catena-Poly[[[diaquaterbium(III)]-tri-μ2-isonicotinato-κ6O:O′] tris(perchlorate) monohydrate]
In the title complex, {[Tb(C6H5NO2)3(H2O)2](ClO4)3·H2O}n, the TbIII ion is coordinated by six O atoms from six isonicotinate (inic) ligands and two water molecules, displaying a bicapped trigonal-prismatic geometry. The inic ligands, which are protonated at the pyridine N atom, link the met...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808023623 |
| _version_ | 1798017985662681088 |
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| author | Xiao-Hui Huang Wei-Bo Pan Xiao-Hong Xu Rong-Hua Zeng |
| author_facet | Xiao-Hui Huang Wei-Bo Pan Xiao-Hong Xu Rong-Hua Zeng |
| author_sort | Xiao-Hui Huang |
| collection | DOAJ |
| description | In the title complex, {[Tb(C6H5NO2)3(H2O)2](ClO4)3·H2O}n, the TbIII ion is coordinated by six O atoms from six isonicotinate (inic) ligands and two water molecules, displaying a bicapped trigonal-prismatic geometry. The inic ligands, which are protonated at the pyridine N atom, link the metal centres, forming a polymeric chain running parallel to the a axis. The chains are further assembled via intra- and intermolecular O—H...O and N—H...O hydrogen-bonding interactions into a three-dimensional supramolecular network involving the inic ligands, the water molecules and the perchlorate anions. One of the perchlorate ions is disordered over two sites with occupancies of 0.561 (17) and 0.439 (17). |
| first_indexed | 2024-04-11T16:16:32Z |
| format | Article |
| id | doaj.art-74ffc869719649d090eabc416ed4c83e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:16:32Z |
| publishDate | 2008-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-74ffc869719649d090eabc416ed4c83e2022-12-22T04:14:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-08-01648m1098m109910.1107/S1600536808023623catena-Poly[[[diaquaterbium(III)]-tri-μ2-isonicotinato-κ6O:O′] tris(perchlorate) monohydrate]Xiao-Hui HuangWei-Bo PanXiao-Hong XuRong-Hua ZengIn the title complex, {[Tb(C6H5NO2)3(H2O)2](ClO4)3·H2O}n, the TbIII ion is coordinated by six O atoms from six isonicotinate (inic) ligands and two water molecules, displaying a bicapped trigonal-prismatic geometry. The inic ligands, which are protonated at the pyridine N atom, link the metal centres, forming a polymeric chain running parallel to the a axis. The chains are further assembled via intra- and intermolecular O—H...O and N—H...O hydrogen-bonding interactions into a three-dimensional supramolecular network involving the inic ligands, the water molecules and the perchlorate anions. One of the perchlorate ions is disordered over two sites with occupancies of 0.561 (17) and 0.439 (17).http://scripts.iucr.org/cgi-bin/paper?S1600536808023623 |
| spellingShingle | Xiao-Hui Huang Wei-Bo Pan Xiao-Hong Xu Rong-Hua Zeng catena-Poly[[[diaquaterbium(III)]-tri-μ2-isonicotinato-κ6O:O′] tris(perchlorate) monohydrate] Acta Crystallographica Section E |
| title | catena-Poly[[[diaquaterbium(III)]-tri-μ2-isonicotinato-κ6O:O′] tris(perchlorate) monohydrate] |
| title_full | catena-Poly[[[diaquaterbium(III)]-tri-μ2-isonicotinato-κ6O:O′] tris(perchlorate) monohydrate] |
| title_fullStr | catena-Poly[[[diaquaterbium(III)]-tri-μ2-isonicotinato-κ6O:O′] tris(perchlorate) monohydrate] |
| title_full_unstemmed | catena-Poly[[[diaquaterbium(III)]-tri-μ2-isonicotinato-κ6O:O′] tris(perchlorate) monohydrate] |
| title_short | catena-Poly[[[diaquaterbium(III)]-tri-μ2-isonicotinato-κ6O:O′] tris(perchlorate) monohydrate] |
| title_sort | catena poly diaquaterbium iii tri 956 2 isonicotinato 954 6o o 8242 tris perchlorate monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808023623 |
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