Nano-SiO<sub>2</sub> and Silane Coupling Agent Co-Decorated Graphene Oxides with Enhanced Anti-Corrosion Performance of Epoxy Composite Coatings

Coatings are of great significance for irons and steels in regards to the harsh marine environment. Graphene oxides (GO) have been considered as an ideal filler material of epoxy coating. However, the undesired dispersion in the epoxy together with easy agglomeration and stacking remain great proble...

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Main Authors: Guangjie Hu, Yuxuan Xiao, Jie Ying
Format: Article
Language:English
Published: MDPI AG 2021-10-01
Series:International Journal of Molecular Sciences
Subjects:
Online Access:https://www.mdpi.com/1422-0067/22/20/11087
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author Guangjie Hu
Yuxuan Xiao
Jie Ying
author_facet Guangjie Hu
Yuxuan Xiao
Jie Ying
author_sort Guangjie Hu
collection DOAJ
description Coatings are of great significance for irons and steels in regards to the harsh marine environment. Graphene oxides (GO) have been considered as an ideal filler material of epoxy coating. However, the undesired dispersion in the epoxy together with easy agglomeration and stacking remain great problems for practical application of GO composited epoxy coatings. A method that can effectively solve both self-aggregation and poor dispersion of GO is highly desired. Herein, we present a high dispersion strategy of graphene oxides in epoxy by co-decoration of nano-SiO<sub>2</sub> and silane coupling agent. The co-decorated GO filled epoxy coating exhibits high anti-corrosion performance, including high electrochemical impedance, high self-corrosive potential, low self-corrosive current, and superior electrochemical impedance stability for ten days to Q235 carbon steel. This work displays new possibilities for designing novel coating materials with high performance toward practical marine anti-corrosion applications.
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spelling doaj.art-7510857dd54f48c7a908ff56db3d7b262023-11-22T18:33:36ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672021-10-0122201108710.3390/ijms222011087Nano-SiO<sub>2</sub> and Silane Coupling Agent Co-Decorated Graphene Oxides with Enhanced Anti-Corrosion Performance of Epoxy Composite CoatingsGuangjie Hu0Yuxuan Xiao1Jie Ying2School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, ChinaSchool of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, ChinaSchool of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, ChinaCoatings are of great significance for irons and steels in regards to the harsh marine environment. Graphene oxides (GO) have been considered as an ideal filler material of epoxy coating. However, the undesired dispersion in the epoxy together with easy agglomeration and stacking remain great problems for practical application of GO composited epoxy coatings. A method that can effectively solve both self-aggregation and poor dispersion of GO is highly desired. Herein, we present a high dispersion strategy of graphene oxides in epoxy by co-decoration of nano-SiO<sub>2</sub> and silane coupling agent. The co-decorated GO filled epoxy coating exhibits high anti-corrosion performance, including high electrochemical impedance, high self-corrosive potential, low self-corrosive current, and superior electrochemical impedance stability for ten days to Q235 carbon steel. This work displays new possibilities for designing novel coating materials with high performance toward practical marine anti-corrosion applications.https://www.mdpi.com/1422-0067/22/20/11087graphene oxideepoxy coatingsurface decorationanti-corrosion
spellingShingle Guangjie Hu
Yuxuan Xiao
Jie Ying
Nano-SiO<sub>2</sub> and Silane Coupling Agent Co-Decorated Graphene Oxides with Enhanced Anti-Corrosion Performance of Epoxy Composite Coatings
International Journal of Molecular Sciences
graphene oxide
epoxy coating
surface decoration
anti-corrosion
title Nano-SiO<sub>2</sub> and Silane Coupling Agent Co-Decorated Graphene Oxides with Enhanced Anti-Corrosion Performance of Epoxy Composite Coatings
title_full Nano-SiO<sub>2</sub> and Silane Coupling Agent Co-Decorated Graphene Oxides with Enhanced Anti-Corrosion Performance of Epoxy Composite Coatings
title_fullStr Nano-SiO<sub>2</sub> and Silane Coupling Agent Co-Decorated Graphene Oxides with Enhanced Anti-Corrosion Performance of Epoxy Composite Coatings
title_full_unstemmed Nano-SiO<sub>2</sub> and Silane Coupling Agent Co-Decorated Graphene Oxides with Enhanced Anti-Corrosion Performance of Epoxy Composite Coatings
title_short Nano-SiO<sub>2</sub> and Silane Coupling Agent Co-Decorated Graphene Oxides with Enhanced Anti-Corrosion Performance of Epoxy Composite Coatings
title_sort nano sio sub 2 sub and silane coupling agent co decorated graphene oxides with enhanced anti corrosion performance of epoxy composite coatings
topic graphene oxide
epoxy coating
surface decoration
anti-corrosion
url https://www.mdpi.com/1422-0067/22/20/11087
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AT yuxuanxiao nanosiosub2subandsilanecouplingagentcodecoratedgrapheneoxideswithenhancedanticorrosionperformanceofepoxycompositecoatings
AT jieying nanosiosub2subandsilanecouplingagentcodecoratedgrapheneoxideswithenhancedanticorrosionperformanceofepoxycompositecoatings