Detailed Analysis of Peripheral Reflection from a Photonic Ball

Colloidal crystals with spherical shapes are called photonic balls, and their optical properties have been extensively studied because they can be applied as structurally colored pigments or colorimetric sensors. When a colloidal crystal consists of small colloidal particles, e.g., 250 nm in diamete...

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Main Authors: Ryosuke Ohnuki, Miki Sakai, Yukikazu Takeoka, Shinya Yoshioka
Format: Article
Language:English
Published: Wiley-VCH 2021-12-01
Series:Advanced Photonics Research
Subjects:
Online Access:https://doi.org/10.1002/adpr.202100131
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author Ryosuke Ohnuki
Miki Sakai
Yukikazu Takeoka
Shinya Yoshioka
author_facet Ryosuke Ohnuki
Miki Sakai
Yukikazu Takeoka
Shinya Yoshioka
author_sort Ryosuke Ohnuki
collection DOAJ
description Colloidal crystals with spherical shapes are called photonic balls, and their optical properties have been extensively studied because they can be applied as structurally colored pigments or colorimetric sensors. When a colloidal crystal consists of small colloidal particles, e.g., 250 nm in diameter, the (111) crystal planes of the face‐centered cubic lattice cause Bragg reflection, resulting in a brilliant structural color. However, in colloidal crystals that consist of larger particles, e.g., 400 nm in diameter, different crystal planes may be involved in the coloration; the (220) planes cause ring‐like iridescent reflection in the peripheral part of the spherical crystal. Herein, a detailed optical analysis of this peripheral reflection is presented. The photonic ball consists of many small crystal domains, and the reflecting crystal planes are oriented in different directions from one domain to another. Thus, in some domains, significantly tilted planes and refraction at the spherical surface cause reflection in a highly oblique direction, such that the reflection path requires a 3D description. This study shows that such an oblique reflection significantly affects the appearance of the photonic ball.
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spelling doaj.art-7502762849de4189a49f310f0e58f2b22022-12-21T21:24:23ZengWiley-VCHAdvanced Photonics Research2699-92932021-12-01212n/an/a10.1002/adpr.202100131Detailed Analysis of Peripheral Reflection from a Photonic BallRyosuke Ohnuki0Miki Sakai1Yukikazu Takeoka2Shinya Yoshioka3Graduate School of Science and Technology Tokyo University of Science Yamazaki Noda 278-8510 JapanGraduate School of Engineering Nagoya University Furo-cho Chikusa-ku Nagoya 464-8603 JapanGraduate School of Engineering Nagoya University Furo-cho Chikusa-ku Nagoya 464-8603 JapanGraduate School of Science and Technology Tokyo University of Science Yamazaki Noda 278-8510 JapanColloidal crystals with spherical shapes are called photonic balls, and their optical properties have been extensively studied because they can be applied as structurally colored pigments or colorimetric sensors. When a colloidal crystal consists of small colloidal particles, e.g., 250 nm in diameter, the (111) crystal planes of the face‐centered cubic lattice cause Bragg reflection, resulting in a brilliant structural color. However, in colloidal crystals that consist of larger particles, e.g., 400 nm in diameter, different crystal planes may be involved in the coloration; the (220) planes cause ring‐like iridescent reflection in the peripheral part of the spherical crystal. Herein, a detailed optical analysis of this peripheral reflection is presented. The photonic ball consists of many small crystal domains, and the reflecting crystal planes are oriented in different directions from one domain to another. Thus, in some domains, significantly tilted planes and refraction at the spherical surface cause reflection in a highly oblique direction, such that the reflection path requires a 3D description. This study shows that such an oblique reflection significantly affects the appearance of the photonic ball.https://doi.org/10.1002/adpr.202100131colloidal crystalsnumerical aperture dependenceoptical analysisphotonic ballspigmentsstructural colors
spellingShingle Ryosuke Ohnuki
Miki Sakai
Yukikazu Takeoka
Shinya Yoshioka
Detailed Analysis of Peripheral Reflection from a Photonic Ball
Advanced Photonics Research
colloidal crystals
numerical aperture dependence
optical analysis
photonic balls
pigments
structural colors
title Detailed Analysis of Peripheral Reflection from a Photonic Ball
title_full Detailed Analysis of Peripheral Reflection from a Photonic Ball
title_fullStr Detailed Analysis of Peripheral Reflection from a Photonic Ball
title_full_unstemmed Detailed Analysis of Peripheral Reflection from a Photonic Ball
title_short Detailed Analysis of Peripheral Reflection from a Photonic Ball
title_sort detailed analysis of peripheral reflection from a photonic ball
topic colloidal crystals
numerical aperture dependence
optical analysis
photonic balls
pigments
structural colors
url https://doi.org/10.1002/adpr.202100131
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AT yukikazutakeoka detailedanalysisofperipheralreflectionfromaphotonicball
AT shinyayoshioka detailedanalysisofperipheralreflectionfromaphotonicball