Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition

A new photocatalytic hydroxyapatite (HA) synthesis method has been developed. This method is based on the unique ability of the TiO<sub>2</sub> photocatalyst to decompose the Ca(EDTA) complex under UV illumination. As a result, released Ca<sup>2+</sup> ions react with PO<s...

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Main Authors: Veronika Yu. Yurova, Polina I. Zyrianova, Pavel V. Nesterov, Vyacheslav V. Goncharov, Ekaterina V. Skorb, Sviatlana A. Ulasevich
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/13/6/993
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author Veronika Yu. Yurova
Polina I. Zyrianova
Pavel V. Nesterov
Vyacheslav V. Goncharov
Ekaterina V. Skorb
Sviatlana A. Ulasevich
author_facet Veronika Yu. Yurova
Polina I. Zyrianova
Pavel V. Nesterov
Vyacheslav V. Goncharov
Ekaterina V. Skorb
Sviatlana A. Ulasevich
author_sort Veronika Yu. Yurova
collection DOAJ
description A new photocatalytic hydroxyapatite (HA) synthesis method has been developed. This method is based on the unique ability of the TiO<sub>2</sub> photocatalyst to decompose the Ca(EDTA) complex under UV illumination. As a result, released Ca<sup>2+</sup> ions react with PO<sub>4</sub><sup>3−</sup> ions forming the HA particles. The photocatalytic formation of hydroxyapatite is found to have a fractional order, which may indicate the complex reaction mechanism and the presence of several limiting stages. The TNT-HA samples were studied by XRD, FTIR, SEM, GDOES, and biocompatibility study. High biocompatibility of the surfaces is proven by pre-osteoblast cell growth.
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spelling doaj.art-752c5ae987ca46c2b32d43636b26c0d92023-11-18T09:42:13ZengMDPI AGCatalysts2073-43442023-06-0113699310.3390/catal13060993Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex DecompositionVeronika Yu. Yurova0Polina I. Zyrianova1Pavel V. Nesterov2Vyacheslav V. Goncharov3Ekaterina V. Skorb4Sviatlana A. Ulasevich5Infochemistry Scientific Center, ITMO University, 9 Lomonosov Str., Saint-Petersburg 191002, RussiaInfochemistry Scientific Center, ITMO University, 9 Lomonosov Str., Saint-Petersburg 191002, RussiaInfochemistry Scientific Center, ITMO University, 9 Lomonosov Str., Saint-Petersburg 191002, RussiaInfochemistry Scientific Center, ITMO University, 9 Lomonosov Str., Saint-Petersburg 191002, RussiaInfochemistry Scientific Center, ITMO University, 9 Lomonosov Str., Saint-Petersburg 191002, RussiaInfochemistry Scientific Center, ITMO University, 9 Lomonosov Str., Saint-Petersburg 191002, RussiaA new photocatalytic hydroxyapatite (HA) synthesis method has been developed. This method is based on the unique ability of the TiO<sub>2</sub> photocatalyst to decompose the Ca(EDTA) complex under UV illumination. As a result, released Ca<sup>2+</sup> ions react with PO<sub>4</sub><sup>3−</sup> ions forming the HA particles. The photocatalytic formation of hydroxyapatite is found to have a fractional order, which may indicate the complex reaction mechanism and the presence of several limiting stages. The TNT-HA samples were studied by XRD, FTIR, SEM, GDOES, and biocompatibility study. High biocompatibility of the surfaces is proven by pre-osteoblast cell growth.https://www.mdpi.com/2073-4344/13/6/993photodepositionhydroxyapatitetitania nanotubesCa(EDTA) complex decomposition
spellingShingle Veronika Yu. Yurova
Polina I. Zyrianova
Pavel V. Nesterov
Vyacheslav V. Goncharov
Ekaterina V. Skorb
Sviatlana A. Ulasevich
Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition
Catalysts
photodeposition
hydroxyapatite
titania nanotubes
Ca(EDTA) complex decomposition
title Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition
title_full Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition
title_fullStr Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition
title_full_unstemmed Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition
title_short Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition
title_sort photodeposition of hydroxyapatite into a titanium dioxide nanotubular layer using ca edta complex decomposition
topic photodeposition
hydroxyapatite
titania nanotubes
Ca(EDTA) complex decomposition
url https://www.mdpi.com/2073-4344/13/6/993
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