Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition

A new photocatalytic hydroxyapatite (HA) synthesis method has been developed. This method is based on the unique ability of the TiO<sub>2</sub> photocatalyst to decompose the Ca(EDTA) complex under UV illumination. As a result, released Ca<sup>2+</sup> ions react with PO<s...

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Bibliographic Details
Main Authors: Veronika Yu. Yurova, Polina I. Zyrianova, Pavel V. Nesterov, Vyacheslav V. Goncharov, Ekaterina V. Skorb, Sviatlana A. Ulasevich
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/13/6/993
Description
Summary:A new photocatalytic hydroxyapatite (HA) synthesis method has been developed. This method is based on the unique ability of the TiO<sub>2</sub> photocatalyst to decompose the Ca(EDTA) complex under UV illumination. As a result, released Ca<sup>2+</sup> ions react with PO<sub>4</sub><sup>3−</sup> ions forming the HA particles. The photocatalytic formation of hydroxyapatite is found to have a fractional order, which may indicate the complex reaction mechanism and the presence of several limiting stages. The TNT-HA samples were studied by XRD, FTIR, SEM, GDOES, and biocompatibility study. High biocompatibility of the surfaces is proven by pre-osteoblast cell growth.
ISSN:2073-4344