SYNTHESIS OF OXIMES WITH THE DOPED POTASSIUM FLUORIDE ANIMAL BONE MEAL AS A CATALYST
The potassium fluoride doped Animal Bone Meal (KF/ABM) was prepared and characterized using several techniques to identify the structural properties. After, it has been used as a new and eco-friendly catalyst for the preparation of from aldehydes and ketones oximes under solvent-free conditions. It...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2017-12-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201704&vol=4&aid=4637 |
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| author | M. AIT TALEB R. MAMOUNI N. SAFFAJ M. AIT BENOMAR A. BAKKA A. MOUNA A. BENLHACHEMI B. BAKIZ S. LAZAR |
| author_facet | M. AIT TALEB R. MAMOUNI N. SAFFAJ M. AIT BENOMAR A. BAKKA A. MOUNA A. BENLHACHEMI B. BAKIZ S. LAZAR |
| author_sort | M. AIT TALEB |
| collection | DOAJ |
| description | The potassium fluoride doped Animal Bone Meal (KF/ABM) was prepared and characterized using several techniques to identify the structural properties. After, it has been used as a new and eco-friendly catalyst for the preparation of from aldehydes and ketones oximes under solvent-free conditions. It is clearly shown that this reaction (using this catalyst) can lead to the corresponding oximes in good yields (80 %) to excellent yields (96 %). In the case of dissymmetric aldehydes and ketones, this catalyst can lead to a mixture of Z- and E- isomers (Z/E = 86/14–90/10). The remarkable advantages of this catalyst are high conversion, short reaction times, cleaner reaction profiles, reusability up to 8 times without significant loss of activity, and reduction in catalyst toxicity. |
| first_indexed | 2024-12-11T01:08:47Z |
| format | Article |
| id | doaj.art-73c4675a54a04f589e81356c024b0510 |
| institution | Directory Open Access Journal |
| issn | 1582-540X 1582-540X |
| language | English |
| last_indexed | 2024-12-11T01:08:47Z |
| publishDate | 2017-12-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj.art-73c4675a54a04f589e81356c024b05102022-12-22T01:26:06ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2017-12-01184417426SYNTHESIS OF OXIMES WITH THE DOPED POTASSIUM FLUORIDE ANIMAL BONE MEAL AS A CATALYSTM. AIT TALEB 0R. MAMOUNI 1N. SAFFAJ 2M. AIT BENOMAR 3 A. BAKKA 4A. MOUNA 5A. BENLHACHEMI6 B. BAKIZ7S. LAZAR 8Equipe de Matériaux, Catalyse & Valorisation des Ressources Naturelles/ Equipe de Chimie Bio-Organique Appliquée,Equipe de Matériaux, Catalyse & Valorisation des Ressources NaturellesEquipe de Matériaux, Catalyse & Valorisation des Ressources NaturellesEquipe de Matériaux, Catalyse & Valorisation des Ressources NaturellesEquipe de Matériaux, Catalyse & Valorisation des Ressources NaturellesEquipe de Chimie Bio-Organique Appliquée,Laboratoire de Matériaux & Environnement, Université Ibn Zohr, BP 8106, 80000 Agadir, MoroccoLaboratoire de Matériaux & Environnement, Université Ibn Zohr, BP 8106, 80000 Agadir, MoroccoLaboratoire de Biochimie, Environnement & Agroalimentaire, URAC 36, Université Hassan II-Casablanca, BP 146, 20650 Mohammedia, MoroccoThe potassium fluoride doped Animal Bone Meal (KF/ABM) was prepared and characterized using several techniques to identify the structural properties. After, it has been used as a new and eco-friendly catalyst for the preparation of from aldehydes and ketones oximes under solvent-free conditions. It is clearly shown that this reaction (using this catalyst) can lead to the corresponding oximes in good yields (80 %) to excellent yields (96 %). In the case of dissymmetric aldehydes and ketones, this catalyst can lead to a mixture of Z- and E- isomers (Z/E = 86/14–90/10). The remarkable advantages of this catalyst are high conversion, short reaction times, cleaner reaction profiles, reusability up to 8 times without significant loss of activity, and reduction in catalyst toxicity.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201704&vol=4&aid=4637animal bone mealcatalysteco-friendlyoximesreusable catalyst |
| spellingShingle | M. AIT TALEB R. MAMOUNI N. SAFFAJ M. AIT BENOMAR A. BAKKA A. MOUNA A. BENLHACHEMI B. BAKIZ S. LAZAR SYNTHESIS OF OXIMES WITH THE DOPED POTASSIUM FLUORIDE ANIMAL BONE MEAL AS A CATALYST Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry animal bone meal catalyst eco-friendly oximes reusable catalyst |
| title | SYNTHESIS OF OXIMES WITH THE DOPED POTASSIUM FLUORIDE ANIMAL BONE MEAL AS A CATALYST |
| title_full | SYNTHESIS OF OXIMES WITH THE DOPED POTASSIUM FLUORIDE ANIMAL BONE MEAL AS A CATALYST |
| title_fullStr | SYNTHESIS OF OXIMES WITH THE DOPED POTASSIUM FLUORIDE ANIMAL BONE MEAL AS A CATALYST |
| title_full_unstemmed | SYNTHESIS OF OXIMES WITH THE DOPED POTASSIUM FLUORIDE ANIMAL BONE MEAL AS A CATALYST |
| title_short | SYNTHESIS OF OXIMES WITH THE DOPED POTASSIUM FLUORIDE ANIMAL BONE MEAL AS A CATALYST |
| title_sort | synthesis of oximes with the doped potassium fluoride animal bone meal as a catalyst |
| topic | animal bone meal catalyst eco-friendly oximes reusable catalyst |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201704&vol=4&aid=4637 |
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