Hydrothermal synthesis of CdO nanoparticles for photocatalytic and antimicrobial activities

CdO is an II-IV group n-type semiconductor coming under the non stochiometric condition such as interstitial cadmium or oxygen vacancies. CdO nanoparticles having the direct band gap of 2.5 ​eV with an indirect band gap of 1.96 ​eV. CdO nanoparticles were synthesized by using hydrothermal method. Th...

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Main Authors: Gopi Somasundaram, Jayaprakash Rajan, P. Sangaiya, R. Dilip
Format: Article
Language:English
Published: Elsevier 2019-12-01
Series:Results in Materials
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590048X19300445
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author Gopi Somasundaram
Jayaprakash Rajan
P. Sangaiya
R. Dilip
author_facet Gopi Somasundaram
Jayaprakash Rajan
P. Sangaiya
R. Dilip
author_sort Gopi Somasundaram
collection DOAJ
description CdO is an II-IV group n-type semiconductor coming under the non stochiometric condition such as interstitial cadmium or oxygen vacancies. CdO nanoparticles having the direct band gap of 2.5 ​eV with an indirect band gap of 1.96 ​eV. CdO nanoparticles were synthesized by using hydrothermal method. The main raw materials used for CdO nanoparticles are cadmium nitrate and ammonium hydroxide. This sample was characterized by XRD, UV-DRS, TEM, FE-SEM with EDS and FTIR. It exhibits simple cubic structure with an average crystallite size of 27 ​nm. The surface morphological image displays spherical like structure with agglomeration. The vibrational stretching mode of Cd–O is 493 ​cm−1. The optical energy bandgap is estimated as 2.56 ​eV. The significant antimicrobial activities were studied against gram negative (Escherichia coli) and gram positive (Staphylococcus aureus) bacteria. The zone of inhibition is found to be more for gram negative than gram positive bacteria. The photocatalytic activity of cationic dye is also studied for hydrothermally prepared CdO nanoparticles.
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spelling doaj.art-74c415d784d04ca083e3d10f82ca2b812022-12-22T00:23:01ZengElsevierResults in Materials2590-048X2019-12-014100044Hydrothermal synthesis of CdO nanoparticles for photocatalytic and antimicrobial activitiesGopi Somasundaram0Jayaprakash Rajan1P. Sangaiya2R. Dilip3Corresponding author.; Department of Physics, Nanotechnology Laboratory, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, 641020, IndiaDepartment of Physics, Nanotechnology Laboratory, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, 641020, IndiaDepartment of Physics, Nanotechnology Laboratory, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, 641020, IndiaDepartment of Physics, Nanotechnology Laboratory, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, 641020, IndiaCdO is an II-IV group n-type semiconductor coming under the non stochiometric condition such as interstitial cadmium or oxygen vacancies. CdO nanoparticles having the direct band gap of 2.5 ​eV with an indirect band gap of 1.96 ​eV. CdO nanoparticles were synthesized by using hydrothermal method. The main raw materials used for CdO nanoparticles are cadmium nitrate and ammonium hydroxide. This sample was characterized by XRD, UV-DRS, TEM, FE-SEM with EDS and FTIR. It exhibits simple cubic structure with an average crystallite size of 27 ​nm. The surface morphological image displays spherical like structure with agglomeration. The vibrational stretching mode of Cd–O is 493 ​cm−1. The optical energy bandgap is estimated as 2.56 ​eV. The significant antimicrobial activities were studied against gram negative (Escherichia coli) and gram positive (Staphylococcus aureus) bacteria. The zone of inhibition is found to be more for gram negative than gram positive bacteria. The photocatalytic activity of cationic dye is also studied for hydrothermally prepared CdO nanoparticles.http://www.sciencedirect.com/science/article/pii/S2590048X19300445Crystalline sizeAgglomerationBand gapCationicInhibition
spellingShingle Gopi Somasundaram
Jayaprakash Rajan
P. Sangaiya
R. Dilip
Hydrothermal synthesis of CdO nanoparticles for photocatalytic and antimicrobial activities
Results in Materials
Crystalline size
Agglomeration
Band gap
Cationic
Inhibition
title Hydrothermal synthesis of CdO nanoparticles for photocatalytic and antimicrobial activities
title_full Hydrothermal synthesis of CdO nanoparticles for photocatalytic and antimicrobial activities
title_fullStr Hydrothermal synthesis of CdO nanoparticles for photocatalytic and antimicrobial activities
title_full_unstemmed Hydrothermal synthesis of CdO nanoparticles for photocatalytic and antimicrobial activities
title_short Hydrothermal synthesis of CdO nanoparticles for photocatalytic and antimicrobial activities
title_sort hydrothermal synthesis of cdo nanoparticles for photocatalytic and antimicrobial activities
topic Crystalline size
Agglomeration
Band gap
Cationic
Inhibition
url http://www.sciencedirect.com/science/article/pii/S2590048X19300445
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