Crystal structure of 3-amino-1-propylpyridinium bromide
The title molecular salt, C8H13N2+·Br−, crystallizes with two independent 3-aminopyridinium cations and two bromide anions in the asymmetric unit (Z′ = 2). In the pyridine ring, the N atom is alkylated by a propyl group. The dihedral angle between the mean planes of the pyridinium ring and the propy...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-12-01
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| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814025665 |
| _version_ | 1818958162943803392 |
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| author | P. Venkatesan V. Rajakannan S. Thamotharan |
| author_facet | P. Venkatesan V. Rajakannan S. Thamotharan |
| author_sort | P. Venkatesan |
| collection | DOAJ |
| description | The title molecular salt, C8H13N2+·Br−, crystallizes with two independent 3-aminopyridinium cations and two bromide anions in the asymmetric unit (Z′ = 2). In the pyridine ring, the N atom is alkylated by a propyl group. The dihedral angle between the mean planes of the pyridinium ring and the propyl group is 84.84 (2)° in cation A, whereas the corresponding angle is 89.23 (2)° in cation B. In the crystal, the anions and cations are linked via N—H...Br and C—H...Br hydrogen bonds, forming chains propagating along [100]. |
| first_indexed | 2024-12-20T11:21:22Z |
| format | Article |
| id | doaj.art-7473d926e68642d199ee123a587feb78 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:21:22Z |
| publishDate | 2014-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7473d926e68642d199ee123a587feb782022-12-21T19:42:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-12-01701258058310.1107/S1600536814025665su5025Crystal structure of 3-amino-1-propylpyridinium bromideP. Venkatesan0V. Rajakannan1S. Thamotharan2School of Chemistry, Bharathidasan University, Tiruchirappalli 620 024, IndiaCentre of Advanced Study in Crystallography and Biophysics, University of Madras, Chennai 600 025, IndiaDepartment of Bioinformatics, School of Chemical and Biotechnology, SASTRA University, Thanjavur 613 401, IndiaThe title molecular salt, C8H13N2+·Br−, crystallizes with two independent 3-aminopyridinium cations and two bromide anions in the asymmetric unit (Z′ = 2). In the pyridine ring, the N atom is alkylated by a propyl group. The dihedral angle between the mean planes of the pyridinium ring and the propyl group is 84.84 (2)° in cation A, whereas the corresponding angle is 89.23 (2)° in cation B. In the crystal, the anions and cations are linked via N—H...Br and C—H...Br hydrogen bonds, forming chains propagating along [100].http://scripts.iucr.org/cgi-bin/paper?S1600536814025665crystal structuremolecular saltpyridinium saltN—H...Br hydrogen bondsC—H...Br hydrogen bonds |
| spellingShingle | P. Venkatesan V. Rajakannan S. Thamotharan Crystal structure of 3-amino-1-propylpyridinium bromide Acta Crystallographica Section E crystal structure molecular salt pyridinium salt N—H...Br hydrogen bonds C—H...Br hydrogen bonds |
| title | Crystal structure of 3-amino-1-propylpyridinium bromide |
| title_full | Crystal structure of 3-amino-1-propylpyridinium bromide |
| title_fullStr | Crystal structure of 3-amino-1-propylpyridinium bromide |
| title_full_unstemmed | Crystal structure of 3-amino-1-propylpyridinium bromide |
| title_short | Crystal structure of 3-amino-1-propylpyridinium bromide |
| title_sort | crystal structure of 3 amino 1 propylpyridinium bromide |
| topic | crystal structure molecular salt pyridinium salt N—H...Br hydrogen bonds C—H...Br hydrogen bonds |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814025665 |
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