Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate
The title complex, [Cu2(C13H16N3O3)(C12H8N2)(H2O)]NO3, consists of a nitrate ion and a binuclear CuII unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one CuII atom and in a tetradentate fashion to the other CuII atom. The CuII atom coordi...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810035919 |
| _version_ | 1819280163622354944 |
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| author | Yanbao Wang Zhongjun Gao |
| author_facet | Yanbao Wang Zhongjun Gao |
| author_sort | Yanbao Wang |
| collection | DOAJ |
| description | The title complex, [Cu2(C13H16N3O3)(C12H8N2)(H2O)]NO3, consists of a nitrate ion and a binuclear CuII unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one CuII atom and in a tetradentate fashion to the other CuII atom. The CuII atom coordination geometries are distorted square-planar and distorted square-pyramidal. In the crystal structure, binuclear complexes and nitrate ions are connected by classical O—H...O and non-classical C—H...O hydrogen bonds into a three-dimensional framework. The alkyl chains of the anion are equally disorded over two positions. |
| first_indexed | 2024-12-24T00:39:26Z |
| format | Article |
| id | doaj.art-73a99d85e24b46f0acc1e08a8380409e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:39:26Z |
| publishDate | 2010-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-73a99d85e24b46f0acc1e08a8380409e2022-12-21T17:24:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1249m125010.1107/S1600536810035919Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrateYanbao WangZhongjun GaoThe title complex, [Cu2(C13H16N3O3)(C12H8N2)(H2O)]NO3, consists of a nitrate ion and a binuclear CuII unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one CuII atom and in a tetradentate fashion to the other CuII atom. The CuII atom coordination geometries are distorted square-planar and distorted square-pyramidal. In the crystal structure, binuclear complexes and nitrate ions are connected by classical O—H...O and non-classical C—H...O hydrogen bonds into a three-dimensional framework. The alkyl chains of the anion are equally disorded over two positions.http://scripts.iucr.org/cgi-bin/paper?S1600536810035919 |
| spellingShingle | Yanbao Wang Zhongjun Gao Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate Acta Crystallographica Section E |
| title | Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate |
| title_full | Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate |
| title_fullStr | Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate |
| title_full_unstemmed | Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate |
| title_short | Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate |
| title_sort | aqua amp 956 n 3 dimethylamino propyl n amp 8242 2 oxidophenyl oxamidato 3 amp 8722 1 10 phenanthroline dicopper ii nitrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810035919 |
| work_keys_str_mv | AT yanbaowang aquaamp956n3dimethylaminopropylnamp82422oxidophenyloxamidato3amp8722110phenanthrolinedicopperiinitrate AT zhongjungao aquaamp956n3dimethylaminopropylnamp82422oxidophenyloxamidato3amp8722110phenanthrolinedicopperiinitrate |