Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System
Polyimide membranes have excellent physiochemical properties which make them valuable materials for optical area. However, common aromatic polyimide membrane trend to show low transmittance in visible region because of the charge-transfer complex (CTC) in molecular structures. Moreover, it’s trendin...
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MDPI AG
2022-06-01
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Series: | Membranes |
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Online Access: | https://www.mdpi.com/2077-0375/12/6/592 |
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author | Jiajia Yin Haohao Hui Bin Fan Jiang Bian Junfeng Du Hu Yang |
author_facet | Jiajia Yin Haohao Hui Bin Fan Jiang Bian Junfeng Du Hu Yang |
author_sort | Jiajia Yin |
collection | DOAJ |
description | Polyimide membranes have excellent physiochemical properties which make them valuable materials for optical area. However, common aromatic polyimide membrane trend to show low transmittance in visible region because of the charge-transfer complex (CTC) in molecular structures. Moreover, it’s trending to show high moisture uptakes because of the hydrophilic imide rings in molecular structure. In this work, a polyimide composite membrane with SiO<sub>2</sub> antireflective membrane on both sides was prepared. High transmittance (93% within 500~800 nm) and surface hydrophobicity was realized simultaneously. The polyimide composite membrane showed great optical homogeneity. The SiO<sub>2</sub> antireflective membranes on polyimide substrate were prepared through a simple and efficient sol-gel method. The surface roughness of polyimide membrane substrate on each side has been improved to 1.56 nm and 3.14 nm, respectively. Moreover, the excellent thermal stability and mechanical property of polyimide membrane has been preserved, which greatly improves the range of applications for the composite membrane. It is a good candidate for light weight optical system. |
first_indexed | 2024-03-09T23:05:00Z |
format | Article |
id | doaj.art-7536272e025e4913b008fabe1d20ce22 |
institution | Directory Open Access Journal |
issn | 2077-0375 |
language | English |
last_indexed | 2024-03-09T23:05:00Z |
publishDate | 2022-06-01 |
publisher | MDPI AG |
record_format | Article |
series | Membranes |
spelling | doaj.art-7536272e025e4913b008fabe1d20ce222023-11-23T17:54:26ZengMDPI AGMembranes2077-03752022-06-0112659210.3390/membranes12060592Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical SystemJiajia Yin0Haohao Hui1Bin Fan2Jiang Bian3Junfeng Du4Hu Yang5Institute of Optics and Electronics, Chinese Academy of Sciences, Chengdu 610209, ChinaLaser Fusion Research Center, China Academy of Engineering Physics, Chengdu 610200, ChinaInstitute of Optics and Electronics, Chinese Academy of Sciences, Chengdu 610209, ChinaInstitute of Optics and Electronics, Chinese Academy of Sciences, Chengdu 610209, ChinaInstitute of Optics and Electronics, Chinese Academy of Sciences, Chengdu 610209, ChinaInstitute of Optics and Electronics, Chinese Academy of Sciences, Chengdu 610209, ChinaPolyimide membranes have excellent physiochemical properties which make them valuable materials for optical area. However, common aromatic polyimide membrane trend to show low transmittance in visible region because of the charge-transfer complex (CTC) in molecular structures. Moreover, it’s trending to show high moisture uptakes because of the hydrophilic imide rings in molecular structure. In this work, a polyimide composite membrane with SiO<sub>2</sub> antireflective membrane on both sides was prepared. High transmittance (93% within 500~800 nm) and surface hydrophobicity was realized simultaneously. The polyimide composite membrane showed great optical homogeneity. The SiO<sub>2</sub> antireflective membranes on polyimide substrate were prepared through a simple and efficient sol-gel method. The surface roughness of polyimide membrane substrate on each side has been improved to 1.56 nm and 3.14 nm, respectively. Moreover, the excellent thermal stability and mechanical property of polyimide membrane has been preserved, which greatly improves the range of applications for the composite membrane. It is a good candidate for light weight optical system.https://www.mdpi.com/2077-0375/12/6/592polyimide composite membranehigh transmittancehydrophobic surface |
spellingShingle | Jiajia Yin Haohao Hui Bin Fan Jiang Bian Junfeng Du Hu Yang Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System Membranes polyimide composite membrane high transmittance hydrophobic surface |
title | Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System |
title_full | Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System |
title_fullStr | Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System |
title_full_unstemmed | Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System |
title_short | Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System |
title_sort | preparation and properties of polyimide composite membrane with high transmittance and surface hydrophobicity for lightweight optical system |
topic | polyimide composite membrane high transmittance hydrophobic surface |
url | https://www.mdpi.com/2077-0375/12/6/592 |
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