Superhydrophobic Modification of Biomass Cuttlebone Applied to Oil Spill Remediation
The spills of crude oil and other organic chemicals are common around the world, resulting in severe damage to the environment and ecosystem. Therefore, developing low-cost and eco-friendly absorption material is in urgent need. In this study, we report a superhydrophobic and oleophilic porous mater...
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2022-06-01
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author | Junfei Xu Pengchao Che Hailong Zhang Yuliang Zhang Jun Wu Weiqi Li Jizhong He Zhihui Ma Tengfei Li Yunyuan Dong Jianping Yu Ruiping Tong |
author_facet | Junfei Xu Pengchao Che Hailong Zhang Yuliang Zhang Jun Wu Weiqi Li Jizhong He Zhihui Ma Tengfei Li Yunyuan Dong Jianping Yu Ruiping Tong |
author_sort | Junfei Xu |
collection | DOAJ |
description | The spills of crude oil and other organic chemicals are common around the world, resulting in severe damage to the environment and ecosystem. Therefore, developing low-cost and eco-friendly absorption material is in urgent need. In this study, we report a superhydrophobic and oleophilic porous material using biomass cuttlebone as the scaffold. A layer of polydopamine is grafted on the cuttlebone as the adhesion layer between the cuttlebone and the superhydrophobic coating. The in situ grown silica micro/nanoparticles on top of the adhesion layer provide the anchoring spots for grafting the fluorinated hydrocarbon and a rough topography for realizing superhydrophobicity. The static water contact angle of the superhydrophobic cuttlebone reaches 152°, and its oil contact angle is ~0°. The excellent oil–water separation efficiency of the prepared superhydrophobic cuttlebone is demonstrated using high-density oil/water mixtures and low-density oil/water mixtures. |
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institution | Directory Open Access Journal |
issn | 1996-1944 |
language | English |
last_indexed | 2024-03-09T04:03:37Z |
publishDate | 2022-06-01 |
publisher | MDPI AG |
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spelling | doaj.art-74042bccefe645569b5cf241ac0d6e422023-12-03T14:09:34ZengMDPI AGMaterials1996-19442022-06-011513440110.3390/ma15134401Superhydrophobic Modification of Biomass Cuttlebone Applied to Oil Spill RemediationJunfei Xu0Pengchao Che1Hailong Zhang2Yuliang Zhang3Jun Wu4Weiqi Li5Jizhong He6Zhihui Ma7Tengfei Li8Yunyuan Dong9Jianping Yu10Ruiping Tong11Key Laboratory of Air-Driven Equipment of Zhejiang Province, College of Mechanical Engineering, Quzhou University, Quzhou 324000, ChinaKey Laboratory of Air-Driven Equipment of Zhejiang Province, College of Mechanical Engineering, Quzhou University, Quzhou 324000, ChinaKey Laboratory of Air-Driven Equipment of Zhejiang Province, College of Mechanical Engineering, Quzhou University, Quzhou 324000, ChinaKey Laboratory of Air-Driven Equipment of Zhejiang Province, College of Mechanical Engineering, Quzhou University, Quzhou 324000, ChinaKey Laboratory of Air-Driven Equipment of Zhejiang Province, College of Mechanical Engineering, Quzhou University, Quzhou 324000, ChinaKey Laboratory of Air-Driven Equipment of Zhejiang Province, College of Mechanical Engineering, Quzhou University, Quzhou 324000, ChinaKey Laboratory of Air-Driven Equipment of Zhejiang Province, College of Mechanical Engineering, Quzhou University, Quzhou 324000, ChinaKey Laboratory of Air-Driven Equipment of Zhejiang Province, College of Mechanical Engineering, Quzhou University, Quzhou 324000, ChinaKey Laboratory of Air-Driven Equipment of Zhejiang Province, College of Mechanical Engineering, Quzhou University, Quzhou 324000, ChinaCollege of Chemical & Materials Engineering, Quzhou University, Quzhou 324000, ChinaKey Laboratory of Air-Driven Equipment of Zhejiang Province, College of Mechanical Engineering, Quzhou University, Quzhou 324000, ChinaKey Laboratory of Air-Driven Equipment of Zhejiang Province, College of Mechanical Engineering, Quzhou University, Quzhou 324000, ChinaThe spills of crude oil and other organic chemicals are common around the world, resulting in severe damage to the environment and ecosystem. Therefore, developing low-cost and eco-friendly absorption material is in urgent need. In this study, we report a superhydrophobic and oleophilic porous material using biomass cuttlebone as the scaffold. A layer of polydopamine is grafted on the cuttlebone as the adhesion layer between the cuttlebone and the superhydrophobic coating. The in situ grown silica micro/nanoparticles on top of the adhesion layer provide the anchoring spots for grafting the fluorinated hydrocarbon and a rough topography for realizing superhydrophobicity. The static water contact angle of the superhydrophobic cuttlebone reaches 152°, and its oil contact angle is ~0°. The excellent oil–water separation efficiency of the prepared superhydrophobic cuttlebone is demonstrated using high-density oil/water mixtures and low-density oil/water mixtures.https://www.mdpi.com/1996-1944/15/13/4401seafood byproductcuttlebonebiomasssuperhydrophobicityoil spill remediation |
spellingShingle | Junfei Xu Pengchao Che Hailong Zhang Yuliang Zhang Jun Wu Weiqi Li Jizhong He Zhihui Ma Tengfei Li Yunyuan Dong Jianping Yu Ruiping Tong Superhydrophobic Modification of Biomass Cuttlebone Applied to Oil Spill Remediation Materials seafood byproduct cuttlebone biomass superhydrophobicity oil spill remediation |
title | Superhydrophobic Modification of Biomass Cuttlebone Applied to Oil Spill Remediation |
title_full | Superhydrophobic Modification of Biomass Cuttlebone Applied to Oil Spill Remediation |
title_fullStr | Superhydrophobic Modification of Biomass Cuttlebone Applied to Oil Spill Remediation |
title_full_unstemmed | Superhydrophobic Modification of Biomass Cuttlebone Applied to Oil Spill Remediation |
title_short | Superhydrophobic Modification of Biomass Cuttlebone Applied to Oil Spill Remediation |
title_sort | superhydrophobic modification of biomass cuttlebone applied to oil spill remediation |
topic | seafood byproduct cuttlebone biomass superhydrophobicity oil spill remediation |
url | https://www.mdpi.com/1996-1944/15/13/4401 |
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