Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System

Polyimide membranes have excellent physiochemical properties which make them valuable materials for optical area. However, common aromatic polyimide membrane trend to show low transmittance in visible region because of the charge-transfer complex (CTC) in molecular structures. Moreover, it’s trendin...

Full description

Bibliographic Details
Main Authors: Jiajia Yin, Haohao Hui, Bin Fan, Jiang Bian, Junfeng Du, Hu Yang
Format: Article
Language:English
Published: MDPI AG 2022-06-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/12/6/592
_version_ 1797484480725778432
author Jiajia Yin
Haohao Hui
Bin Fan
Jiang Bian
Junfeng Du
Hu Yang
author_facet Jiajia Yin
Haohao Hui
Bin Fan
Jiang Bian
Junfeng Du
Hu Yang
author_sort Jiajia Yin
collection DOAJ
description Polyimide membranes have excellent physiochemical properties which make them valuable materials for optical area. However, common aromatic polyimide membrane trend to show low transmittance in visible region because of the charge-transfer complex (CTC) in molecular structures. Moreover, it’s trending to show high moisture uptakes because of the hydrophilic imide rings in molecular structure. In this work, a polyimide composite membrane with SiO<sub>2</sub> antireflective membrane on both sides was prepared. High transmittance (93% within 500~800 nm) and surface hydrophobicity was realized simultaneously. The polyimide composite membrane showed great optical homogeneity. The SiO<sub>2</sub> antireflective membranes on polyimide substrate were prepared through a simple and efficient sol-gel method. The surface roughness of polyimide membrane substrate on each side has been improved to 1.56 nm and 3.14 nm, respectively. Moreover, the excellent thermal stability and mechanical property of polyimide membrane has been preserved, which greatly improves the range of applications for the composite membrane. It is a good candidate for light weight optical system.
first_indexed 2024-03-09T23:05:00Z
format Article
id doaj.art-7536272e025e4913b008fabe1d20ce22
institution Directory Open Access Journal
issn 2077-0375
language English
last_indexed 2024-03-09T23:05:00Z
publishDate 2022-06-01
publisher MDPI AG
record_format Article
series Membranes
spelling doaj.art-7536272e025e4913b008fabe1d20ce222023-11-23T17:54:26ZengMDPI AGMembranes2077-03752022-06-0112659210.3390/membranes12060592Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical SystemJiajia Yin0Haohao Hui1Bin Fan2Jiang Bian3Junfeng Du4Hu Yang5Institute of Optics and Electronics, Chinese Academy of Sciences, Chengdu 610209, ChinaLaser Fusion Research Center, China Academy of Engineering Physics, Chengdu 610200, ChinaInstitute of Optics and Electronics, Chinese Academy of Sciences, Chengdu 610209, ChinaInstitute of Optics and Electronics, Chinese Academy of Sciences, Chengdu 610209, ChinaInstitute of Optics and Electronics, Chinese Academy of Sciences, Chengdu 610209, ChinaInstitute of Optics and Electronics, Chinese Academy of Sciences, Chengdu 610209, ChinaPolyimide membranes have excellent physiochemical properties which make them valuable materials for optical area. However, common aromatic polyimide membrane trend to show low transmittance in visible region because of the charge-transfer complex (CTC) in molecular structures. Moreover, it’s trending to show high moisture uptakes because of the hydrophilic imide rings in molecular structure. In this work, a polyimide composite membrane with SiO<sub>2</sub> antireflective membrane on both sides was prepared. High transmittance (93% within 500~800 nm) and surface hydrophobicity was realized simultaneously. The polyimide composite membrane showed great optical homogeneity. The SiO<sub>2</sub> antireflective membranes on polyimide substrate were prepared through a simple and efficient sol-gel method. The surface roughness of polyimide membrane substrate on each side has been improved to 1.56 nm and 3.14 nm, respectively. Moreover, the excellent thermal stability and mechanical property of polyimide membrane has been preserved, which greatly improves the range of applications for the composite membrane. It is a good candidate for light weight optical system.https://www.mdpi.com/2077-0375/12/6/592polyimide composite membranehigh transmittancehydrophobic surface
spellingShingle Jiajia Yin
Haohao Hui
Bin Fan
Jiang Bian
Junfeng Du
Hu Yang
Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System
Membranes
polyimide composite membrane
high transmittance
hydrophobic surface
title Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System
title_full Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System
title_fullStr Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System
title_full_unstemmed Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System
title_short Preparation and Properties of Polyimide Composite Membrane with High Transmittance and Surface Hydrophobicity for Lightweight Optical System
title_sort preparation and properties of polyimide composite membrane with high transmittance and surface hydrophobicity for lightweight optical system
topic polyimide composite membrane
high transmittance
hydrophobic surface
url https://www.mdpi.com/2077-0375/12/6/592
work_keys_str_mv AT jiajiayin preparationandpropertiesofpolyimidecompositemembranewithhightransmittanceandsurfacehydrophobicityforlightweightopticalsystem
AT haohaohui preparationandpropertiesofpolyimidecompositemembranewithhightransmittanceandsurfacehydrophobicityforlightweightopticalsystem
AT binfan preparationandpropertiesofpolyimidecompositemembranewithhightransmittanceandsurfacehydrophobicityforlightweightopticalsystem
AT jiangbian preparationandpropertiesofpolyimidecompositemembranewithhightransmittanceandsurfacehydrophobicityforlightweightopticalsystem
AT junfengdu preparationandpropertiesofpolyimidecompositemembranewithhightransmittanceandsurfacehydrophobicityforlightweightopticalsystem
AT huyang preparationandpropertiesofpolyimidecompositemembranewithhightransmittanceandsurfacehydrophobicityforlightweightopticalsystem