lithography and reactive ion etching pattern transfer for fabrication of 2.5D Si master molds
Micro and Nano Engineering
Grayscale lithography
Direct write laser
Pattern transfer
Reactive ion etching
Microlens arrays
title Assessing tolerances in direct write laser grayscale lithography and reactive ion etching pattern transfer for fabrication of 2.5D Si master molds
title_full Assessing tolerances in direct write laser grayscale lithography and reactive ion etching pattern transfer for fabrication of 2.5D Si master molds
title_fullStr Assessing tolerances in direct write laser grayscale lithography and reactive ion etching pattern transfer for fabrication of 2.5D Si master molds
title_full_unstemmed Assessing tolerances in direct write laser grayscale lithography and reactive ion etching pattern transfer for fabrication of 2.5D Si master molds
title_short Assessing tolerances in direct write laser grayscale lithography and reactive ion etching pattern transfer for fabrication of 2.5D Si master molds
title_sort assessing tolerances in direct write laser grayscale lithography and reactive ion etching pattern transfer for fabrication of 2 5d si master molds
topic Grayscale lithography
Direct write laser
Pattern transfer
Reactive ion etching
Microlens arrays
url http://www.sciencedirect.com/science/article/pii/S2590007223000126
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