Batch study, equilibrium and kinetics of adsorption of naphthalene using waste tyre rubber granules

The potential use of waste tyre rubber granules (WTRG) for the batch adsorption of naphthalene from aqueous solutions was investigated. The effect of various operational variables such as contact time, initial naphthalene concentration, adsorbent dose, size of adsorbent particles, and temperature of...

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Main Authors: Felix A. Aisien, Andrew N. Amenaghawon, Albert I. Adinkwuye
Format: Article
Language:English
Published: MDPI AG 2014-04-01
Series:Journal of Xenobiotics
Subjects:
Online Access:http://www.pagepressjournals.org/index.php/xeno/article/view/2264
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author Felix A. Aisien
Andrew N. Amenaghawon
Albert I. Adinkwuye
author_facet Felix A. Aisien
Andrew N. Amenaghawon
Albert I. Adinkwuye
author_sort Felix A. Aisien
collection DOAJ
description The potential use of waste tyre rubber granules (WTRG) for the batch adsorption of naphthalene from aqueous solutions was investigated. The effect of various operational variables such as contact time, initial naphthalene concentration, adsorbent dose, size of adsorbent particles, and temperature of solution on the adsorption capacity of WTRG was evaluated. The adsorption of naphthalene by WTRG was a fast kinetic process with an equilibrium contact time of 60 min. A low temperature (5°C), small adsorbent particle size (0.212 mm) and higher adsorbent dosage favored the adsorption process. Results of isotherm studies revealed that adsorption of naphthalene was best described by the Langmuir isotherm equation (R<sup>2</sup>=0.997) while the kinetics of the process was best described by the Lagergren pseudofirst order kinetic equation (R<sup>2</sup>=0.998). This study has demonstrated the suitability of WTRG for the removal of naphthalene from aqueous solution.
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spelling doaj.art-73c282217cc5433194695ca8d660ae172022-12-22T04:10:01ZengMDPI AGJournal of Xenobiotics2039-47052039-47132014-04-014110.4081/xeno.2014.22642581Batch study, equilibrium and kinetics of adsorption of naphthalene using waste tyre rubber granulesFelix A. Aisien0Andrew N. Amenaghawon1Albert I. Adinkwuye2Department of Chemical Engineering, University of BeninDepartment of Chemical Engineering, University of BeninDepartment of Chemical Engineering, University of BeninThe potential use of waste tyre rubber granules (WTRG) for the batch adsorption of naphthalene from aqueous solutions was investigated. The effect of various operational variables such as contact time, initial naphthalene concentration, adsorbent dose, size of adsorbent particles, and temperature of solution on the adsorption capacity of WTRG was evaluated. The adsorption of naphthalene by WTRG was a fast kinetic process with an equilibrium contact time of 60 min. A low temperature (5°C), small adsorbent particle size (0.212 mm) and higher adsorbent dosage favored the adsorption process. Results of isotherm studies revealed that adsorption of naphthalene was best described by the Langmuir isotherm equation (R<sup>2</sup>=0.997) while the kinetics of the process was best described by the Lagergren pseudofirst order kinetic equation (R<sup>2</sup>=0.998). This study has demonstrated the suitability of WTRG for the removal of naphthalene from aqueous solution.http://www.pagepressjournals.org/index.php/xeno/article/view/2264adsorption, naphthalene, kinetics, adsorption capacity, isotherm.
spellingShingle Felix A. Aisien
Andrew N. Amenaghawon
Albert I. Adinkwuye
Batch study, equilibrium and kinetics of adsorption of naphthalene using waste tyre rubber granules
Journal of Xenobiotics
adsorption, naphthalene, kinetics, adsorption capacity, isotherm.
title Batch study, equilibrium and kinetics of adsorption of naphthalene using waste tyre rubber granules
title_full Batch study, equilibrium and kinetics of adsorption of naphthalene using waste tyre rubber granules
title_fullStr Batch study, equilibrium and kinetics of adsorption of naphthalene using waste tyre rubber granules
title_full_unstemmed Batch study, equilibrium and kinetics of adsorption of naphthalene using waste tyre rubber granules
title_short Batch study, equilibrium and kinetics of adsorption of naphthalene using waste tyre rubber granules
title_sort batch study equilibrium and kinetics of adsorption of naphthalene using waste tyre rubber granules
topic adsorption, naphthalene, kinetics, adsorption capacity, isotherm.
url http://www.pagepressjournals.org/index.php/xeno/article/view/2264
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AT andrewnamenaghawon batchstudyequilibriumandkineticsofadsorptionofnaphthaleneusingwastetyrerubbergranules
AT albertiadinkwuye batchstudyequilibriumandkineticsofadsorptionofnaphthaleneusingwastetyrerubbergranules