A new insight into the unique magneto‐optical effect of layered perovskite (C6H5C2H3FNH3)2MnCl4
Abstract Magnet‐optical materials embracing coupled magnetic and photoluminescent properties in single phase are promising in microelectronics and optoelectronic devices. However, the current research mainly focuses on traditional inorganic materials, and there are few reports on molecule materials....
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Wiley
2023-06-01
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| Series: | Aggregate |
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| Online Access: | https://doi.org/10.1002/agt2.294 |
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| author | Zhao‐Bo Hu Long‐He Li Yibo Han Jinlei Zhang Jianrong Li Zilu Chen Shuyi Wu Yi Zhang Heng‐Yun Ye You Song |
| author_facet | Zhao‐Bo Hu Long‐He Li Yibo Han Jinlei Zhang Jianrong Li Zilu Chen Shuyi Wu Yi Zhang Heng‐Yun Ye You Song |
| author_sort | Zhao‐Bo Hu |
| collection | DOAJ |
| description | Abstract Magnet‐optical materials embracing coupled magnetic and photoluminescent properties in single phase are promising in microelectronics and optoelectronic devices. However, the current research mainly focuses on traditional inorganic materials, and there are few reports on molecule materials. Recently, we synthesized an organic–inorganic hybrid complex (C6H5C2H3FNH3)2MnCl4 (1) with perovskite structure. Physical measurements show that 1 not only behaves as an antiferromagnet with spin canting but also exhibits unusual fluorescent properties. Importantly, under the magnetic field at different temperatures, the luminous intensity of 1 changed, and a red‐shift occurred with obviously optical hysteresis. These phenomena directly prove the existence of magneto‐optical coupling in 1. More interestingly, the optical hysteresis can be observed in both low and high field, which is unprecedented in other molecular materials. Even in traditional inorganic materials, it can only be observed in strong field. This special function provides the possibility for the application of low energy consumption optoelectronic devices. |
| first_indexed | 2024-03-13T03:54:55Z |
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| id | doaj.art-74c9c82439f543b0b76f88ad9b0083a6 |
| institution | Directory Open Access Journal |
| issn | 2692-4560 |
| language | English |
| last_indexed | 2024-03-13T03:54:55Z |
| publishDate | 2023-06-01 |
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| spelling | doaj.art-74c9c82439f543b0b76f88ad9b0083a62023-06-22T06:24:45ZengWileyAggregate2692-45602023-06-0143n/an/a10.1002/agt2.294A new insight into the unique magneto‐optical effect of layered perovskite (C6H5C2H3FNH3)2MnCl4Zhao‐Bo Hu0Long‐He Li1Yibo Han2Jinlei Zhang3Jianrong Li4Zilu Chen5Shuyi Wu6Yi Zhang7Heng‐Yun Ye8You Song9State Key Laboratory of Coordination Chemistry School of Chemistry and Chemical Engineering Nanjing University Nanjing PR ChinaChaotic Matter Science Research Center Faculty of Materials Metallurgy and Chemistry Jiangxi University of Science and Technology Ganzhou PR ChinaWuhan National High Magnetic Field Center and School of Physics Huazhong University of Science and Technology Wuhan PR ChinaJiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application School of Physical Science and Technology Suzhou University of Science and Technology Suzhou PR ChinaChaotic Matter Science Research Center Faculty of Materials Metallurgy and Chemistry Jiangxi University of Science and Technology Ganzhou PR ChinaState Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources School of Chemistry and Pharmaceutical Sciences Guangxi Normal University Guilin PR ChinaJiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application School of Physical Science and Technology Suzhou University of Science and Technology Suzhou PR ChinaChaotic Matter Science Research Center Faculty of Materials Metallurgy and Chemistry Jiangxi University of Science and Technology Ganzhou PR ChinaChaotic Matter Science Research Center Faculty of Materials Metallurgy and Chemistry Jiangxi University of Science and Technology Ganzhou PR ChinaState Key Laboratory of Coordination Chemistry School of Chemistry and Chemical Engineering Nanjing University Nanjing PR ChinaAbstract Magnet‐optical materials embracing coupled magnetic and photoluminescent properties in single phase are promising in microelectronics and optoelectronic devices. However, the current research mainly focuses on traditional inorganic materials, and there are few reports on molecule materials. Recently, we synthesized an organic–inorganic hybrid complex (C6H5C2H3FNH3)2MnCl4 (1) with perovskite structure. Physical measurements show that 1 not only behaves as an antiferromagnet with spin canting but also exhibits unusual fluorescent properties. Importantly, under the magnetic field at different temperatures, the luminous intensity of 1 changed, and a red‐shift occurred with obviously optical hysteresis. These phenomena directly prove the existence of magneto‐optical coupling in 1. More interestingly, the optical hysteresis can be observed in both low and high field, which is unprecedented in other molecular materials. Even in traditional inorganic materials, it can only be observed in strong field. This special function provides the possibility for the application of low energy consumption optoelectronic devices.https://doi.org/10.1002/agt2.294magnetic ordermagneto‐optical effectoptical hysteresisoptical phenomena |
| spellingShingle | Zhao‐Bo Hu Long‐He Li Yibo Han Jinlei Zhang Jianrong Li Zilu Chen Shuyi Wu Yi Zhang Heng‐Yun Ye You Song A new insight into the unique magneto‐optical effect of layered perovskite (C6H5C2H3FNH3)2MnCl4 Aggregate magnetic order magneto‐optical effect optical hysteresis optical phenomena |
| title | A new insight into the unique magneto‐optical effect of layered perovskite (C6H5C2H3FNH3)2MnCl4 |
| title_full | A new insight into the unique magneto‐optical effect of layered perovskite (C6H5C2H3FNH3)2MnCl4 |
| title_fullStr | A new insight into the unique magneto‐optical effect of layered perovskite (C6H5C2H3FNH3)2MnCl4 |
| title_full_unstemmed | A new insight into the unique magneto‐optical effect of layered perovskite (C6H5C2H3FNH3)2MnCl4 |
| title_short | A new insight into the unique magneto‐optical effect of layered perovskite (C6H5C2H3FNH3)2MnCl4 |
| title_sort | new insight into the unique magneto optical effect of layered perovskite c6h5c2h3fnh3 2mncl4 |
| topic | magnetic order magneto‐optical effect optical hysteresis optical phenomena |
| url | https://doi.org/10.1002/agt2.294 |
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