Site-Selective Solvation-Induced Conformational Switching of Heteroleptic Heteronuclear Tb(III) and Y(III) Trisphthalocyaninates for the Control of Their Magnetic Anisotropy

Site-Selective Solvation-Induced Conformational Switching of Heteroleptic Heteronuclear Tb(III) and Y(III) Trisphthalocyaninates for the Control of Their Magnetic Anisotropy

In the present work, we report the synthesis of isomeric heteronuclear terbium(III) and yttrium(III) triple-decker phthalocyaninates <b>[(BuO)<sub>8</sub>Pc]M[(BuO)<sub>8</sub>Pc]M*[(15C5)<sub>4</sub>Pc]</b> (M = Tb, M* = Y or M = Y, M* = Tb, [(BuO)<...

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Bibliographic Details
Main Authors: Alexander G. Martynov, Kirill P. Birin, Gayane A. Kirakosyan, Yulia G. Gorbunova, Aslan Yu. Tsivadze
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Molecules
Subjects:
triple-decker phthalocyaninate
terbium
lanthanide-induced shift
axial magnetic anisotropy
conformational switching
solvation
Online Access:https://www.mdpi.com/1420-3049/28/11/4474

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