Crystal structure of bis(3,5-dimethylpyridine-κN)bis(methanol-κO)bis(thiocyanato-κN)cobalt(II)
The asymmetric unit of the title complex, [Co(NCS)2(C7H9N)2(CH3OH)2], comprises of one CoII cation located on a centre of inversion, one thiocyanate ligand, one methanol ligand and one 3,5-dimethylpyridine ligand. The CoII cation is octahedrally coordinated by two terminal N-bonding thiocyanate anio...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-12-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016018326 |
| _version_ | 1818959223715790848 |
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| author | Stefan Suckert Inke Jess Christian Näther |
| author_facet | Stefan Suckert Inke Jess Christian Näther |
| author_sort | Stefan Suckert |
| collection | DOAJ |
| description | The asymmetric unit of the title complex, [Co(NCS)2(C7H9N)2(CH3OH)2], comprises of one CoII cation located on a centre of inversion, one thiocyanate ligand, one methanol ligand and one 3,5-dimethylpyridine ligand. The CoII cation is octahedrally coordinated by two terminal N-bonding thiocyanate anions, two methanol molecules and two 3,5-dimethylpyridine ligands into a discrete complex. The complex molecules are linked by intermolecular O—H...S hydrogen bonding into chains that elongate in the direction parallel to the b axis. |
| first_indexed | 2024-12-20T11:38:14Z |
| format | Article |
| id | doaj.art-751501d65e834a6fa9846ef8315a78c2 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T11:38:14Z |
| publishDate | 2016-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-751501d65e834a6fa9846ef8315a78c22022-12-21T19:42:02ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-12-0172121824182610.1107/S2056989016018326wm5338Crystal structure of bis(3,5-dimethylpyridine-κN)bis(methanol-κO)bis(thiocyanato-κN)cobalt(II)Stefan Suckert0Inke Jess1Christian Näther2Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, GermanyInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, GermanyInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, GermanyThe asymmetric unit of the title complex, [Co(NCS)2(C7H9N)2(CH3OH)2], comprises of one CoII cation located on a centre of inversion, one thiocyanate ligand, one methanol ligand and one 3,5-dimethylpyridine ligand. The CoII cation is octahedrally coordinated by two terminal N-bonding thiocyanate anions, two methanol molecules and two 3,5-dimethylpyridine ligands into a discrete complex. The complex molecules are linked by intermolecular O—H...S hydrogen bonding into chains that elongate in the direction parallel to the b axis.http://scripts.iucr.org/cgi-bin/paper?S2056989016018326crystal structurecobalt(II) thiocyanate complex3,5-dimethylpyridine ligandhydrogen bonding |
| spellingShingle | Stefan Suckert Inke Jess Christian Näther Crystal structure of bis(3,5-dimethylpyridine-κN)bis(methanol-κO)bis(thiocyanato-κN)cobalt(II) Acta Crystallographica Section E: Crystallographic Communications crystal structure cobalt(II) thiocyanate complex 3,5-dimethylpyridine ligand hydrogen bonding |
| title | Crystal structure of bis(3,5-dimethylpyridine-κN)bis(methanol-κO)bis(thiocyanato-κN)cobalt(II) |
| title_full | Crystal structure of bis(3,5-dimethylpyridine-κN)bis(methanol-κO)bis(thiocyanato-κN)cobalt(II) |
| title_fullStr | Crystal structure of bis(3,5-dimethylpyridine-κN)bis(methanol-κO)bis(thiocyanato-κN)cobalt(II) |
| title_full_unstemmed | Crystal structure of bis(3,5-dimethylpyridine-κN)bis(methanol-κO)bis(thiocyanato-κN)cobalt(II) |
| title_short | Crystal structure of bis(3,5-dimethylpyridine-κN)bis(methanol-κO)bis(thiocyanato-κN)cobalt(II) |
| title_sort | crystal structure of bis 3 5 dimethylpyridine κn bis methanol κo bis thiocyanato κn cobalt ii |
| topic | crystal structure cobalt(II) thiocyanate complex 3,5-dimethylpyridine ligand hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989016018326 |
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