Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse
Different commercial reverse osmosis (RO) membranes from Vontron and DuPont Filmtec were evaluated for textile dyeing and finishing wastewater (TDFW) reuse in China. All six tested RO membranes produced qualified permeate meeting TDFW reuse standards at a water recovery ratio (WRR) of 70% in single...
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MDPI AG
2023-04-01
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author | Chunhai Wei Yequan Lao Rulu Ouyang Guorui Zhang Guijing Huang Feilong Deng Qicheng Tan Genghao Lin Hong Zhou |
author_facet | Chunhai Wei Yequan Lao Rulu Ouyang Guorui Zhang Guijing Huang Feilong Deng Qicheng Tan Genghao Lin Hong Zhou |
author_sort | Chunhai Wei |
collection | DOAJ |
description | Different commercial reverse osmosis (RO) membranes from Vontron and DuPont Filmtec were evaluated for textile dyeing and finishing wastewater (TDFW) reuse in China. All six tested RO membranes produced qualified permeate meeting TDFW reuse standards at a water recovery ratio (WRR) of 70% in single batch tests. The rapid decline of apparent specific flux at WRR over 50% was mainly ascribed to feed osmotic pressure increase caused by concentrating effects. Multiple batch tests using Vontron HOR and DuPont Filmtec BW RO membranes with comparable permeability and selectivity demonstrated the reproducibility and showed low fouling development. The occurrence of carbonate scaling on both RO membranes was identified by scanning electron microscopy and energy disperse spectroscopy. No obvious organic fouling was detected on both RO membranes by attenuated total reflectance Fourier transform infrared spectrometry. From the orthogonal tests, with an integrated RO membrane performance index (i.e., 25% rejection ratio of total organic carbon + 25% rejection ratio of conductivity + 50% flux ratio of final to initial) as a target, the optimal parameters were determined as WRR of 60%, cross-flow velocity (CFV) of 1.0 m/s, temperature (T) of 20 °C for both RO membranes, while trans-membrane pressures (TMP) of 2 and 4 MPa were optimal for Vontron HOR RO membrane and DuPont Filmtec BW RO membrane, respectively. Both RO membranes with the optimal parameters produced good permeate quality for TDFW reuse and kept a high flux ratio of final to initial, demonstrating the effectiveness of the orthogonal tests. |
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spelling | doaj.art-73e9cde0a081407281fcec9b609c24862023-11-17T20:23:21ZengMDPI AGMembranes2077-03752023-04-0113442010.3390/membranes13040420Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater ReuseChunhai Wei0Yequan Lao1Rulu Ouyang2Guorui Zhang3Guijing Huang4Feilong Deng5Qicheng Tan6Genghao Lin7Hong Zhou8Department of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Civil and Environmental Engineering, Texas A&M University, College Station, TX 77843-3122, USADepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDifferent commercial reverse osmosis (RO) membranes from Vontron and DuPont Filmtec were evaluated for textile dyeing and finishing wastewater (TDFW) reuse in China. All six tested RO membranes produced qualified permeate meeting TDFW reuse standards at a water recovery ratio (WRR) of 70% in single batch tests. The rapid decline of apparent specific flux at WRR over 50% was mainly ascribed to feed osmotic pressure increase caused by concentrating effects. Multiple batch tests using Vontron HOR and DuPont Filmtec BW RO membranes with comparable permeability and selectivity demonstrated the reproducibility and showed low fouling development. The occurrence of carbonate scaling on both RO membranes was identified by scanning electron microscopy and energy disperse spectroscopy. No obvious organic fouling was detected on both RO membranes by attenuated total reflectance Fourier transform infrared spectrometry. From the orthogonal tests, with an integrated RO membrane performance index (i.e., 25% rejection ratio of total organic carbon + 25% rejection ratio of conductivity + 50% flux ratio of final to initial) as a target, the optimal parameters were determined as WRR of 60%, cross-flow velocity (CFV) of 1.0 m/s, temperature (T) of 20 °C for both RO membranes, while trans-membrane pressures (TMP) of 2 and 4 MPa were optimal for Vontron HOR RO membrane and DuPont Filmtec BW RO membrane, respectively. Both RO membranes with the optimal parameters produced good permeate quality for TDFW reuse and kept a high flux ratio of final to initial, demonstrating the effectiveness of the orthogonal tests.https://www.mdpi.com/2077-0375/13/4/420concentration polarizationorthogonal testosmotic pressurereverse osmosistextile dyeing and finishing wastewaterwater recovery ratio |
spellingShingle | Chunhai Wei Yequan Lao Rulu Ouyang Guorui Zhang Guijing Huang Feilong Deng Qicheng Tan Genghao Lin Hong Zhou Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse Membranes concentration polarization orthogonal test osmotic pressure reverse osmosis textile dyeing and finishing wastewater water recovery ratio |
title | Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse |
title_full | Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse |
title_fullStr | Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse |
title_full_unstemmed | Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse |
title_short | Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse |
title_sort | evaluation of different reverse osmosis membranes for textile dyeing and finishing wastewater reuse |
topic | concentration polarization orthogonal test osmotic pressure reverse osmosis textile dyeing and finishing wastewater water recovery ratio |
url | https://www.mdpi.com/2077-0375/13/4/420 |
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