Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate
The title complex, [Cu2(C13H16N3O3)(C12H8N2)(H2O)]NO3, consists of a nitrate ion and a binuclear CuII unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one CuII atom and in a tetradentate fashion to the other CuII atom. The CuII atom coordi...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810035919 |
| Summary: | The title complex, [Cu2(C13H16N3O3)(C12H8N2)(H2O)]NO3, consists of a nitrate ion and a binuclear CuII unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one CuII atom and in a tetradentate fashion to the other CuII atom. The CuII atom coordination geometries are distorted square-planar and distorted square-pyramidal. In the crystal structure, binuclear complexes and nitrate ions are connected by classical O—H...O and non-classical C—H...O hydrogen bonds into a three-dimensional framework. The alkyl chains of the anion are equally disorded over two positions. |
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| ISSN: | 1600-5368 |