trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN1)nickel(II)
In the mononuclear NiII title complex, [Ni(C7H4FO2)2(C6H6N2O)2(H2O)2], the NiII atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluorobenzoate ligands and two water molecules in a distorted N2O4 octahedral geometry. The dihedral angle between the carboxylate group...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811044771 |
| _version_ | 1819107612329771008 |
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| author | Hacali Necefoğlu Vijdan Öztürk Füreya Elif Özbek Vedat Adıgüzel Tuncer Hökelek |
| author_facet | Hacali Necefoğlu Vijdan Öztürk Füreya Elif Özbek Vedat Adıgüzel Tuncer Hökelek |
| author_sort | Hacali Necefoğlu |
| collection | DOAJ |
| description | In the mononuclear NiII title complex, [Ni(C7H4FO2)2(C6H6N2O)2(H2O)2], the NiII atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluorobenzoate ligands and two water molecules in a distorted N2O4 octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 8.95 (8)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 75.01 (7)°. The water molecule links the adjacent carboxylate O atom via an intramolecular O—H...O hydrogen bond. In the crystal, O—H...O, N—H...O, C—H...O and C—H...F hydrogen bonds link the molecules into a three-dimensional network. π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.7287 (11) Å] is also observed. |
| first_indexed | 2024-12-22T02:56:48Z |
| format | Article |
| id | doaj.art-749de8a366c14ff489deb6fd3f941c32 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:56:48Z |
| publishDate | 2011-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-749de8a366c14ff489deb6fd3f941c322022-12-21T18:41:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711m1638m163910.1107/S1600536811044771trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN1)nickel(II)Hacali NecefoğluVijdan ÖztürkFüreya Elif ÖzbekVedat AdıgüzelTuncer HökelekIn the mononuclear NiII title complex, [Ni(C7H4FO2)2(C6H6N2O)2(H2O)2], the NiII atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluorobenzoate ligands and two water molecules in a distorted N2O4 octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 8.95 (8)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 75.01 (7)°. The water molecule links the adjacent carboxylate O atom via an intramolecular O—H...O hydrogen bond. In the crystal, O—H...O, N—H...O, C—H...O and C—H...F hydrogen bonds link the molecules into a three-dimensional network. π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.7287 (11) Å] is also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536811044771 |
| spellingShingle | Hacali Necefoğlu Vijdan Öztürk Füreya Elif Özbek Vedat Adıgüzel Tuncer Hökelek trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN1)nickel(II) Acta Crystallographica Section E |
| title | trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN1)nickel(II) |
| title_full | trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN1)nickel(II) |
| title_fullStr | trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN1)nickel(II) |
| title_full_unstemmed | trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN1)nickel(II) |
| title_short | trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN1)nickel(II) |
| title_sort | trans diaquabis 4 fluorobenzoato amp 954 o bis nicotinamide amp 954 n1 nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811044771 |
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