Study of sulfur dioxide adsorption on Y zeolite
Sulfur dioxide adsorptive properties of Y zeolite, the structure of which was confirmed by XRD, were investigated at temperatures within the 25200 ºC range and sulfur dioxide concentrations between 0.9 to 6 % (vol./vol.). It was found that this sorbent possesses a relatively high adsorption capacity...
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Format: | Article |
Language: | English |
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Serbian Chemical Society
2004-07-01
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Series: | Journal of the Serbian Chemical Society |
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Online Access: | http://www.shd.org.yu/HtDocs/SHD/Vol69/No7/V69-No7-07.pdf |
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author | IOAN SANDULESCU IOAN-CEZAR MARCU |
author_facet | IOAN SANDULESCU IOAN-CEZAR MARCU |
author_sort | IOAN SANDULESCU |
collection | DOAJ |
description | Sulfur dioxide adsorptive properties of Y zeolite, the structure of which was confirmed by XRD, were investigated at temperatures within the 25200 ºC range and sulfur dioxide concentrations between 0.9 to 6 % (vol./vol.). It was found that this sorbent possesses a relatively high adsorption capacity. The Y zeolite did not lose its activity during 20 adsorption-desorption-regeneration cycles. The manner in which sulfur dioxide is adsorbed on Y type zeolite was also investigated by analyzing the sample with and without adsorbed SO2, using IR spectroscopy, as well as total and Lewis acidity measurements. The sulfur dioxide molecule is probably adsorbed by hydrogen bonding to one or two conveniently positioned surface hydroxyl groups. |
first_indexed | 2024-12-19T08:33:51Z |
format | Article |
id | doaj.art-7402a0ea9ddd494ca331752091cac83a |
institution | Directory Open Access Journal |
issn | 0352-5139 |
language | English |
last_indexed | 2024-12-19T08:33:51Z |
publishDate | 2004-07-01 |
publisher | Serbian Chemical Society |
record_format | Article |
series | Journal of the Serbian Chemical Society |
spelling | doaj.art-7402a0ea9ddd494ca331752091cac83a2022-12-21T20:29:07ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392004-07-01697563569Study of sulfur dioxide adsorption on Y zeoliteIOAN SANDULESCUIOAN-CEZAR MARCUSulfur dioxide adsorptive properties of Y zeolite, the structure of which was confirmed by XRD, were investigated at temperatures within the 25200 ºC range and sulfur dioxide concentrations between 0.9 to 6 % (vol./vol.). It was found that this sorbent possesses a relatively high adsorption capacity. The Y zeolite did not lose its activity during 20 adsorption-desorption-regeneration cycles. The manner in which sulfur dioxide is adsorbed on Y type zeolite was also investigated by analyzing the sample with and without adsorbed SO2, using IR spectroscopy, as well as total and Lewis acidity measurements. The sulfur dioxide molecule is probably adsorbed by hydrogen bonding to one or two conveniently positioned surface hydroxyl groups.http://www.shd.org.yu/HtDocs/SHD/Vol69/No7/V69-No7-07.pdfsulfur dioxideadsorptionY zeolitedesulfurization |
spellingShingle | IOAN SANDULESCU IOAN-CEZAR MARCU Study of sulfur dioxide adsorption on Y zeolite Journal of the Serbian Chemical Society sulfur dioxide adsorption Y zeolite desulfurization |
title | Study of sulfur dioxide adsorption on Y zeolite |
title_full | Study of sulfur dioxide adsorption on Y zeolite |
title_fullStr | Study of sulfur dioxide adsorption on Y zeolite |
title_full_unstemmed | Study of sulfur dioxide adsorption on Y zeolite |
title_short | Study of sulfur dioxide adsorption on Y zeolite |
title_sort | study of sulfur dioxide adsorption on y zeolite |
topic | sulfur dioxide adsorption Y zeolite desulfurization |
url | http://www.shd.org.yu/HtDocs/SHD/Vol69/No7/V69-No7-07.pdf |
work_keys_str_mv | AT ioansandulescu studyofsulfurdioxideadsorptiononyzeolite AT ioancezarmarcu studyofsulfurdioxideadsorptiononyzeolite |