Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse

Different commercial reverse osmosis (RO) membranes from Vontron and DuPont Filmtec were evaluated for textile dyeing and finishing wastewater (TDFW) reuse in China. All six tested RO membranes produced qualified permeate meeting TDFW reuse standards at a water recovery ratio (WRR) of 70% in single...

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Main Authors: Chunhai Wei, Yequan Lao, Rulu Ouyang, Guorui Zhang, Guijing Huang, Feilong Deng, Qicheng Tan, Genghao Lin, Hong Zhou
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/13/4/420
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author Chunhai Wei
Yequan Lao
Rulu Ouyang
Guorui Zhang
Guijing Huang
Feilong Deng
Qicheng Tan
Genghao Lin
Hong Zhou
author_facet Chunhai Wei
Yequan Lao
Rulu Ouyang
Guorui Zhang
Guijing Huang
Feilong Deng
Qicheng Tan
Genghao Lin
Hong Zhou
author_sort Chunhai Wei
collection DOAJ
description Different commercial reverse osmosis (RO) membranes from Vontron and DuPont Filmtec were evaluated for textile dyeing and finishing wastewater (TDFW) reuse in China. All six tested RO membranes produced qualified permeate meeting TDFW reuse standards at a water recovery ratio (WRR) of 70% in single batch tests. The rapid decline of apparent specific flux at WRR over 50% was mainly ascribed to feed osmotic pressure increase caused by concentrating effects. Multiple batch tests using Vontron HOR and DuPont Filmtec BW RO membranes with comparable permeability and selectivity demonstrated the reproducibility and showed low fouling development. The occurrence of carbonate scaling on both RO membranes was identified by scanning electron microscopy and energy disperse spectroscopy. No obvious organic fouling was detected on both RO membranes by attenuated total reflectance Fourier transform infrared spectrometry. From the orthogonal tests, with an integrated RO membrane performance index (i.e., 25% rejection ratio of total organic carbon + 25% rejection ratio of conductivity + 50% flux ratio of final to initial) as a target, the optimal parameters were determined as WRR of 60%, cross-flow velocity (CFV) of 1.0 m/s, temperature (T) of 20 °C for both RO membranes, while trans-membrane pressures (TMP) of 2 and 4 MPa were optimal for Vontron HOR RO membrane and DuPont Filmtec BW RO membrane, respectively. Both RO membranes with the optimal parameters produced good permeate quality for TDFW reuse and kept a high flux ratio of final to initial, demonstrating the effectiveness of the orthogonal tests.
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spelling doaj.art-73e9cde0a081407281fcec9b609c24862023-11-17T20:23:21ZengMDPI AGMembranes2077-03752023-04-0113442010.3390/membranes13040420Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater ReuseChunhai Wei0Yequan Lao1Rulu Ouyang2Guorui Zhang3Guijing Huang4Feilong Deng5Qicheng Tan6Genghao Lin7Hong Zhou8Department of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Civil and Environmental Engineering, Texas A&M University, College Station, TX 77843-3122, USADepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDepartment of Municipal Engineering, School of Civil Engineering, Guangzhou University, Guangzhou 510006, ChinaDifferent commercial reverse osmosis (RO) membranes from Vontron and DuPont Filmtec were evaluated for textile dyeing and finishing wastewater (TDFW) reuse in China. All six tested RO membranes produced qualified permeate meeting TDFW reuse standards at a water recovery ratio (WRR) of 70% in single batch tests. The rapid decline of apparent specific flux at WRR over 50% was mainly ascribed to feed osmotic pressure increase caused by concentrating effects. Multiple batch tests using Vontron HOR and DuPont Filmtec BW RO membranes with comparable permeability and selectivity demonstrated the reproducibility and showed low fouling development. The occurrence of carbonate scaling on both RO membranes was identified by scanning electron microscopy and energy disperse spectroscopy. No obvious organic fouling was detected on both RO membranes by attenuated total reflectance Fourier transform infrared spectrometry. From the orthogonal tests, with an integrated RO membrane performance index (i.e., 25% rejection ratio of total organic carbon + 25% rejection ratio of conductivity + 50% flux ratio of final to initial) as a target, the optimal parameters were determined as WRR of 60%, cross-flow velocity (CFV) of 1.0 m/s, temperature (T) of 20 °C for both RO membranes, while trans-membrane pressures (TMP) of 2 and 4 MPa were optimal for Vontron HOR RO membrane and DuPont Filmtec BW RO membrane, respectively. Both RO membranes with the optimal parameters produced good permeate quality for TDFW reuse and kept a high flux ratio of final to initial, demonstrating the effectiveness of the orthogonal tests.https://www.mdpi.com/2077-0375/13/4/420concentration polarizationorthogonal testosmotic pressurereverse osmosistextile dyeing and finishing wastewaterwater recovery ratio
spellingShingle Chunhai Wei
Yequan Lao
Rulu Ouyang
Guorui Zhang
Guijing Huang
Feilong Deng
Qicheng Tan
Genghao Lin
Hong Zhou
Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse
Membranes
concentration polarization
orthogonal test
osmotic pressure
reverse osmosis
textile dyeing and finishing wastewater
water recovery ratio
title Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse
title_full Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse
title_fullStr Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse
title_full_unstemmed Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse
title_short Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse
title_sort evaluation of different reverse osmosis membranes for textile dyeing and finishing wastewater reuse
topic concentration polarization
orthogonal test
osmotic pressure
reverse osmosis
textile dyeing and finishing wastewater
water recovery ratio
url https://www.mdpi.com/2077-0375/13/4/420
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