| Summary: | Abstract Bentonite is a key material for engineering barriers to prevent groundwater and nuclide migration in the multi-barrier system of high-level radioactive waste (HLW) geological disposal. However, its barrier property will be degraded under the action of iron corrosion products of steel disposal containers. In this paper, the effects of iron corrosion products on the degradation of bentonite structure and properties were investigated in the simulated environments for HLW geological disposal. The results showed that Fe2+/Fe3+ dissolved from iron powder could enter montmorillonite (Mt) interlayer and substituted part of Na+, which caused the decrease of the volume and interlayer spacing of Mt, and the structural integrity of Mt was destroyed. Macroscopically, the water absorption and swelling property of bentonite were significantly decreased. The degradation mechanism of Mt structure was mainly that Fe2+/Fe3+ generated by iron corrosion entered the interlayer domain of Mt to compensate for the interlayer charge deficit.
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