Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid
A repetitive two-step method involving the Pd-catalyzed Suzuki-Miyaura coupling of hydroxyterphenylboronic acid and the subsequent nonaflation of the hydroxy group has been developed for the synthesis of oligophenylenes. This method readily afforded o,o,p- and o,p-oligophenylenes with defined chain...
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| Format: | Article |
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MDPI AG
2013-12-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/18/12/15207 |
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| author | Miyuki Yamaguchi Takeshi Kimura Naomi Shinohara Kei Manabe |
| author_facet | Miyuki Yamaguchi Takeshi Kimura Naomi Shinohara Kei Manabe |
| author_sort | Miyuki Yamaguchi |
| collection | DOAJ |
| description | A repetitive two-step method involving the Pd-catalyzed Suzuki-Miyaura coupling of hydroxyterphenylboronic acid and the subsequent nonaflation of the hydroxy group has been developed for the synthesis of oligophenylenes. This method readily afforded o,o,p- and o,p-oligophenylenes with defined chain lengths. X-ray crystallography was employed to obtain the structure of the o,p-oligophenylene 9-mer. |
| first_indexed | 2024-12-23T13:20:00Z |
| format | Article |
| id | doaj.art-7386b96f4ef442619b83847cfb2b6181 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-23T13:20:00Z |
| publishDate | 2013-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-7386b96f4ef442619b83847cfb2b61812022-12-21T17:45:29ZengMDPI AGMolecules1420-30492013-12-011812152071521910.3390/molecules181215207molecules181215207Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic AcidMiyuki Yamaguchi0Takeshi Kimura1Naomi Shinohara2Kei Manabe3School of Pharmaceutical Sciences, University of Shizuoka, 52-1 Yada, Suruga-ku, Shizuoka 422-8526, JapanSchool of Pharmaceutical Sciences, University of Shizuoka, 52-1 Yada, Suruga-ku, Shizuoka 422-8526, JapanSchool of Pharmaceutical Sciences, University of Shizuoka, 52-1 Yada, Suruga-ku, Shizuoka 422-8526, JapanSchool of Pharmaceutical Sciences, University of Shizuoka, 52-1 Yada, Suruga-ku, Shizuoka 422-8526, JapanA repetitive two-step method involving the Pd-catalyzed Suzuki-Miyaura coupling of hydroxyterphenylboronic acid and the subsequent nonaflation of the hydroxy group has been developed for the synthesis of oligophenylenes. This method readily afforded o,o,p- and o,p-oligophenylenes with defined chain lengths. X-ray crystallography was employed to obtain the structure of the o,p-oligophenylene 9-mer.http://www.mdpi.com/1420-3049/18/12/15207palladiumSuzuki-Miyaura couplingoligoarenenonaflate |
| spellingShingle | Miyuki Yamaguchi Takeshi Kimura Naomi Shinohara Kei Manabe Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid Molecules palladium Suzuki-Miyaura coupling oligoarene nonaflate |
| title | Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid |
| title_full | Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid |
| title_fullStr | Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid |
| title_full_unstemmed | Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid |
| title_short | Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid |
| title_sort | repetitive two step method for o o p and o p oligophenylene synthesis through pd catalyzed cross coupling of hydroxyterphenylboronic acid |
| topic | palladium Suzuki-Miyaura coupling oligoarene nonaflate |
| url | http://www.mdpi.com/1420-3049/18/12/15207 |
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